E-resources
Peer reviewed
-
Yan, Zhengquan; Zheng, Xiaoyu; Meng, Guoqing; Tang, Yulian; Zhou, Xuemei; Hao, Junkai; Feng, Jing
Mikrochimica acta (1966), 01/2023, Volume: 190, Issue: 1Journal Article
A portable sensor for visual monitoring of Fe.sup.2+ and H.sub.2O.sub.2, two-dimensional Co.sub.3O.sub.4 modified by nano-IrO.sub.2 (IrO.sub.2@2D Co.sub.3O.sub.4) was prepared in this work, for the first time, with the help of microwave radiation at 140 °C, which was further stabilized onto common test strips. The present IrO.sub.2@2D Co.sub.3O.sub.4 possessed superior dual-function enzyme-like activity with low toxicity and excellent biocompatibility. Especially, trace Fe.sup.2+ and H.sub.2O.sub.2 could exclusively alter their enzyme-like catalytic activity with discriminating hyperchromic or hypochromic effect, i.e., from blue to colorless or to dark blue for both IrO.sub.2@2D Co.sub.3O.sub.4 dispersion and its functionalized test strips. The linear regression equations were A.sub.652 = 0.5940 - 0.00041 c.sub.Fe.sup.2+ (10.sup.-8 M, R.sup.2 = 0.9927) for Fe.sup.2+ and âA.sub.652 = 0.0023 c.sub.H2O2 + 0.00025 (10.sup.-7 M, R.sup.2 = 0.9982) for H.sub.2O.sub.2, respectively. When applied to visual monitoring of aqueous Fe.sup.2+ and intercellular H.sub.2O.sub.2, the recoveries were 101.2 ~ 102.5% and 95.8 ~ 103.7% with detection limits of 1.25 x 10.sup.-8 mol/L and 1.02 x 10.sup.-7 mol/L, respectively, far below the permitted values in drinking water set by the World Health Organization. The mechanisms for the enhancing enzyme-mimetic activity of IrO.sub.2@2D Co.sub.3O.sub.4 and its selective responses to Fe.sup.2+ and H.sub.2O.sub.2 were investigated in detail. Graphical
Author
![loading ... loading ...](themes/default/img/ajax-loading.gif)
Shelf entry
Permalink
- URL:
Impact factor
Access to the JCR database is permitted only to users from Slovenia. Your current IP address is not on the list of IP addresses with access permission, and authentication with the relevant AAI accout is required.
Year | Impact factor | Edition | Category | Classification | ||||
---|---|---|---|---|---|---|---|---|
JCR | SNIP | JCR | SNIP | JCR | SNIP | JCR | SNIP |
Select the library membership card:
If the library membership card is not in the list,
add a new one.
DRS, in which the journal is indexed
Database name | Field | Year |
---|
Links to authors' personal bibliographies | Links to information on researchers in the SICRIS system |
---|
Source: Personal bibliographies
and: SICRIS
The material is available in full text. If you wish to order the material anyway, click the Continue button.