Abstract
Recent works have developed samples of blazars from among the Fermi Large Area Telescope unassociated sources via machine-learning comparisons with known blazar samples. Continued analysis ...of these new blazars tests the predictions of the blazar sequence and enables more flux-complete samples of blazars as a population. Using Fermi, Swift, Wide-field Infrared Survey Explorer, and archival radio data, we construct broadband spectral energy distributions for 106 recently identified blazars. Drawn from the unassociated 4FGL source sample, this new sample has a lower median flux than the overall sample of gamma-ray blazars. By measuring the synchrotron peak frequency, we compare our sample of new blazars with known blazars from the 4LAC catalog. We find that the bulk of the new blazars are similar to high-synchrotron-peaked BL Lac objects, with a higher median synchrotron peak; the sample has a median
log
(
ν
syn
/
Hz
)
=
15.5
via
BLaST
peak estimation, compared to
log
(
ν
syn
/
Hz
)
=
14.2
for the 4LAC BL Lacs. Finally, we conduct synchrotron self-Compton leptonic modeling, comparing fitted physical and phenomenological properties to brighter blazars. We find that the new blazars have smaller characteristic Lorentz factors
γ
boost
and fitted magnetic fields
B
, in agreement with blazar sequence predictions. The new blazars have slightly higher Compton dominance ratios than expected, which may point to alternative emission models for these dim blazars. Our results extend the predictions of the blazar sequence to a sample of dimmer blazars, confirming the broad predictions of that theory.
Abstract
Among the ∼2157 unassociated sources in the third data release (DR3) of the fourth Fermi catalog, ∼1200 were observed with the Neil Gehrels Swift Observatory pointed instruments. These ...observations yielded 238 high signal-to-noise ratio X-ray sources within the 95% Fermi uncertainty regions. Recently, Kerby et al. employed neural networks to find blazar candidates among these 238 X-ray counterparts to the 4FGL unassociated sources and found 112 likely blazar counterpart sources. A complete sample of blazars, along with their subclassification, is a necessary step to help understand the puzzle of the blazar sequence and for the overall completeness of the gamma-ray emitting blazar class in the Fermi catalog. We employed a multi-perceptron neural network classifier to identify flat spectrum radio quasars (FSRQs) and BL Lac objects among these 112 blazar candidates using the gamma-ray, X-ray, UV/optical, and IR properties. This classifier provided probability estimates for each source to be associated with one or the other category, such that
P
fsrq
represents the probability for a source to be associated with the FSRQ subclass. Using this approach, four FSRQs and 50 BL Lac objects are classified as such with >99% confidence, while the remaining 58 blazars could not be unambiguously classified as either BL Lac objects or FSRQs.
ABSTRACT We apply a number of statistical and machine learning techniques to classify and rank gamma-ray sources from the Third Fermi Large Area Telescope Source Catalog (3FGL), according to their ...likelihood of falling into the two major classes of gamma-ray emitters: pulsars (PSR) or active galactic nuclei (AGNs). Using 1904 3FGL sources that have been identified/associated with AGNs (1738) and PSR (166), we train (using 70% of our sample) and test (using 30%) our algorithms and find that the best overall accuracy (>96%) is obtained with the Random Forest (RF) technique, while using a logistic regression (LR) algorithm results in only marginally lower accuracy. We apply the same techniques on a subsample of 142 known gamma-ray pulsars to classify them into two major subcategories: young (YNG) and millisecond pulsars (MSP). Once more, the RF algorithm has the best overall accuracy (∼90%), while a boosted LR analysis comes a close second. We apply our two best models (RF and LR) to the entire 3FGL catalog, providing predictions on the likely nature of unassociated sources, including the likely type of pulsar (YNG or MSP). We also use our predictions to shed light on the possible nature of some gamma-ray sources with known associations (e.g., binaries, supernova remnants/pulsar wind nebulae). Finally, we provide a list of plausible X-ray counterparts for some pulsar candidates, obtained using Swift, Chandra, and XMM. The results of our study will be of interest both for in-depth follow-up searches (e.g., pulsar) at various wavelengths and for broader population studies.
The common observations of multiple radio VLBI stationary knots in high-frequency-peaked BL Lacs (HBLs) can be interpreted as multiple recollimation shocks accelerating particles along jets. This ...approach can resolve the so-called "bulk Lorentz factor crisis" of sources with a high Lorentz factor deduced from maximum γ-γ opacity and fast variability and apparently inconsistent slow/stationary radio knots. It also suggests that a unique pattern of the nonthermal emission variability should appear after each strong flare. Taking advantage of the 13 yr of observation of the HBL Mrk 421 by the X-ray Telescope on the Neil Gehrels Swift Observatory (Swift-XRT), we probe for such an intrinsic variability pattern. Its significance is then statistically estimated via comparisons with numerous similar simulated light curves. A suggested variability pattern is identified, consistent with a main flare emission zone located in the most upstream 15.3 GHz radio knot at 0.38 mas from the core. Subsequent flux excesses in the light curve are consistent with a perturbation crossing all of the downstream radio knots with a constant apparent speed of 45c. The significance of the observed variability pattern not arising from stochastic processes is found above three standard deviations, opening a promising path for further investigations in other blazars and with other energy bands. In addition to highlighting the role of stationary radio knots as high-energy particle accelerators in jets, the developed method allows estimates of the apparent speed and size of a jet perturbation without the need to directly observe any motion in jets.
Abstract
Following the discovery of radio pulsars at the position of Fermi-LAT unassociated sources by the TRAPUM group, we conduct Swift-XRT observations of six of those 4FGL sources to determine if ...any pulsar-like X-ray sources are present and to confirm the reported detection of an X-ray counterpart via eROSITA at 4FGL J1803.1−6708. At two of the six targets, we detect no X-ray sources at the TRAPUM radio position, placing an upper limit on the 0.3–10.0 keV flux. At 4FGL J1803.1−6708 we find an X-ray source at the TRAPUM and eROSITA position. At 4FGL J1858.3−5424 we find a new X-ray counterpart at the TRAPUM position with signal-to-noise ratio S/N = 4.17, but also detect a distinct and separate X-ray source. At 4FGL J1823.8−3544 and 4FGL J1906.4−1757 we detect no X-ray flux at the TRAPUM positions, but we do detect separate X-ray sources elsewhere in the Fermi error ellipse. At these last two targets, our newly detected Swift sources are possible alternatives to the radio pulsar associations proposed by TRAPUM. Our findings confirm several of the discoveries reported by the TRAPUM group but suggest that further observations and investigations are necessary to confirm the low-energy counterpart of several unassociated sources.
Rhenium substantially promotes the rate of Pt-catalyzed glycerol hydrogenolysis to propanediols and shifts the product selectivity from 1,2-propanediol to a mixture of 1,2 and 1,3-propanediols. This ...work presents experimental evidence for a tandem dehydration–hydrogenation mechanism that occurs over a bifunctional Pt–Re catalyst. Infrared spectroscopy of adsorbed pyridine and the rate of aqueous-phase hydrolysis of propyl acetate were used to identify and quantify Brønsted acid sites associated with the Re component. Near-ambient-pressure XPS revealed a range of Re oxidation states on the Pt–Re catalysts after reduction in H2 at 393 and 493 K, which accounts for the presence of Brønsted acidity. A mechanism involving acid-catalyzed dehydration followed by Pt-catalyzed hydrogenation was consistent with the negative influence of added base, a primary kinetic isotope effect with deuterated glycerol, an inverse isotope effect with dideuterium gas, and the observed orders of reaction.
•Pt deactivated during alcohol oxidation because of strongly adsorbing species.•Oxidized Pt was reduced by alcohol in an inert atmosphere.•CO was observed by ATR-IR spectroscopy on Pt after alcohol ...adsorption.•Aqueous O2 rapidly oxidized CO on the Pt surface.•H2 treatment more effectively regenerated deactivated Pt than He treatment.
The oxidation of a variety of terminal alcohols with O2 in liquid water at 343K over Pt supported on C, BN, SiO2, TiO2, and Al2O3 was explored to determine the origin of catalyst deactivation. The sintering of Pt nanoparticles and dissolution of Pt did not contribute significantly to the observed deactivation. A decrease in TOF for 1,6-hexanediol oxidation after the exposure of Pt/C to dioxygen was easily reversed by reduction with the alcohol substrate, indicating that over-oxidation of Pt was not the mode of deactivation. Strongly adsorbed CO on Pt was observed by ATR-IR spectroscopy after contacting the catalysts with alcohols, but the CO was easily removed by oxidation with dissolved O2. Results from thermogravimetric analysis and regeneration studies indicate a strongly adsorbed species other than CO and product acid deactivated the catalysts.
GRB observations with Swift produced the initially surprising result that many bursts have large, late-time X-ray flares. The flares were sometimes intense, had rapid rise and decay phases, and ...occurred late relative to the prompt phase. Many GRBs have had several flares, which were sometimes overlapping. The origin of the flares can be investigated by comparing the spectra during the flares to those of the afterglow and the initial prompt emission. In this work we have analyzed all significant X-ray flares from the first 110 GRBs observed by Swift. Significant X-ray flares (>3 sigma ) were found in 33 of these GRBs, with 77 flares detected. A variety of spectral models have been fit to each flare. We find that the spectral fits sometimes favor a Band function model, which is more akin to the prompt emission than to that of the afterglow. While some flares are approximately as energetic as the prompt GRB emission, we find that the average fluence of the flares is approximately 10 times below the average prompt GRB fluence. We also find that the peak energy of the observed flares is typically in the soft X-ray band, as one might expect due to the X-ray selection of the sample. These results, when combined with those presented in the companion paper on temporal properties of flares, support the hypothesis that many X-ray flares are from late-time activity of the internal engine that spawned the initial GRB, not from an afterglow-related effect.
We present the first systematic investigation of the morphological and timing properties of flares in GRBs observed by Swift XRT. We consider a large sample drawn from all GRBs detected by Swift, ...INTEGRAL, and HETE-2 prior to 2006 January 31, which had an XRT follow-up and which showed significant flaring. Our sample of 33 GRBs includes long and short, at low and high redshift, and a total of 69 flares. The strongest flares occur in the early phases, with a clear anticorrelation between the flare peak intensity and the flare time of occurrence. Fitting each X-ray flare with a Gaussian model, we find that the mean ratio of the width and peak time is < Delta t/t> similar to 0.13 plus or minus 0.10, albeit with a large scatter. Late flares at times >2000 s have long durations, Delta t > 300 s, and can be very energetic compared to the underlying continuum. We further investigated whether there is a clear link between the number of pulses detected in the prompt phase by BAT and the number of X-ray flares detected by XRT, finding no correlation. However, we find that the distribution of intensity ratios between successive BAT prompt pulses and that between successive XRT flares is the same, an indication of a common origin for gamma-ray pulses and X-ray flares. All evidence indicates that flares are indeed related to the workings of the central engine and, in the standard fireball scenario, originate from internal shocks rather than external shocks. While all flares can be explained by long-lasting engine activity, 29/69 flares may also be explained by refreshed shocks. However, 10 can only be explained by prolonged activity of the central engine.
Abstract We report the results of an extensive set of simulations exploring the sensitivity of the BlackCAT CubeSat to long-duration gamma-ray bursts (GRBs). BlackCAT is a NASA APRA-funded CubeSat ...mission for the detection and real-time subarcminute localization of high-redshift ( z ≳ 3.5) GRBs. Thanks to their luminous and long-lived afterglow emissions, GRBs are uniquely valuable probes of high-redshift star-forming galaxies and the intergalactic medium. In addition, each detected GRB with a known redshift serves to localize a region of high-redshift star formation in three dimensions, enabling deep follow-on searches for host galaxies and associated local and large-scale structures. We explore two distinct models for the GRB redshift distribution and luminosity function, both consistent with Swift observations. We find that, for either model, BlackCAT is expected to detect a mean of 42 bursts per year on orbit, with 6.7% to 10% of these at z > 3.5. BlackCAT bursts will be localized to an r 90 ≲ 55″ precision and reported to the community within seconds. Due to the mission orbit and pointing scheme, bursts will be located in the night sky and well placed for deep multiwavelength follow-up observations. BlackCAT is on schedule to achieve launch readiness in 2025.
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