Over the past twenty years, numerous research outcomes have been published, related to the design and implementation of soft sensors. In modern industrial processes, various types of soft sensors are ...used, which play essential roles in process monitoring, control and optimization. Emerging new theories, advanced techniques and the information infrastructure have enabled the elevation of the performance of soft sensing. However, novel opportunities are accompanied by novel challenges. This work is motivated by these observations and aims to present a comprehensive review of the developments since the start of the millennium. While a few books and review articles are published on the related topics, more focus on the most up-to-the-date advancement is put in this work, from the perspective of systems and control.
Polyanion-type Li2FeSiO4 has been considered as an advanced positive material for lithium energy storage owing to the low cost, good safety and high theoretical capacity. Unfortunately, the inferior ...electrical conductivity and bad diffusivity of Li+ inhibit its widespread applications for lithium energy storage. In the present research, we have used the simple spray-drying route to fabricate the three-dimensional carbon nanotubes (3D CNTs) encapsulated Li2FeSiO4 microspheres (3D-Li2FeSiO4/CNTs). Benefiting from the interconnected conducting networks, the as-fabricated 3D-Li2FeSiO4/CNTs cathode displays superior battery property with a specific capacity of 169.1 mAh g−1 at 0.1C. Besides, it also delivers a discharge capacity of 104.1 mAh g−1 at 5C over 500 cycles with a capacity retention ratio of around 91.2%. The above results suggest that the designed 3D-Li2FeSiO4/CNTs composite is an advanced positive material in lithium energy storage.
The direction estimation of the coherent source in a uniform circular array is an essential part of the signal processing area of the array, but the traditional uniform circular array algorithm has a ...low localization accuracy and a poor localization effect on the coherent source. To solve this problem, this paper proposes a two-dimensional direction of arrival (DOA) estimation for the coherent source in broadband. Firstly, the central frequency of the coherent sound source is estimated using the frequency estimation method of the delayed data, and a real-valued beamformer is constructed using the concept of the multiloop phase mode. Then, the cost function in the beam space is obtained. Finally, the cost function is searched in two dimensions to locate the sound source. In this paper, we simulate the DOA of the sound source at different frequencies and signal-to-noise ratios and analyze the resolution of the circular array. The simulation results show that the proposed algorithm can estimate the direction of arrival with high precision and achieve the desired results.
Band structure dictates optical and electronic properties of solids and eventually the efficiency of the semiconductor based solar conversion. Compared to numerous theoretical calculations, the ...experimentally measured band structure of rutile TiO2, a prototypical photocatalytic material, is rare. In this work, the valence band structure of rutile TiO2(110) is measured by angle-resolved photoelectron spectroscopy using polarized extreme ultraviolet light. The effective mass of the hole, which has never been measured before, is determined to be 4.66–6.87 m 0 (free electron mass) and anisotropic. The dependence of photoemission intensities on excitation light polarization is analyzed by taking into account of the parity symmetry of molecular orbitals in the blocking unit of rutile TiO2. This work reports a direct measurement of valence band structure and hole effective mass of rutile TiO2(110), which will deepen our understanding of the electronic structure and charge carrier properties of the model material and provide reference data for future theoretical calculations.
The high penetration of renewable energy resources and power electronic-based components has led to a low-inertia power grid which would bring challenges to system operations. The new model of load ...frequency control (LFC) must be able to handle the modern scenario where controlled areas are interconnected by parallel AC/HVDC links and storage devices are added to provide virtual inertia. Notably, vulnerabilities within the communication channels for wide-area data exchange in LFC loops may make them exposed to various cyber attacks, while it still remains largely unexplored how the new LFC in the AC/HVDC interconnected system with emulated inertia would be affected under malicious intrusions. Thus, in this article, we are motivated to explore possible effects of the major types of data availability and integrity attacks—Denial of Service (DoS) and false data injection (FDI) attacks—on such a new LFC system. By using a system-theoretic approach, we explore the optimal strategies that attackers can exploit to launch DoS or FDI attacks to corrupt the system stability. Besides, a comparison study is performed to learn the impact of these two types of attacks on LFC models of power systems with or without HVDC link and emulated inertia. The simulation results on the the exemplary two-area system illustrate that both DoS and FDI attacks can cause large frequency deviations or even make the system unstable; moreover, the LFC system with AC/HVDC interconnections and emulated inertia could be more vulnerable to these two types of attacks in many adversarial scenarios.
We investigate black phosphorus by time- and angle-resolved photoelectron spectroscopy. The electrons excited by 1.57 eV photons relax down to a conduction band minimum within 1 ps. Despite the low ...band gap value, no relevant amount of carrier multiplication could be detected at an excitation density 3–6 × 1019 cm–3. In the thermalized state, the band gap renormalization is negligible up to a photoexcitation density that fills the conduction band by 150 meV. Astonishingly, a Stark broadening of the valence band takes place at an early delay time. We argue that electrons and holes with a high excess energy lead to inhomogeneous screening of near surface fields. As a consequence, the chemical potential is no longer pinned in a narrow impurity band.
Abstract
Previous studies have documented that Chlorella sorokiniana could grow well on cooking cocoon wastewater (CCW) with a maximum biomass of 0.49 g/L. In order to further enhance the biomass ...production and nutrient removals, a bubble-column bioreactor was designed and performed to cultivate C. sorokiniana in CCW, and two main cultivation parameters were investigated in this work. Results showed that a maximum algal biomass, specific growth rate, and biomass productivity of 2.83 g/L, 0.854 d−1, and 476.25 g/L/d, respectively, were achieved when this alga was cultivated in the bioreactor with an initial cell density of 0.8 g/L and an aeration rate of 3.34 L air/L culture/min; meanwhile, removal efficiencies of ammonium, total nitrogen, total phosphorus, and chemical oxygen demand reached 97.96, 85.66, 97.96, and 86.43%, respectively, which were significantly higher than that obtained in our previous studies. Moreover, chemical compositions in the algal cells varied with the changes of cultivation conditions (i.e., initial cell density and aeration rate). Thus, it is concluded that (1) the bubble-column bioreactor was suitable for cultivation of C. sorokiniana coupled with the CCW treatment and (2) initial cell density and aeration rate affected the biomass production, nutrient removals and chemical compositions of this alga.
Ionic liquids (ILs) have been reported to be a potential water and soil pollutant, whose toxicity has gained much attention in recent years. In this work, silkworm larvae were used as a novel in vivo ...model to assess the biotoxicity of ILs, which were performed by three steps. The first step was to determine the susceptibility of different silkworm strains to ILs. Data showed that Jingsong×haoyue was the most susceptible one among three silkworm strains (Jingsong×haoyue, P50, and Yi16) for evaluating the biological effects of ILs. The second step was to compare the toxicity of ILs with different structures using the larvae of Jingsong×haoyue. It was found that three representative ILs, 1-octyl-3-methylimidazole chloride (C8mimCl), N-octyl-3-methylpyridine chloride (C8mpyCl), and 1-octyl-3-methylimidazole tetrafluoroborate (C8mimBF4), had significant toxic effects on the growth and development of the larvae with 24 h median lethal concentration (24 h-LC50) values of 112.3, 156.3, and 68.9 μg g−1, respectively, indicating that the types of anions and cations had impacts on the toxicity of ILs. The last step was targeted at investigating responses of the larvae to the exposure of ILs. It was observed that remarkable physiological and biochemical responses occurred in different tissues of the larvae. For example, activities of superoxide dismutase (SOD), catalase (CAT), and peroxidase (POD) in different tissues increased significantly to form an active protective mechanism for alleviating the toxic effects of ILs. Additionally, an increase of malondialdehyde (MDA) contents was found in the larvae. The data suggested that ILs could induce lipid peroxidation and cellular damage, which may be the main reason for toxicity of ILs to the larvae. Therefore, silkworm larvae could be used as a susceptible and reliable in vivo model to evaluate the toxicity of ILs, and the results are helpful to reveal their toxic mechanism to insects.
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•Toxicity of ionic liquids (ILs) to silkworm larvae was firstly investigated.•Jingsong×haoyue was the most susceptible strain among three silkworm strains.•Types of anions and cations had impacts on the toxicity of ILs to silkworm larvae.•ILs could induce the silkworm midguts to produce pathological changes.•ILs triggered the regulation of antioxidant defense mechanisms in silkworm tissues.
In a previous study, silkworm larvae were used as a novel model to assess the biotoxicity of ILs, which showed that ILs could cause significant physiological and biochemical changes in midguts and ...silk glands of the larvae, and result in the death of larvae. In order to investigate the toxicity of 1-octyl-3-methylimidazole chloride (C8mimCl) to the larvae at molecular level, RNA-sequencing technology was used to construct transcriptomic profiles of midguts and silk glands in this work. Results showed that a lot of differentially expressed genes (DEGs) were effectively screened out through bioinformatics software based on the transcriptome data and reference genome. To give more detail, 5118 and 2211 DEGs (926 and 822 DEGs) were obtained in the midguts (silk glands) when the larvae were exposed to C8mimCl for 6 and 12 h, respectively, relative to the controls. In addition, gene ontology (GO) analysis suggested that the DEGs could be divided into three categories (i.e., biological process, cellular component, and molecular function), and were involved in multiple organelle functions and complex biological processes. Kyoto encyclopedia of genes and genomes (KEGG) analysis showed that the DEGs were enriched in a variety of pathways, such as signal transduction, apoptosis, glycolysis, peroxisome, autophagy, hippo signaling pathway, arginine and proline metabolism. Results of quantitative real-time PCR and histopathological observation indicated that molecular mechanism of the larvae against C8mimCl toxicology may be attributed to cell apoptosis regulation via both the mitochondrial pathway and the death receptor-initiated pathway. Thus, these results provided useful data for exploring the toxicity of ILs to insects at molecular level.
•Toxicity of C8mimCl to silkworm larvae was first reported at molecular level.•C8mimCl affected the morphology and structure of midguts and silk glands.•We constructed a transcriptome library of the larvae exposed to C8mimCl.•Lots of differentially expressed genes (DEGs) were obtained in this work.•The DEGs were involved in multiple biological processes and pathways.
Stacking order plays a crucial role in determining the crystal symmetry and has significant impacts on electronic, optical, magnetic, and topological properties. Electron-phonon coupling, which is ...central to a wide range of intriguing quantum phenomena, is expected to be intricately connected with stacking order. Understanding the stacking order-dependent electron-phonon coupling is essential for understanding peculiar physical phenomena associated with electron-phonon coupling, such as superconductivity and charge density waves. In this study, we investigate the effect of stacking order on electron-infrared phonon coupling in graphene trilayers. By using gate-tunable Raman spectroscopy and excitation frequency-dependent near-field infrared nanoscopy, we show that rhombohedral ABC-stacked trilayer graphene has a significant electron-infrared phonon coupling strength. Our findings provide novel insights into the superconductivity and other fundamental physical properties of rhombohedral ABC-stacked trilayer graphene, and can enable nondestructive and high-throughput imaging of trilayer graphene stacking order using Raman scattering.
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