•Density functional theory and microkinetic modelling are used to quantitatively determine the activities of flat and stepped surfaces of both nickel and nickel carbide.•The coke formation ...probability is evaluated on each surface.•A deactivation scheme, which could be used to rationalise the activity and coke formation observed experimentally, is developed.
Dry reforming is a promising reaction to utilise the greenhouse gases CO2 and CH4. Nickel-based catalysts are the most popular catalysts for the reaction, and the coke formation on the catalysts is the main obstacle to the commercialisation of dry reforming. In this study, the whole reaction network of dry reformation on both flat and stepped nickel catalysts (Ni(111) and Ni(211)) as well as nickel carbide (flat: Ni3C(001); stepped: Ni3C(111)) is investigated using density functional theory calculations. The overall reaction energy profiles in the free energy landscape are obtained, and kinetic analyses are utilised to evaluate the activity of the four surfaces. By careful examination of our results, we find the following regarding the activity: (i) flat surfaces are more active than stepped surfaces for the dry reforming and (ii) metallic nickel catalysts are more active than those of nickel carbide, and therefore, the phase transformation from nickel to nickel carbide will reduce the activity. With respect to the coke formation, the following is found: (i) the coke formation probability can be measured by the rate ratio of CH oxidation pathway to C oxidation pathway (rCH/rC) and the barrier of CO dissociation, (ii) on Ni(111), the coke is unlikely to form, and (iii) the coke formations on the stepped surfaces of both nickel and nickel carbide can readily occur. A deactivation scheme, using which experimental results can be rationalised, is proposed.
Blazars at the Cosmic Dawn Paliya, Vaidehi S.; Ajello, M.; Cao, H.-M. ...
Astrophysical journal/The Astrophysical journal,
07/2020, Letnik:
897, Številka:
2
Journal Article
Recenzirano
Odprti dostop
The uncharted territory of the high-redshift (z 3) universe holds the key to understanding the evolution of quasars. In an attempt to identify the most extreme members of the quasar population, that ...is, blazars, we have carried out a multiwavelength study of a large sample of radio-loud quasars beyond z = 3. Our sample consists of nine γ-ray-detected blazars and 133 candidate blazars selected based on the flatness of their soft X-ray spectra (0.3-10 keV photon index ≤1.75), including 15 with Nuclear Spectroscopic Telescope Array (NuSTAR) observations. The application of the likelihood profile stacking technique reveals that the high-redshift blazars are faint γ-ray emitters with steep spectra. The high-redshift blazars host massive black holes ( ) and luminous accretion disks ( erg s−1). Their broadband spectral energy distributions are found to be dominated by high-energy radiation, indicating their jets are among the most luminous ones. Focusing on the sources exhibiting resolved X-ray jets (as observed with the Chandra satellite), we find the bulk Lorentz factor to be larger with respect to other z > 3 blazars, indicating faster moving jets. We conclude that the presented list of high-redshift blazars may act as a reservoir for follow-up observations, such as with NuSTAR, to understand the evolution of relativistic jets at the dawn of the universe.
Trapped ions constitute one of the most promising systems for implementing quantum computing and networking1,2. For large-scale ion-trap-based quantum computers and networks, it is critical to have ...two types of qubit: one for computation and storage, and another for auxiliary operations such as qubit detection3, sympathetic cooling4–7 and entanglement generation through photon links8,9. Although the two qubit types can be implemented using two different ion species3,10–13, this approach introduces substantial complexity into creating and controlling each qubit type14,15. Here we resolve these challenges by implementing two coherently convertible qubit types using one ion species. We encode the qubits into two pairs of clock states of the 171Yb+ ions, and achieve microsecond-level conversion rates between the two types with one-way fidelities of 99.5%. We further demonstrate that operations on one qubit type, including sympathetic laser cooling, single-qubit gates and qubit detection, have crosstalk errors less than 0.06% on the other type, which is below the best-known error threshold of ~1% for fault-tolerant quantum computing using the surface code1,16. Our work establishes the feasibility and advantages of using coherently convertible dual-type qubits with the same ion species for large-scale quantum computing and networking.Quantum computing with trapped ions requires qubits that can store and manipulate quantum information, and others that can be used for destructive incoherent operations. Different states of ytterbium-171 ions can be used to realize both qubit types
Non-Hermitian systems generically have complex energies, which may host topological structures, such as links or knots. While there has been great progress in experimentally engineering non-Hermitian ...models in quantum simulators, it remains a significant challenge to experimentally probe complex energies in these systems, thereby making it difficult to directly diagnose complex-energy topology. Here, we experimentally realize a two-band non-Hermitian model with a single trapped ion whose complex eigenenergies exhibit the unlink, unknot, or Hopf link topological structures. Based on non-Hermitian absorption spectroscopy, we couple one system level to an auxiliary level through a laser beam and then experimentally measure the population of the ion on the auxiliary level after a long period of time. Complex eigenenergies are then extracted, illustrating the unlink, unknot, or Hopf link topological structure. Our work demonstrates that complex energies can be experimentally measured in quantum simulators via non-Hermitian absorption spectroscopy, thereby opening the door for exploring various complex-energy properties in non-Hermitian quantum systems, such as trapped ions, cold atoms, superconducting circuits, or solid-state spin systems.
Context.
IceCube has reported a very-high-energy neutrino (IceCube-170922A) in a region containing the blazar
TXS 0506+056
. Correlated gamma-ray activity has led to the first high-probability ...association of a high-energy neutrino with an extragalactic source. This blazar has been found to be in a radio outburst during the neutrino event.
Aims.
Our goal is to probe the sub-milliarcsecond properties of the radio jet right after the neutrino detection and during the further evolution of the radio outburst.
Methods.
We performed target of opportunity observations at 43 GHz frequency using very long baseline interferometry imaging, corresponding to 7 mm in wavelength, with the Very Long Baseline Array two and eight months after the neutrino event.
Results.
We produced two images of the radio jet of TXS 0506+056 at 43 GHz with angular resolutions of (0.2 × 1.1) mas and (0.2 × 0.5) mas, respectively. The source shows a compact, high brightness temperature core, albeit not approaching the equipartition limit and a bright and originally very collimated inner jet. Beyond approximately 0.5 mas from the millimeter-VLBI core, the jet loses this tight collimation and expands rapidly. During the months after the neutrino event associated with this source, the overall flux density is rising. This flux density increase happens solely within the core. Notably, the core expands in size with apparent superluminal velocity during these six months so that the brightness temperature drops by a factor of three despite the strong flux density increase.
Conclusions.
The radio jet of TXS 0506+056 shows strong signs of deceleration and/or a spine-sheath structure within the inner 1 mas, corresponding to about 70–140 pc in deprojected distance, from the millimeter-VLBI core. This structure is consistent with theoretical models that attribute the neutrino and gamma-ray production in TXS 0506+056 to interactions of electrons and protons in the highly relativistic jet spine with external photons originating from a slower moving jet region. Proton loading due to jet-star interactions in the inner host galaxy is suggested as the possible cause of deceleration.
Organ-on-A-chip (OoAC) devices are miniaturized, functional, in vitro constructs that aim to recapitulate the in vivo physiology of an organ using different cell types and extracellular matrix, while ...maintaining the chemical and mechanical properties of the surrounding microenvironments. From an end-point perspective, the success of a microfluidic OoAC relies mainly on the type of biomaterial and the fabrication strategy employed. Certain biomaterials, such as PDMS (polydimethylsiloxane), are preferred over others due to their ease of fabrication and proven success in modelling complex organ systems. However, the inherent nature of human microtissues to respond differently to surrounding stimulations has led to the combination of biomaterials ranging from simple PDMS chips to 3D-printed polymers coated with natural and synthetic materials, including hydrogels. In addition, recent advances in 3D printing and bioprinting techniques have led to the powerful combination of utilizing these materials to develop microfluidic OoAC devices. In this narrative review, we evaluate the different materials used to fabricate microfluidic OoAC devices while outlining their pros and cons in different organ systems. A note on combining the advances made in additive manufacturing (AM) techniques for the microfabrication of these complex systems is also discussed.
The strong spectral dependence of light absorption of brown carbon (BrC) aerosol is regarded to influence aerosol's radiative forcing significantly. The Absorption Angstrom Exponent (AAE) method has ...been widely used in previous studies to attribute light absorption of BrC at shorter wavelengths for ambient aerosols, with a theoretical assumption that the AAE of "pure" black carbon (BC) aerosol equals to 1.0. In this study, the AAE method was applied to both urban and rural environments in the Pearl River Delta (PRD) region of China, with an improvement of constraining the realistic AAE of "pure" BC through statistical analysis of on-line measurement data. A three-wavelength photo-acoustic soot spectrometer (PASS-3) and aerosol mass spectrometers (AMS) were used to explore the relationship between the measured AAE and the relative abundance of organic aerosol to BC. The regression and extrapolation analysis revealed that more realistic AAE values for "pure" BC aerosol (AAEBC) were 0.86, 0.82, and 1.02 between 405 and 781 nm, and 0.70, 0.71, and 0.86 between 532 and 781 nm, in the campaigns of urbanwinter, urbanfall, and ruralfall, respectively. Roadway tunnel experiments were conducted and the results further confirmed the representativeness of the obtained AAEBC values for the urban environment. Finally, the average light absorption contributions of BrC ( relative uncertainties) at 405 nm were quantified to be 11.7 % ( 5 %), 6.3 % ( 4 %), and 12.1 % ( 7 %) in the campaigns of urbanwinter, urbanfall, and ruralfall, respectively, and those at 532 nm were 10.0 % ( 2 %), 4.1 % ( 3 %), and 5.5 % ( 5 %), respectively. The relatively higher BrC absorption contribution at 405 nm in the ruralfall campaign could be reasonably attributed to the biomass burning events nearby, which was then directly supported by the biomass burning simulation experiments performed in this study. This paper indicates that the BrC contribution to total aerosol light absorption at shorter wavelengths is not negligible in the highly urbanized and industrialized PRD region.
Quaternary kesterite-type Cu2ZnSnS4 (CZTS) nanoparticles for low-cost thin film solar cell were successfully synthesised using a relatively simple and convenient solvothermal route. Nanoparticles ...with diameters of about 5–10nm were obtained at the temperature of 180°C, analyzed by transmission electron microscopy (TEM). The morphologies of the continuous CZTS films with satisfactory stoichiometry were characterized by scanning electron microscopy (SEM) and energy dispersive X-ray analysis (EDXA). The crystallinity of CZTS nanoparticles was greatly improved by annealing in H2S (5%)/Ar mixed gases analyzed by X-ray diffraction (XRD). High-resolution X-ray photo-emission spectroscopy (XPS) analysis of the four constituent elements confirmed the purity and composition of CZTS nanoparticles. UV–vis absorption spectra measurement indicated that the band gap of as-synthesised CZTS nanoparticles was about 1.5eV, which was near the optimum value for photovoltaic solar conversion in a single-band-gap device.
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