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•A variety of approaches for the extraction of lipids from microalgae were reviewed.•The bioactivity of microalgae lipids is summarized.•Innovative techniques have advantages in ...improving yield and reducing pollution.
Microalgae, as a photosynthetic autotrophic organism, contain a variety of bioactive compounds, including lipids, proteins, polysaccharides, which have been applied in food, medicine, and fuel industries, among others. Microalgae are considered a good source of marine lipids due to their high content in unsaturated fatty acid (UFA) and can be used as a supplement/replacement for fish-based oil. The high concentration of docosahexaenoic (DHA) and eicosapentaenoic acids (EPA) in microalgae lipids, results in important physiological functions, such as antibacterial, anti-inflammatory, and immune regulation, being also a prerequisite for its development and application. In this paper, a variety of approaches for the extraction of lipids from microalgae were reviewed, including classical and innovative approaches, being the advantages and disadvantages of these methods emphasized. Further, the effects of microalgae lipids as high value bioactive compounds in human health and their use for several applications are dealt with, aiming using green(er) and effective methods to extract lipids from microalgae, as well as develop and extend their application potential.
Emerging pollutants represent a new global problem for water quality. As these compounds get into the environment, they cause severe threats to aquatic environments and human health and are typically ...resistant to conventional wastewater treatments. In this work, TiO2 nanoparticles surface was functionalized with silver (Ag) nanoparticles, and solvent cast and electrospun membranes of poly (vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) were prepared with different concentrations of TiO2 and Ag–TiO2 to produce a multifunctional material. The photocatalytic activity of the nanocomposites was evaluated through the degradation of norfloxacin under ultraviolet (UV) and visible radiation. It is shown that nanocomposites with Ag–TiO2 show the highest degradation efficiencies: 64.2% under UV and 80.7% under visible radiation, for 90 and 300 min, respectively.
Furthermore, the recyclability of the membranes has also been demonstrated. Finally, it is shown the antimicrobial activity of the nanocomposite membranes, demonstrating the suitability of the Ag–TiO2/PVDF-HFP nanocomposites as multifunctional photocatalytic and antimicrobial membranes for water remediation applications.
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•Synthesis of Ag–TiO2 nanocomposites with ability to absorb visible radiation.•Production of Ag–TiO2/PVDF-HFP membranes with different morphologies.•Photocatalytic efficiency tested with norfloxacin under visible and UV radiation.•Antimicrobial tests were performed against two bacteria species (gram + and gram -).
Summary
Soil nutrient availability can strongly affect root traits. In tropical forests, phosphorus (P) is often considered the main limiting nutrient for plants. However, support for the P paradigm ...is limited, and N and cations might also control tropical forests functioning.
We used a large‐scale experiment to determine how the factorial addition of nitrogen (N), P and cations affected root productivity and traits related to nutrient acquisition strategies (morphological traits, phosphatase activity, arbuscular mycorrhizal colonisation and nutrient contents) in a primary rainforest growing on low‐fertility soils in Central Amazonia after 1 yr of fertilisation.
Multiple root traits and productivity were affected. Phosphorus additions increased annual root productivity and root diameter, but decreased root phosphatase activity. Cation additions increased root productivity at certain times of year, also increasing root diameter and mycorrhizal colonisation. P and cation additions increased their element concentrations in root tissues. No responses were detected with N addition.
Here we showed that rock‐derived nutrients determined root functioning in low‐fertility Amazonian soils, demonstrating not only the hypothesised importance of P, but also highlighting the role of cations. The changes in fine root traits and productivity indicated that even slow‐growing tropical rainforests can respond rapidly to changes in resource availability.
This work focuses on the combination of multifunctional photocatalytic and adsorbent materials in a unique polymeric membrane. For this purpose, Au/TiO2 and Y2(CO3)3 nanoparticles were immobilised ...onto a poly (vinylidene fluoride-hexafluoropropylene), (PVDF-HFP) membrane, and the physical-chemical characterisation of these materials was performed, as well as pollutant removal efficiency. An efficient TiO2 functionalisation with gold nanoparticles was achieved, endowing these particles with the capability to absorb visible radiation absorption. A favourable porous structure was obtained for the membranes, with an average pore size of 4 μm, and the nanoparticles immobilisation did not alter the chemical properties of the polymeric membrane. The produced hybrid materials, including both the Au/TiO2 and Y2(CO3)3 nanoparticles, presented an efficiency of 57% in the degradation of norfloxacin (5 mg/L) under ultraviolet radiation for 120 min, 80% under visible radiation for 300 min, and 58% in arsenic adsorption for 240 min. These membranes represent a new multifunctional platform for removing several pollutants, which may allow their incorporation in more efficient and less energy-consuming water treatment processes favouring its application, even in low energy resources countries.
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•Synthesis of Au–TiO2 nanocomposites with ability to absorb visible radiation.•Production of porous multifunctional Au–TiO2/Yttrium/PVDF-HFP membranes.•Photocatalytic and adsorptive efficiency tested in norfloxacin and arsenic removal.•Multifunctional tests performed for simultaneous photocatalysis and adsorption.
The strong intervening absorption system at redshift 1.15 towards the very bright quasar HE 0515−4414 is the most studied absorber for measuring possible cosmological variations in the fine-structure ...constant,
α
. We observed HE 0515−4414 for 16.1 h with the Very Large Telescope and present here the first constraint on relative variations in
α
with parts-per-million (ppm) precision from the new ESPRESSO spectrograph: Δ
α
/
α
= 1.3 ± 1.3
stat
± 0.4
sys
ppm. The statistical uncertainty (1
σ
) is similar to the ensemble precision of previous large samples of absorbers and derives from the high signal-to-noise ratio achieved (≈105 per 0.4 km s
−1
pixel). ESPRESSO’s design, and the calibration of our observations with its laser frequency comb, effectively removed wavelength calibration errors from our measurement. The high resolving power of our ESPRESSO spectrum (
R
= 145 000) enabled the identification of very narrow components within the absorption profile, allowing a more robust analysis of Δ
α
/
α
. The evidence for the narrow components is corroborated by their correspondence with previously detected molecular hydrogen and neutral carbon. The main remaining systematic errors arise from ambiguities in the absorption profile modelling, effects from redispersing the individual quasar exposures, and convergence of the parameter estimation algorithm. All analyses of the spectrum, including systematic error estimates, were initially blinded to avoid human biases. We make our reduced ESPRESSO spectrum of HE 0515−4414 publicly available for further analysis. Combining our ESPRESSO result with 28 measurements, from other spectrographs, in which wavelength calibration errors have been mitigated yields a weighted mean Δ
α
/
α
= −0.5 ± 0.5
stat
± 0.4
sys
ppm at redshifts 0.6−2.4.
Observations of the redshift
= 7.085 quasar J1120+0641 are used to search for variations of the fine structure constant, a, over the redshift range 5:5 to 7:1. Observations at
= 7:1 probe the physics ...of the universe at only 0.8 billion years old. These are the most distant direct measurements of a to date and the first measurements using a near-IR spectrograph. A new AI analysis method is employed. Four measurements from the x-shooter spectrograph on the Very Large Telescope (VLT) constrain changes in a relative to the terrestrial value (α
). The weighted mean electromagnetic force in this location in the universe deviates from the terrestrial value by Δα/α = (α
- α
)/α
= (-2:18 ± 7:27) × 10
, consistent with no temporal change. Combining these measurements with existing data, we find a spatial variation is preferred over a no-variation model at the 3:9σ level.
Photocatalytic processes based on titanium dioxide (TiO2) nanoparticles have attracted increasing attention in the last decades. However, approaches based on nanoparticles show some drawbacks, in ...particular due to the need for expensive and time consuming post-treatment of nanoparticles filtration/separation. This hindrance demands the development of immobilized configurations with tailored properties, as an alternative to allow simple recovery of the photocatalytic particles. Thus, this work reports on the development of photocatalytic membranes based on TiO2 nanoparticles immobilized into a poly(vinylidenefluoride-trifluoroethylene) (P(VDF-TrFE)) membrane and the comparative study of their performance with dispersed TiO2 nanoparticles. Photocatalytic nanocomposite membranes with a highly porous structure ( similar to 75%) and controlled wettability by NaY addition were successfully produced. These properties were paramount to achieve a methylene blue degradation efficiency of 96% in 40 min under ultraviolet (UV) irradiation, corresponding to an efficiency loss of just 3% regarding the TiO2 nanoparticle assays.
We have constrained the spatial variation of the fine structure constant using multi-frequency measurements of the thermal Sunyaev-Zeldovich effect of 618 X-ray selected clusters. Although our ...results are not competitive with the ones from quasar absorption lines, we improved by a factor 10 and ∼2.5 previous results from Cosmic Microwave Background power spectrum and from galaxy clusters, respectively.
Due to its characteristics, fresh fish is a highly perishable food with a very short shelf-life under refrigeration. Several methods have been introduced to slow down its deterioration, such as by ...means of oxygen depletion of the food package (vacuum packaging), or by changing the natural atmosphere that is in contact with the fresh fish (modified atmosphere packaging), or by the use of chemicals generally recognized as safe: such compounds can be directly applied (by dipping or spraying) or incorporated into packaging materials and slowly migrate to the product, exerting a hurdle effect against microbial development and lipid oxidation (active packaging). This review aims to cover the most recent advances in chemical-based approaches for fresh fish preservation, applied either singly or in combination. Vacuum packaging, modified atmosphere, and active packaging preservation methodologies are presented, along with the inclusion of chemical additives, such as organic acids and natural extracts, and their combination with icing systems. Advantages and disadvantages of these methodologies and their impact on fresh fish quality and shelf-life are discussed, reaching the conclusion that both are positively influenced overall. Indeed, the contribution of chemical-based strategies for fresh fish preservation is undeniable, and is expected to be a research topic of increasing interest in the future.
Purpose
Large parts of the Amazon rainforest grow on weathered soils depleted in phosphorus and rock-derived cations. We tested the hypothesis that in this ecosystem, fine roots stimulate ...decomposition and nutrient release from leaf litter biochemically by releasing enzymes, and by exuding labile carbon stimulating microbial decomposers.
Methods
We monitored leaf litter decomposition in a Central Amazon tropical rainforest, where fine roots were either present or excluded, over 188 days and added labile carbon substrates (glucose and citric acid) in a fully factorial design. We tracked litter mass loss, remaining carbon, nitrogen, phosphorus and cation concentrations, extracellular enzyme activity and microbial carbon and nutrient concentrations.
Results
Fine root presence did not affect litter mass loss but significantly increased the loss of phosphorus and cations from leaf litter. In the presence of fine roots, acid phosphatase activity was 43.2% higher, while neither microbial stoichiometry, nor extracellular enzyme activities targeting carbon- and nitrogen-containing compounds changed. Glucose additions increased phosphorus loss from litter when fine roots were present, and enhanced phosphatase activity in root exclusions. Citric acid additions reduced litter mass loss, microbial biomass nitrogen and phosphorus, regardless of fine root presence or exclusion.
Conclusions
We conclude that plant roots release significant amounts of acid phosphatases into the litter layer and mobilize phosphorus without affecting litter mass loss. Our results further indicate that added labile carbon inputs (
i.e
. glucose) can stimulate acid phosphatase production by microbial decomposers, highlighting the potential importance of plant-microbial feedbacks in tropical forest ecosystems.
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