Charge density modulations have been observed in all families of high-critical temperature (
) superconducting cuprates. Although they are consistently found in the underdoped region of the phase ...diagram and at relatively low temperatures, it is still unclear to what extent they influence the unusual properties of these systems. Using resonant x-ray scattering, we carefully determined the temperature dependence of charge density modulations in YBa
Cu
O
and Nd
Ba
Cu
O
for several doping levels. We isolated short-range dynamical charge density fluctuations in addition to the previously known quasi-critical charge density waves. They persist up to well above the pseudogap temperature
, are characterized by energies of a few milli-electron volts, and pervade a large area of the phase diagram.
In the underdoped regime, the cuprate high-temperature superconductors exhibit a host of unusual collective phenomena, including unconventional spin and charge density modulations, Fermi surface ...reconstructions, and a pseudogap in various physical observables. Conversely, overdoped cuprates are generally regarded as conventional Fermi liquids possessing no collective electronic order. In partial contradiction to this widely held picture, we report resonant X-ray scattering measurements revealing incommensurate charge order reflections for overdoped (Bi,Pb)2.12Sr1.88CuO6+δ (Bi2201), with correlation lengths of 40–60 lattice units, that persist up to temperatures of at least 250 K. The value of the charge order wavevector decreases with doping, in line with the extrapolation of the trend previously observed in underdoped Bi2201. In overdoped materials, however, charge order coexists with a single, unreconstructed Fermi surface without nesting or pseudogap features. The discovery of re-entrant charge order in Bi2201 thus calls for investigations in other cuprate families and for a reconsideration of theories that posit an essential relationship between these phenomena.
We use high-resolution resonant inelastic x-ray scattering (RIXS) to study a thin film ofNdNiO3, a compound whose unusual spin- and bond-ordered electronic ground state has been of long-standing ...interest. Below the magnetic ordering temperature, we observe well-defined collective magnon excitations along different high-symmetry directions in momentum space. The magnetic spectra depend strongly on the incident photon energy, which we attribute to RIXS coupling to different local electronic configurations of the expanded and compressedNiO6octahedra in the bond-ordered state. Both the noncollinear magnetic ground state and the observed site-dependent magnon excitations are well described by a model that assumes strong competition between the antiferromagnetic superexchange and ferromagnetic double-exchange interactions. Our study provides direct insight into the magnetic dynamics and exchange interactions of the rare-earth nickelates and demonstrates that RIXS can serve as a site-selective probe of magnetism in these and other materials.
We report a comprehensive Cu L3-edge resonant x-ray scattering (RXS) study of two- and three-dimensional (2D and 3D) incommensurate charge correlations in single crystals of the underdoped ...high-temperature superconductor YBa2Cu3O6.67 under uniaxial compression up to 1% along the two inequivalent Cu─O─Cu bond directions (a and b) in the CuO2 planes. We confirm the strong in-plane anisotropy of the 2D charge correlations and observe their symmetric response to pressure: pressure along a enhances correlations along b, and vice versa. Our results imply that the underlying order parameter is uniaxial. In contrast, 3D long-range charge order is only observed along b in response to compression along a. Spectroscopic RXS measurements show that the 3D charge order resides exclusively in the CuO2 planes and may thus be generic to the cuprates. We discuss implications of these results for models of electronic nematicity and for the interplay between charge order and superconductivity.
The spin-wave dispersions in iron and nickel along the 111 direction are determined using soft x-ray resonant inelastic x-ray scattering (RIXS). For iron, a 10-nm thin film was studied and, over the ...limited q range accessible, the peaks disperse as expected for a spin wave and in agreement with inelastic neutron scattering (INS) results. At the higher q values damping is observed with the peaks weakening and broadening. This damping is less pronounced than in the INS studies. The RIXS results are also compared with ab initio spin fluctuation calculations. The calculations slightly underestimate the energy dispersion and the damping is larger than in the measurement. Nevertheless, the agreement between the RIXS results, INS studies, and the theory is quite satisfactory. For the single crystal of nickel, the measured q dispersion flattens out rapidly and the peaks broaden. The strong damping effect is reproduced by the spin fluctuation calculations but the energy of the peaks is largely overestimated. Nevertheless, the flattening of the dispersion is not reproduced by the calculations and, although similar effects were observed in early INS experiments, they are not seen in more recent work. Possible reasons for this are discussed. These measurements show that using soft x-ray RIXS to study spin fluctuations in metallic systems, which are in general very challenging for the technique, has much promise. More interestingly, since the iron measurements were performed on a 10-nm thin film, the study opens the possibility to study tailor-made thin-film samples, which cannot be easily studied by other techniques. Combining these studies with state-of-the-art ab initio calculations opens up interesting prospects for testing our understanding of spin waves in metallic systems.
In high-temperature cuprate superconductors, stripe order refers broadly to a coupled spin and charge modulation with a commensuration of eight and four lattice units, respectively. How this stripe ...order evolves across optimal doping remains a controversial question. Here we present a systematic resonant inelastic x-ray scattering study of weak charge correlations in La
Sr
CuO
and La
Eu
Sr
CuO
. Ultra high energy resolution experiments demonstrate the importance of the separation of inelastic and elastic scattering processes. Long-range temperature-dependent stripe order is only found below optimal doping. At higher doping, short-range temperature-independent correlations are present up to the highest doping measured. This transformation is distinct from and preempts the pseudogap critical doping. We argue that the doping and temperature-independent short-range correlations originate from unresolved electron-phonon coupling that broadly peaks at the stripe ordering vector. In La
Sr
CuO
, long-range static stripe order vanishes around optimal doping and we discuss both quantum critical and crossover scenarios.
Iron phthalocyanines (FePc) adsorbed onto a Ag(110) substrate self-assemble into different monolayer phases going from rectangular to different oblique phases, with increasing molecular density. We ...have investigated the oxygen uptake capability of the different phases and their associated magneto-structural changes. Our study combines scanning tunneling microscopy and spectroscopy (STM/STS), X-ray magnetic circular dichroism (XMCD), and density functional theory (DFT) calculations. STM measurements reveal that the oxygenation reaction of the FePc/Ag(110) generally involves a displacement and a rotation of the molecules, which affects the electronic state of the Fe centers. The oxygen intercalation between FePc and the substrate is greatly obstructed by the steric hindrance in the high-density phases, to the point that a fraction of oblique phase molecules cannot change their position after oxidizing. Depending on the oxidation state and adsoption geometry, the STS spectra show clear differences in the Fe local density of states, which are mirrored in the XAS and XMCD experiments. Particularly, XMCD spectra of the oxidized phases reflect the distribution of FePc species (nonoxygenated, oxygenated-rotated, and oxygenated-unrotated) in the different cases. Sum rule analysis yields the effective spin (m s eff) and orbital (m L) magnetic moments of Fe in the different FePc species. Upon oxygenation, the magnetic moment of FePc molecules increases about an order of magnitude, reaching m TOT ∼ 2.2 μB per Fe atom.
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