•Techniques used for the measurement of thermal conductivity are reviewed.•A steady state instrument designed to measure the thermal conductivity is presented along with the measurement ...theory.•Tested on helium and KNO3NaNO3 molten salt from 300 °C to 500 °C.•Effects of convection and radiation were mitigated using this technique.•Conductive heat losses will need to be minimized to extend operability above 500 °C.
High-temperature fluids such as molten salts, liquid metals, and gasses are being proposed for many advanced energy systems including thermal energy storage devices, concentrating solar plants, and advanced nuclear reactor designs. However, the chemical behavior and thermophysical properties of many of these fluids have not been well characterized, which hinders the design, modeling, safety analysis, and deployment of these systems. Thermal conductivity is a property that is especially limited by existing measurement capabilities, which are subject to errors caused by convection, material interaction, radiative heat transfer, and instrument degradation. Therefore, there is a lack of standard, systematic measurement techniques for high-temperature, reactive, and corrosive fluids. In this work, the development of a variable gap thermal conductivity measurement system is detailed. The system is designed to measure the thermal conductivity of highly corrosive and reactive fluids, and survive operation between 100 °C and 800 °C. The effects of convection are minimized by limiting the thickness of the specimen to thin sizes (<0.3 mm). Corrections for radiative heat transfer were included in the working equations to consider specimens with varying optical properties. The design, construction, instrumentation, operating principles, and data analysis techniques are discussed in detail. The system was tested up to 500 °C using helium gas and molten KNO3NaNO3 to verify the measurement technique and determine the sources of error. At 300 and 400 °C KNO3NaNO3, results showed maximum relative error of 6% when compared to results in the literature. The helium results were within 13% of those in the literature at 300 and 400 °C. Higher errors were observed at 500 °C for both fluids, and the sources of these errors are discussed.
We describe the details of a silicon–tungsten prototype electromagnetic calorimeter module and associated readout electronics. Detector performance for this prototype has been measured in test beam ...experiments at the CERN PS and SPS accelerator facilities in 2015/16. The results are compared to those in Monte Carlo Geant4 simulations. This is the first real-world demonstration of the performance of a custom ASIC designed for fast, lower-power, high-granularity applications.
Here, we describe the details of a silicon–tungsten prototype electromagnetic calorimeter module and associated readout electronics. Detector performance for this prototype has been measured in test ...beam experiments at the CERN PS and SPS accelerator facilities in 2015/16. The results are compared to those in Monte Carlo Geant4 simulations. This is the first real-world demonstration of the performance of a custom ASIC designed for fast, lower-power, high-granularity applications.
Motor vehicles are among the major sources of pollutants and greenhouse gases in urban areas and a transition to "zero emission vehicles" is underway worldwide. However, emissions associated with ...brake and tire wear will remain. We show here that previously unrecognized volatile and semi-volatile organic compounds, which have a similarity to biomass burning emissions are emitted during braking. These include greenhouse gases or, these classified as Hazardous Air Pollutants, as well as nitrogen-containing organics, nitrogen oxides and ammonia. The distribution and reactivity of these gaseous emissions are such that they can react in air to form ozone and other secondary pollutants with adverse health and climate consequences. Some of the compounds may prove to be unique markers of brake emissions. At higher temperatures, nucleation and growth of nanoparticles is also observed. Regions with high traffic, which are often disadvantaged communities, as well as commuters can be impacted by these emissions even after combustion-powered vehicles are phased out.
Molten salt reactors offer a wide range of potential benefits but pose some unique challenges, particularly for designs that use an unclad liquid salt fuel. This type of fuel will result in the ...transport of fission gases into the headspace of the reactor where in some designs a cover gas can be circulated to remove certain fission products and maintain an inert atmosphere. The cover gas leaving the reactor core is expected to contain both noble and non-noble gases, aerosols, volatile species, tritium, radionuclides, and their daughters. To remove these radioactive gases, it is necessary to develop a robust off-gas system for molten salt–fueled reactors. Various treatment systems must be staged in series to remove the off-gas constituents from the stream before recirculating the gas back to the headspace of the reactor. Treatment options vary greatly depending on what they are designed to remove from the gas stream. This paper reviews the anticipated composition of a typical molten salt reactor off-gas stream and subsequently the available resources that could be employed to remove these species from the gas stream. An example off-gas system is then detailed, along with important design considerations, exemplifying the necessity for high-fidelity modeling. Lastly, the need for further thermophysical property research and the employment of advanced sensor technology for treatment component testing are discussed.
We describe the details of a silicon-tungsten prototype electromagnetic calorimeter module and associated readout electronics. Detector performance for this prototype has been measured in test beam ...experiments at the CERN PS and SPS accelerator facilities in 2015/16. The results are compared to those in Monte Carlo Geant4 simulations. This is the first real-world demonstration of the performance of a custom ASIC designed for fast, lower-power, high-granularity applications.
The importance of using dedicated high-end computing resources to enable high spatial resolution in global climate models and advance knowledge of the climate system has been evaluated in an ...international collaboration called Project Athena. Inspired by the World Modeling Summit of 2008 and made possible by the availability of dedicated high-end computing resources provided by the National Science Foundation from October 2009 through March 2010, Project Athena demonstrated the sensitivity of climate simulations to spatial resolution and to the representation of subgrid-scale processes with horizontal resolutions up to 10 times higher than contemporary climate models. While many aspects of the mean climate were found to be reassuringly similar, beyond a suggested minimum resolution, the magnitudes and structure of regional effects can differ substantially. Project Athena served as a pilot project to demonstrate that an effective international collaboration can be formed to efficiently exploit dedicated supercomputing resources. The outcomes to date suggest that, in addition to substantial and dedicated computing resources, future climate modeling and prediction require a substantial research effort to efficiently explore the fidelity of climate models when explicitly resolving important atmospheric and oceanic processes.
Photooxidation of alpha -pinene at high relative humidity in the presence of increasing concentrations of nitrogen oxides (NO sub(x)) was investigated. The size distributions and number ...concentrations of the particles formed by the photochemistry were measured using a scanning mobility particle sizer (SMPS) consisting of either a nano or long differential mobility analyzer (DMA) and a condensation particle counter (CPC). Trace compounds such as HCHO formed during photooxidation in air were shown to be more sensitive measures of model performance than was ozone and organic nitrates could fulfill a similar role. The results showed that in addition to a complex mixture of gaseous and particulate oxygenated organics, organic nitrates were components of both the gas and particle phases.
A disruption mitigation system (DMS) is under design for ITER to inject sufficient material deeply into the plasma for rapid plasma thermal shutdown and collisional suppression of any resulting ...runaway electrons. Progress on the development and design of both a shattered pellet injector (SPI) that produces large solid cryogenic pellets to provide reliable deep penetration of material and a fast opening high flow rate gas valve for massive gas injection (MGI) is presented. Cryogenic pellets of deuterium and neon up to 25 mm in size have been formed and accelerated with a prototype injector and a full scale prototype MGI valve is now in testing. Implications of the design with respect to response time and reliability at the proposed injector locations on ITER are discussed.
The Undiagnosed Disease Network (UDN) is comprised of clinical and research experts collaborating to diagnose rare disease. The UDN is funded by the National Institutes of Health and includes 12 ...different clinical sites (About Us, 2022). Here we highlight the success of collaborative efforts within the UDN Clinical Site at Vanderbilt University Medical Center (VUMC) in utilizing a cohort of experts in bioinformatics, structural biology, and genetics specialists in diagnosing rare disease. Our UDN team identified a de novo mosaic CACNA1D variant c.2299T>C in a 5‐year‐old female with a history of global developmental delay, dystonia, dyskinesis, and seizures. Using a collaborative multidisciplinary approach, our VUMC UDN team diagnosed the participant with Primary Aldosteronism, Seizures, and Neurologic abnormalities (PASNA) OMIM: 615474 due to a rare mosaic CACNA1D variant (O'Neill, 2013). Interestingly, this patient was mosaic, a phenotypic trait previously unreported in PASNA cases. This report highlights the importance of a multidisciplinary approach in diagnosing rare disease.
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