In this paper, we report a comparative study of fiber optic sensors for applications of relative humidity (RH) monitoring in high-radiation environments. In particular, we present investigations ...carried out since 2011 by our multidisciplinary research group, in collaboration with the European Organization for Nuclear Research (CERN) in Geneva. Our research has been first focused on the development of polyimide-coated fiber Bragg grating (FBG) sensors, and recently, it has been extended to nanoscale metal oxide-coated long-period gratings (LPGs). Experimental tests in the 0-70 %RH range at different temperatures, before and after γ-ionizing radiation exposures, have been carried out to assess the sensors' performances in conditions required in experiments running at CERN. The advantages and disadvantages of the two proposed technologies are discussed in this paper in light of their possible application in high-energy physics environments. In particular, reported results suggest that LPG-based sensors can be preferred in some applications (particularly in presence of very low humidity levels) mainly because they are able to provide very high RH sensitivity (up to 1.4 nm/% RH), which is up to three orders of magnitude higher than that exhibited by FBG-based hygrometers. On the other side, compared with FBGs, LPGs are more difficult to multiplex due to limitations in terms of available bandwidth.
Diffusion through different grain boundaries (GBs) in thin films is analyzed by solving the diffusion equations numerically. Supposing a bimodal grain structure, i.e. boundaries with low and high ...diffusivities, the thin film diffusion problem is solved using the following boundary conditions: one surface is maintained at unit concentration, at the back surface zero flux or fast surface diffusion and the formation of a secondary diffusion source is supposed. In the case of a C kinetic regime, the contributions of the fast and slow boundaries can be separated: the appearance time of the secondary diffusion source is determined by the high diffusivity boundaries, on the other hand, the diffusion broadening of the region in which the grain boundaries are saturated is controlled by the slow GBs. Similarly, the out-diffusion from the secondary diffusion source is also controlled by the slow GBs. From the time evolution of the concentration profiles measured experimentally in the Ta/Co/Si system, Si diffusivities are determined by fitting our numerical solutions. Our results underline the importance of the fitting procedure proposed in this article, i.e. the fitting of the central part of the film can be free of errors due to instrumental broadening around the interfaces.
► We solved the diffusion equation numerically supposing a bimodal grain structure. ► The contribution of fast and slow boundaries could be separated. ► Slow boundaries determine the time evolution of profiles around diffusion sources. ► We determined Si diffusivities from profiles measured in Ta/Co/Si system. ► Errors due instrumental broadening around interfaces can be reduced using our fit.
This benchmarking study aims to compare residual dose rate predictions from the MARS and DORIAN codes with experimental measurements taken from samples irradiated at CERN's CERF facility. The ...research evaluates the residual dose rates of these samples over varied cooling intervals. Additionally, it delves into the influence of parameter choices, such as specific physics processes and energy thresholds, on the production and transport of particles and their effects on simulation outcomes. While both MARS and DORIAN largely align with experimental findings, discrepancies were observed in the copper sample. This prompted an in-depth examination of the elevated dose rates from MARS.
A new parasitic, mixed-field, neutron-dominated irradiation station has been recently commissioned at the European Laboratory for Particle Physics (CERN). The station is installed within the neutron ...time-of-flight (n_TOF) facility, taking advantage of the secondary radiation produced by the neutron spallation target, with neutrons ranging from 0.025 eV to several hundreds of MeV. The new station allows radiation damage studies to be performed in irradiation conditions that are closer to the ones encountered during the operation of particle accelerators; the irradiation tests carried out in the station will be complementary to the standard tests on materials, usually performed with gamma sources. Samples will be exposed to neutron-dominated doses in the MGy range per year, with minimal impact on the n_TOF facility operation. The station has 24 irradiation positions, each hosting up to100cm3of sample material. In view of its proximity to the n_TOF target, inside protective shielding, the irradiation station and its operating procedures have been carefully developed taking into account the safety of personnel and to avoid any unwanted impact on the operation of the n_TOF facility and experiments. Due to the residual radioactivity of the whole area around the n_TOF target and of the irradiated samples, access to the irradiation station is forbidden to human operators even when the n_TOF facility is not in operation. Robots are used for the remote installation and retrieval of the samples, and other optimizations of the handling procedures were developed in compliance with radiation protection regulations and the aim of minimizing doses to personnel. The sample containers were designed to be radiation tolerant, compatible with remote handling, and subject to detailed risk analysis and testing during their development. The whole life cycle of the irradiated materials, including their post-irradiation examinations and final disposal, was considered and optimized.
To determine whether antimicrobial resistance patterns of major mastitis pathogens isolated from milk samples from dairy cows have changed over time.
Retrospective study.
8905 bacterial isolates ...obtained from milk samples submitted to the Wisconsin Veterinary Diagnostic Laboratory between January 1994 and June 2001.
Antimicrobial susceptibility was determined by means of the Kirby-Bauer disk diffusion method. Logistic regression was used to determine whether percentages of isolates resistant to various antimicrobials changed over time.
For the gram-positive mastitis pathogens, percentages of isolates resistant to various flactam antimicrobials did not increase over the course of the study. Percentage of Staphylococcus aureus isolates resistant to penicillin decreased from 49 to 30%; percentage of Streptococcus isolates resistant to penicillin decreased from 6 to 1%. Percentage of isolates resistant to erythromycin increased for S aureus, Escherichia coli, Enterobacter spp, Enterococcus spp, and Pasteurella spp. Percentage of isolates resistant to lincomycin increased for S aureus and Staphylococcus spp. Percentage of coagulase-negative Staphylococcus isolates resistant to pirlimycin increased from 6 to 19%. For several pathogens, percentages of isolates resistant to sulfisoxazole and to trimethoprim-sulfamethoxazole decreased. No pathogens had a significant increase in the percentage of isolates resistant to novobiocin-penicillin.
Results did not indicate a trend toward increased antimicrobial resistance among mastitis pathogens isolated from milk samples from dairy cows between 1994 and 2001. Reduced resistance to flactam antimicrobials was identified for several gram-positive mastitis pathogens.
Low temperature analysis of diffusion and intermixing of Co–Si systems are very important in applications for microelectronics and Ultra Large Scale Integration (ULSI). In this communication a ...comprehensive report has been given on degradation and diffusion processes in the Si(substrate)/Co(150 nm)/Ta(10 nm) system. The samples were prepared by DC magnetron sputtering and were annealed in argon ambient at several temperatures ranging from 400 to 623 K for various times. The composition of the samples was investigated by Secondary Neutral Mass Spectrometry (SNMS). The degradation/intermixing starts with fast (grain boundary (GB)) diffusion of the Si into the Co layer. After some incubation time Si atoms appear and spread over the Co/Ta interface. This amount of Si accumulated at the Co/Ta interface acts as a reservoir for back-diffusion into the Co layer from the Co/Ta interface through the slower grain boundaries. At higher temperatures the formation of a Co–Si phase was detected at the Co/Si and Co/Ta interface. Three different diffusion coefficients were calculated from the SNMS concentration–depth profiles using “Central-gradient” (CG) and “First-appearance” methods. The observed intermixing was interpreted as a mixture of different “C-type” grain boundary diffusion processes. Furthermore, the experimental results are also compared with computer simulations modelling the grain-boundary diffusion through different grain-boundary paths. From the SNMS profiles measured at different temperatures the activation energy of the GB interdiffusion coefficients was deduced using the “CG method”.
The objective of this study was to examine the characteristics of milk samples submitted for microbiological examination at the Wisconsin Veterinary Diagnostic Laboratory between 1994 and 2001. ...Results (n = 83,650) of microbiological testing of milk samples (n = 77,172) submitted to the Wisconsin Veterinary Diagnostic Laboratory from January 1994 until June 2001 were analyzed. Submissions included milk samples obtained from cases of clinical and subclinical mastitis as well as samples obtained for mastitis surveillance programs. Results were recorded as no growth, contaminated, or identified as specific bacterial pathogens. Statistical analysis was performed to determine trends in the isolation of mastitis pathogens. The proportion of samples identified as contaminated decreased from 20.6 (1997) to 9.5% (2001). The proportion of samples coded as no growth increased from 22.6 (1994) to 49.7% (2001). Isolation of Staphylococcus aureus decreased from 17.7% (1994) of isolates to 9.7% (2001), while isolation of Streptococcus agalactiae decreased from 8.1 (1994) to 3.0% (2001). Coagulase-negative Staphylococcus spp. were isolated from 12.7 to 17.5%, environmental Streptococcus spp. were isolated from 11.6 to 20.1%, and Escherichia coli were isolated from 3.1 to 6.7% of all isolates. No growth and contaminated samples comprised almost 50% of total submissions, and it is important that producers have proper expectations when submitting milk samples. The proportion of isolates identified as Staph. aureus and Strep. agalactiae decreased, suggesting the proportion of contagious bacteria causing mastitis has decreased. Environmental and contagious pathogens demonstrated characteristic differences by season.
This benchmarking study aims to compare residual dose rate predictions from the MARS and DORIAN codes with experimental measurements taken from samples irradiated at CERN's CERF facility. The ...research evaluates the residual dose rates of these samples over varied cooling intervals. Additionally, it delves into the influence of parameter choices, such as specific physics processes and energy thresholds, on the production and transport of particles and their effects on simulation outcomes. While both MARS and DORIAN largely align with experimental findings, discrepancies were observed in the copper sample. This prompted an in-depth examination of the elevated dose rates from MARS.
A new parasitic, mixed-field, neutron-dominated irradiation station has been recently commissioned at the European Laboratory for Particle Physics (CERN). The station is installed in the Neutron ...Time-Of-Flight (n\_TOF) facility, taking advantage of the secondary radiation produced by the neutron spallation target. The new station allows radiation damage studies to be performed in irradiation conditions that are closer to the ones encountered during the operation of particle accelerators; the irradiation tests carried out in the station will be complementary to the standard tests on materials, usually performed with gamma sources. Samples will be exposed to neutron doses in the MGy range per year, with minimal impact on the n TOF facility operation. The station has twenty-four irradiation positions, each hosting up to 100 cm3 of sample material. In view of its proximity to the n\_TOF target, inside protective shielding, the irradiation station and its operating procedures have been carefully developed taking into account the safety of personnel and to avoid any unwanted impact on the operation of the n\_TOF facility and experiments. Due to the residual radioactivity of the whole area around the n\_TOF target and of the irradiated samples, access to the irradiation station is forbidden to human operators even when the n\_TOF facility is not in operation. Robots are used for the remote installation and retrieval of the samples, and other optimizations of the handling procedures were developed in compliance with radiation protection regulations and the aim of minimizing doses to personnel.
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