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Qin, Lei; Yu, You-Zhu; Liao, Pei-Qin; Xue, Wei; Zheng, Zhiping; Chen, Xiao-Ming; Zheng, Yan-Zhen
Advanced materials (Weinheim), 12/2016, Volume: 28, Issue: 48Journal Article
A lanthanide cluster, PCC‐72, which is the second largest, with 72 Dy(III) ions assembled into an unprecedented tubular structure, is synthesized. Remarkably, PCC‐72 exhibits superionic proton conductivity (>10−4 S cm−1) under both ambient (with relative humidity RH < 75%) and hot (T > 90 °C, RH = 95%) conditions. Moreover, slow magnetic relaxation is observed, making PCC‐72 the largest Dy(III) cluster that is a single‐molecule magnet.
