E-resources
-
Arrowsmith, Merle; Auerhammer, Dominic; Bertermann, Rüdiger; Braunschweig, Holger; Celik, Mehmet Ali; Erdmannsdörfer, Julian; Krummenacher, Ivo; Kupfer, Thomas
Angewandte Chemie, September 4, 2017, Volume: 56, Issue: 37Journal Article
Deprotonation of (cAAC)BH2(CN) provided clean access to the stable boryl anion, (cAAC)BH(CN)−. Whereas the addition of soft electrophiles occurred at the nucleophilic boron center, harder silyl electrophiles added to the harder terminal cyano nitrogen. The resulting (cAAC)BH(CNSiPh3) species behaved like a silylium boryl nucleophile as well as a neutral silylisonitrile borylene. Whereas the salt metathesis of soft electrophiles with the (cyano)hydroboryl anion (cAAC)B(CN)H− occurs at the nucleophilic boron center, comparatively harder silyl electrophiles add to the harder terminal cyano nitrogen. The resulting (cAAC)BH(CNSiR3) species behave as both zwitterionic silylium boryl and neutral silylisonitrile borylene, a BI compound accessed through simple deprotonation and salt metathesis. cAAC=cyclic (alkyl)(amino)carbene.
![loading ... loading ...](themes/default/img/ajax-loading.gif)
Shelf entry
Permalink
- URL:
Impact factor
Access to the JCR database is permitted only to users from Slovenia. Your current IP address is not on the list of IP addresses with access permission, and authentication with the relevant AAI accout is required.
Year | Impact factor | Edition | Category | Classification | ||||
---|---|---|---|---|---|---|---|---|
JCR | SNIP | JCR | SNIP | JCR | SNIP | JCR | SNIP |
Select the library membership card:
If the library membership card is not in the list,
add a new one.
DRS, in which the journal is indexed
Database name | Field | Year |
---|
Links to authors' personal bibliographies | Links to information on researchers in the SICRIS system |
---|
Source: Personal bibliographies
and: SICRIS
The material is available in full text. If you wish to order the material anyway, click the Continue button.