Model dvostupanjske troelektronske površinske redoks-reakcije

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Model dvostupanjske troelektronske površinske redoks-reakcije

Lovrić, Milivoj

Kemija u industriji 73, Issue: 5-6

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Razvijena je teorija cikličke voltametrije površinskog redoks-mehanizma, koji se sastoji od uzastopnih prijenosa jednog i dvaju elektrona. Pretpostavljeno je da prvi korak zavisi o kinetici prijenosa, a da je drugi reverzibilan. Javljaju se tri tipa odziva koji zavise o kinetičkim parametrima i razlici standardnih potencijala. Objašnjeno je kako se mogu izračunati koeficijenti prijelaza i standardna konstanta brzine prve elektrodne reakcije.

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