Abstract
Many volcanoes erupt compositionally homogeneous magmas over timescales ranging from decades to millennia. This monotonous activity is thought to reflect a high degree of chemical ...homogeneity in their magmatic systems, leading to predictable eruptive behaviour. We combine petrological analyses of erupted crystals with new thermodynamic models to characterise the diversity of melts in magmatic systems beneath monotonous shield volcanoes in the Galápagos Archipelago (Wolf and Fernandina). In contrast with the uniform basaltic magmas erupted at the surface over long timescales, we find that the sub-volcanic systems contain extreme heterogeneity, with melts extending to rhyolitic compositions. Evolved melts are in low abundance and large volumes of basalt flushing through the crust from depth overprint their chemical signatures. This process will only maintain monotonous activity while the volume of melt entering the crust is high, raising the possibility of transitions to more silicic activity given a decrease in the crustal melt flux.
The 2011 eruption of Nabro volcano, Eritrea, produced one of the largest volcanic sulphur inputs to the atmosphere since the 1991 eruption of Mt. Pinatubo, yet has received comparatively little ...scientific attention. Nabro forms part of an off-axis alignment, broadly perpendicular to the Afar Rift, and has a history of large-magnitude explosive silicic eruptions, as well as smaller more mafic ones. Here, we present and analyse extensive petrological data obtained from samples of trachybasaltic tephra erupted during the 2011 eruption to assess the pre-eruptive magma storage system and explain the large sulphur emission. We show that the eruption involved two texturally distinct batches of magma, one of which was more primitive and richer in sulphur than the other, which was higher in water (up to 2.5 wt%). Modelling of the degassing and crystallisation histories demonstrates that the more primitive magma rose rapidly from depth and experienced degassing crystallisation, while the other experienced isobaric cooling in the crust at around 5 km depth. Interaction between the two batches occurred shortly before the eruption. The eruption itself was likely triggered by recharge-induced destabilisation of vertically extensive mush zone under the volcano. This could potentially account for the large volume of sulphur released. Some of the melt inclusions are volatile undersaturated, and suggest that the original water content of the magma was around 1.3 wt%, which is relatively high for an intraplate setting, but consistent with seismic studies of the Afar plume. This eruption was smaller than some geological eruptions at Nabro, but provides important insights into the plumbing systems and dynamics of off-axis volcanoes in Afar.
Millennial storage of near-Moho magma Mutch, Euan J F; Maclennan, John; Holland, Tim J B ...
Science (American Association for the Advancement of Science),
2019-Jul-19, 2019-07-19, 20190719, Letnik:
365, Številka:
6450
Journal Article
Recenzirano
Odprti dostop
The lower crust plays a critical role in the processing of mantle melts and the triggering of volcanic eruptions by supply of magma from greater depth. Our understanding of the deeper parts of ...magmatic systems is obscured by overprinting of deep signals by shallow processes. We provide a direct estimate of magma residence time in basaltic systems of the deep crust by studying ultramafic nodules from the Borgarhraun eruption in Iceland. Modeling of chromium-aluminum interdiffusion in spinel crystals provides a record of long-term magmatic storage on the order of 1000 years. This places firm constraints on the total crustal residence time of mantle-derived magmas and has important implications for modeling the growth and evolution of transcrustal magmatic systems.
Magma mingling and mixing are common processes at basaltic volcanoes and play a fundamental role in magma petrogenesis and eruption dynamics. Mingling occurs most commonly when hot primitive magma is ...introduced into cooler magma. Here, we investigate a scenario whereby cool, partially degassed lava is drained back into a conduit, where it mingles with hotter, less degassed magma. The 1959 eruption of Kīlauea Iki, Hawaiʻi involved 16 high fountaining episodes. During each episode, fountains fed a lava lake in a pit crater, which then partially drained back into the conduit during and after each episode. We infer highly crystalline tachylite inclusions and streaks in the erupted crystal-poor scoria to be the result of the recycling of this drain-back lava. The crystal phases present are dendrites of plagioclase, augite and magnetite/ilmenite, at sizes of up to 10 µm. Host sideromelane glass contains 7–8 wt% MgO and the tachylite glass (up to 0.5% by area) contains 2.5–6 wt% MgO. The vesicle population in the tachylite is depleted in the smallest size classes (< 0.5 mm) and has overall lower vesicle number densities and a higher degree of vesicle coalescence than the sideromelane component. The tachylite exhibits increasingly complex ‘stretching and folding’ mingling textures through the episodes, with discrete blocky tachylite inclusions in episodes 1 and 3 giving way to complex, folded, thin filaments of tachylite in pyroclasts erupted in episodes 15 and 16. We calculate that a lava lake crust 8–35 cm thick may have formed in the repose times between episodes, and then foundered and been entrained into the conduit during drain-back. The recycled fragments of crust would have been reheated in the conduit, inducing glass devitrification and crystallisation of pyroxene, magnetite and plagioclase dendrites and eventually undergoing ductile flow as the temperature of the fragments approached the host magma temperature. We use simple models of magma mingling to establish that stretching and folding of recycled, ductile lava could involve thinning of the clasts by up to a factor of 10 during the timescale of the eruption, consistent with observations of streaks and filaments of tachylite erupted during episodes 15 and 16, which may have undergone multiple cycles of eruption, drain-back and reheating.
Deformation of the continental crust is influenced by the pre-existing structural framework, fluid availability, strain rate, and pressure-temperature conditions. We investigate the evolution of a ...large (hundreds-of-meters wide) heterogeneous shear zone and associated brittle and ductile deformation structures (Lofoten, Norway) using structural analysis, mineral-chemical and microstructural observations, and U-Pb dating. The shear zone developed through a sequence of metamorphic stages: (1) migmatization and granulite-facies metamorphism, (2) eclogite-facies metamorphism, and (3) amphibolite-facies metamorphism. Stage (1) was related to magmatic activity at lower-crustal conditions prior to 1.7 Ga. Stage (2) likely occurred during the early phases of the collision between Baltica and Laurentia (Caledonian collision). Stage (3) was related to shortening during the main phase of the Caledonian collision (∼430–400 Ma) and was accompanied by hydration of the shear zone. We demonstrate how mechanical heterogeneities influence the deformation style from the centimeter to meter scale. Zones with a pre-existing fabric deformed by ductile shearing and folding, whereas homogeneous, dry rocks fractured. Fractures provided precursors for small-scale shear zones. These contrasting deformation styles occurred repeatedly. Consequently, pre-existing structures define the deformation style and serve as conduits for the channelization of fluids over extended periods of time.
•Long-lived localization of metamorphism and deformation.•Cyclical brittle failure in a ductile shear zone.•Multiphase metamorphism of the Lofoten block (northern Norway).•Pre-existing structures serve as long-lived fluid pathways.
Plagioclase textures were investigated in the products of the voluminous 1783-1784 CE Laki eruption from the Eastern Volcanic Zone (EVZ) of Iceland to establish whether mush disaggregation occurred ...solely at the onset of the eight-month eruption or throughout its whole duration. Phase proportions and plagioclase size distributions were determined using standard optical and manual techniques as well as automated approaches based on Quantitative Evaluation of Minerals by SCANing electron microscopy (QEMSCAN). Based on optical microscopy and the explicit combination of textural and compositional information in QEMSCAN images, plagioclase crystals were divided into two populations: small (<0.5 mm long), high-aspect ratio (length/width >4) microcrysts with low-anorthite (<An80) cores; and large (>0.5 mm long), low-aspect ratio (length/width = 2-3) macrocrysts with high-anorthite (An84-An92) cores. Small microcrysts grew from their carrier liquid during the final phase of pre-eruptive crystallization while large macrocrysts, which are out of geochemical equilibrium with their carrier liquids, were entrained from crystal mushes. Changes in phase proportions and plagioclase size distributions between eruptive episodes demonstrate that macrocryst entrainment efficiency varied substantially during the eruption; material erupted in later episodes contain proportionally more mush-derived material. Using stereologically corrected plagioclase size distributions, we estimate that the pre-eruptive residence times of microcrysts in the Laki carrier liquid were probably of the order of 2-20 days. Because microcryst crystallization was concurrent with macrocryst rim growth, these day-to-week residence times also indicate that macrocryst entrainment occurred on much shorter timescales than the eruption's eight-month duration. In line with constraints from independent geochronometers, macrocryst entrainment and mush disaggregation thus appears to have continued throughout the eruption. Magmas were assembled on an episode by episode basis, and the volume of eruptible magma in the plumbing system at any given time was probably closer to 1-2 km3 than the final erupted volume of 15.1 km3.
A significant portion of the continental crust is composed of plutonic igneous rocks. However, little is known about the geochemical behaviour of N between the different minerals during magmatic ...differentiation. To provide new constraints for the behaviour of N during crust formation, we have characterised the geochemistry of nitrogen (N) in the compositionally zoned calc-alkaline pluton at Loch Doon, SW Scotland. We present N concentration and N isotope values for whole-rock data alongside biotite, plagioclase and K-feldspar mineral separates and assess the degree to which these data preserve equilibrium partitioning during magmatic differentiation. We show that whole rock likely inherited its N contents and δ15N signatures from the initial source composition and that this signature is homogenous at a pluton scale. Whilst the whole-rock data are best explained as crust-derived N in the source, the degree of homogenisation across a pluton scale is inconsistent with empirical N diffusivities, ruling out syn-emplacement crustal assimilation as the source of N. Instead, our data suggest a crustal signature inherited from depth associated with the Iapetus subduction zone. At a mineral scale, we find that N preferentially partitions into the feldspars over mica in this system in the order K-feldspar > plagioclase ≈ biotite > quartz, with average mineral–mineral distribution coefficients of DN plagioclase-biotite = 1.3 ± 0.6 and DN Kspar-biotite = 2.8 ± 0.6. Partitioning is accompanied by a large and near constant equilibrium isotope fractionation factor between biotite and both feldspars (averages are Δ15NPlag-Biotite = +7.8 ± 1.2‰ and Δ15NKspar-Biotite = +7.9 ± 1.0‰). In contrast, Δ15NKspar-Plagioclase closely approximates 0‰, where both minerals show δ15N values overlapping with the bulk rock δ15N values. These results show that mica crystallisation generates a 15N-depleted reservoir within plutonic rocks. Moreover, our dataset suggests that feldspars might be a more significant host of N in the igneous portion of Earth’s continental and oceanic crust than previously thought.
The eruptions of Eyjafjallajökull volcano in 2010 (including its initial effusive phase at Fimmvörðuháls and its later explosive phase from the central volcano) and Bárðarbunga volcano in 2014–2015 ...(at Holuhraun) were widely reported. Here, we report on complementary, interdisciplinary observations made of the eruptive gases and lavas that shed light on the processes and atmospheric impacts of the eruptions, and afford an intercomparison of contrasting eruptive styles and hazards. We find that (i) consistent with other authors, there are substantial differences in the gas composition between the eruptions; namely that the deeper stored Eyjafjallajökull magmas led to greater enrichment in Cl relative to S; (ii) lava field SO
2
degassing was measured to be 5–20% of the total emissions during Holuhraun, and the lava emissions were enriched in Cl at both fissure eruptions—particularly Fimmvörðuháls; and (iii) BrO is produced in Icelandic plumes in spite of the low UV levels.
For the purpose of geological carbon storage, it is necessary to understand the long-term effects of introducing CO2 and sulfur-species into saline aquifers. CO2 stripped from the flue gas during the ...carbon capture process may contain trace SO2 and H2S and it may be economically beneficial to inject S-bearing CO2 rather than costly purified CO2. Furthermore, reactions between the S-CO2-bearing formation brines and formation minerals will increase pH and promote further dissolution and precipitation reactions. To investigate this we model reactions in a natural analog where CO2- and SO4-H2S bearing fluids have reacted with clay-rich siltstones. In the Mid-Jurassic Carmel formation in a cap rock to a natural CO2-bearing reservoir at Green River, Utah, a 3.1 mm wide bleached alteration zone is observed at the uppermost contact between a primary gypsum bed and red siltstone. Gypsum at the contact is ∼1 mm thick and shows elongate fibers perpendicular to the siltstone surface, suggesting fluid flow along the contact. Mineralogical concentrations, analyzed by Quantitative Evaluation of Minerals by SCANning electron microscopy (QEMSCAN), show the altered siltstone region comprises two main zones: a 0.8 mm wide, hematite-poor, dolomite-poor, and illite-rich region adjacent to the gypsum bed; and a 2.3 mm wide, hematite-poor, dolomite-poor, and illite-poor region adjacent to the hematite alteration front. A one-component analytical solution to reactive-diffusive transport for the bleached zone implies it took less than 20 yr to form before the fluid self-sealed, and that literature hematite dissolution rates between 10-8 and 10-7 mol/m2/s are valid for likely diffusivities. Multi-component reactive-diffusive transport equilibrium modeling for the full phase assemblage, conducted with PHREEQC, suggests dissolution of hematite and dolomite and precipitation of illite over similar short timescales. Reaction progress with CO2-bearing, SO4-rich, and minor H2S-bearing fluids is shown to be much faster than with CO2-poor, SO4-rich with minor H2S-bearing fluids. The substantial buffering capacity of mineral reactions demonstrated by the S- and CO2-related alteration of hematite-bearing siltstones at the Green River CO2 accumulation implies that corrosion of such a cap rock are, at worst, comparable to the 10 000 yr timescales needed for carbon storage.
The 2015 eruption of Wolf volcano was one of the largest eruptions in the Galápagos Islands since the onset of routine satellite‐based volcano monitoring. It therefore provides an excellent ...opportunity to combine geophysical and petrological data, to place detailed constraints on the architecture and dynamics of subvolcanic systems in the western archipelago. We present new geodetic models that show that pre‐eruptive inflation at Wolf was caused by magma accumulation in a shallow flat‐topped reservoir at ~1.1 km, whereas edifice‐scale deformation during the eruption was related to a deflationary source at 6.1–8.8 km. Petrological observations suggest that the erupted material was derived from both a subvolcanic mush and a liquid‐rich magma body. Using a combination of olivine‐plagioclase‐augite‐melt (OPAM) and clinopyroxene‐melt barometry, we show that the majority of magma equilibration, crystallization, and mush entrainment occurred at a depth equal to or greater than the deep geodetic source, with little petrological evidence of material sourced from shallower levels. Hence, our multidisciplinary study does not support a fully transcrustal magmatic system beneath Wolf volcano before the 2015 eruption but instead indicates two discrete storage regions, with a small magma lens at shallow levels and the major zone of magma storage in the lower crust, from which most of the erupted material was sourced. A predominance of lower crustal magma storage has previously been thought typical of subvolcanic systems in the eastern Galápagos Archipelago, but our new data suggest that this may also occur beneath the more active volcanoes of the western archipelago.
Key Points
Combined geophysical and petrological constraints provide a detailed picture of the subvolcanic architecture at Wolf volcano
Wolf is underlain by two discrete magma storage regions: one within the edifice, the other in the lower crust
Almost all the magma ejected during the 2015 eruption of Wolf was derived from the lower crust
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