Spectral energy distributions (SEDs) of the central few tens of parsec region of some of the nearest, most well-studied, active galactic nuclei (AGN) are presented. These genuine AGN-core SEDs, ...mostly from Seyfert galaxies, are characterized by two main features: an infrared (IR) bump with the maximum in the 2–10 μm range and an increasing X-ray spectrum with frequency in the 1 to ∼200 keV region. These dominant features are common to Seyfert type 1 and 2 objects alike. In detail, type 1 AGN are clearly distinguished from type 2 by their high spatial resolution SEDs: type 2 AGN exhibit a sharp drop shortwards of 2 μm, with the optical to UV region being fully absorbed; type 1s instead show a gentle 2 μm drop ensued by a secondary, partially absorbed optical to UV emission bump. On the assumption that the bulk of optical to UV photons generated in these AGN is reprocessed by dust and re-emitted in the IR in an isotropic manner, the IR bump luminosity represents ≳70 per cent of the total energy output in these objects, and the second energetically important contribution is the high energies above 20 keV. Galaxies selected by their warm IR colours, i.e. presenting a relatively flat flux distribution in the 12–60 μm range, have often being classified as AGN. The results from these high spatial resolution SEDs question this criterion as a general rule. It is found that the intrinsic shape of the infrared SED of an AGN and inferred bolometric luminosity largely depart from those derived from large aperture data. AGN luminosities can be overestimated by up to two orders of magnitude if relying on IR satellite data. We find these differences to be critical for AGN luminosities below or about 1044 erg s−1. Above this limit, AGN tend to dominate the light of their host galaxy regardless of the integration aperture size used. Although the number of objects presented in this work is small, we tentatively mark this luminosity as a threshold to identify galaxy-light-dominated versus AGN-dominated objects.
Ni phytomining is a promising technology for Ni recovery from low-grade ores such as ultramafic soils. Metal-hyperaccumulators are good candidates for phytomining due to their extraordinary capacity ...for Ni accumulation. However, many of these plants produce a low biomass, which makes the use of agronomic techniques for improving their growth necessary.
In this study, the Ni hyperaccumulators Alyssum serpyllifolium ssp. lusitanicum, A. serpyllifolium ssp. malacitanum, Alyssum bertolonii and Noccaea goesingense were evaluated for their Ni phytoextraction efficiency from a Ni-rich serpentine soil. Effects of soil inorganic fertilisation (100:100:125kgNPKha−1) and soil organic amendment addition (2.5, 5 or 10% compost) on plant growth and Ni accumulation were determined. All soil treatments greatly improved plant growth, but the highest biomass production was generally found after addition of 2.5 or 5% compost (w/w). The most pronounced beneficial effects were observed for N. goesingense. Total Ni phytoextracted from soils was significantly improved using both soil treatments (inorganic and organic), despite the decrease observed in soil Ni availability and shoot Ni concentrations in compost-amended soils. The most promising results were found using intermediate amount of compost, indicating that these types of organic wastes can be incorporated into phytomining systems.
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•The low biomass of most Ni-hyperaccumulator plants can limit the applicability of phytomining techniques at field scale•The use of traditional agronomic practises such as fertilisation can improve plant establishment and biomass production of these plant species•Changes in soil Ni availability, shoot biomass production and Ni accumulation by four Ni-hyperaccumulator species were evaluated after soil inorganic fertilisation (NPK) or compost amendment•Intermediate doses of compost amendment had a stronger effect on Ni yield, mainly due to the enhanced shoot biomass•The use of organic wastes as amendments in phytomining permits the recycling of these residues
A novel balanced differential bandpass filter implemented in coplanar waveguide (CPW) technology is presented. The filter is based on the use of two magnetically coupled CPW folded-stepped impedance ...resonators. The use of magnetic coupling, instead of the more common electric coupling, provides inherent common-mode rejection. Measured and simulated results demonstrate the benefits of the proposed balanced filter.
The present work studied the uptake of 8:2 perfluoroalkyl phosphate diester (diPAP) by two different crops (lettuce and carrot) and two different amended soils. Firstly, the possible degradation of ...8:2 diPAP in the absence of crop was studied and 8:2 monoPAP (monophosphate), 8:2 FTCA (saturated fluorotelomer carboxylate), 8:2 FTUCA (unsaturated fluorotelomer carboxylate), 7:3 FTCA (saturated fluorotelomer carboxylate), PFHpA (perfluoroheptanoic acid), PFHxA (perfluorohexanoic acid) and PFOA (perfluorooctanoic acid) were detected. In the presence of crops, different degradation products were detected in the soil and, while PFNA (perfluorononanoic acid), PFHpA, PFHxA, PFPeA (perfluoropentacoic acid), PFBA (perfluorobutanoic acid), 7:3 FTCA and PFOA were determined in the cultivation media when carrot was grown, PFOA was the only degradation product detected in the case of lettuce experiments.
Regarding the uptake in carrot, all the degradation products except 7:3 FTCA were translocated from the soil to the carrot. Carrot core, peel and leaves bioconcentration factors, BCFs, were determined for 8:2 diPAP and its degradation products. Values lower than method detection limits for core and low BCFs in peel (0.025–0.042) and leaves (0.028–0.049) were achieved for 8:2 diPAP. Regarding to the degradation products, the higher their water solubility, the higher the plant translocation. In this sense, the lower the carbon chain length of PFCAs, the higher the BCFs determined (PFBA > PFHxA > PFHpA > PFOA > PFNA). In general, lower total BCFs were achieved when the total organic carbon of the soils increased. For lettuce experiments, 8:2 diPAP (0.04–0.18) and PFOA (0.28–1.57) were only determined in lettuce heart.
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•8:2 diPAP was degraded in the presence and absence of crops (lettuce and carrot).•PFOA was always the major metabolite both in the presence and absence of crops.•Low accumulation in carrot and lettuce of 8:2 diPAP was observed.•The higher the solubility of the metabolites, the higher the BCFs observed in carrot.•PFOA was the only metabolite detected in lettuce uptake experiments.
The current Web of Data is producing increasingly large RDF datasets. Massive publication efforts of RDF data driven by initiatives like the Linked Open Data movement, and the need to exchange large ...datasets has unveiled the drawbacks of traditional RDF representations, inspired and designed by a document-centric and human-readable Web. Among the main problems are high levels of verbosity/redundancy and weak machine-processable capabilities in the description of these datasets. This scenario calls for efficient formats for publication and exchange.
This article presents a binary RDF representation addressing these issues. Based on a set of metrics that characterizes the skewed structure of real-world RDF data, we develop a proposal of an RDF representation that modularly partitions and efficiently represents three components of RDF datasets: Header information, a Dictionary, and the actual Triples structure (thus called HDT). Our experimental evaluation shows that datasets in HDT format can be compacted by more than fifteen times as compared to current naive representations, improving both parsing and processing while keeping a consistent publication scheme. Specific compression techniques over HDT further improve these compression rates and prove to outperform existing compression solutions for efficient RDF exchange.
Sewage sludge, which acts like a sink for many pollutants, including metals, pathogens and organic pollutants, that are not completely removed in waste water treatment plants (WWTPs), is applied as a ...nutrient rich organic fertilizer in many agricultural applications. In the present work, carrot and lettuce crops were grown in two different compost amended soils fortified with perfluorooctanoic acid (PFOA), perfluorosulfonate acid (PFOS) and perfluorosulfonamide (FOSA) and cultivated in a greenhouse. The plants were harvested and divided into root core, root peel and leaves in the case of carrots and into heart and leaves for lettuces. Concentrations for all the different compartments were determined to assess the bioconcentration factors (BCFs) and the plant distribution of the target analytes. The highest carrot BCFs for PFOA and PFOS were determined in the leaves (0.6–3.4), while lower values were calculated in the core (0.05–0.6) and the peel (0.05–1.9) compartments. However, PFOA was taken up in the translocation stream and accumulated more than PFOS in the edible part of lettuce.
FOSA was totally degraded in the presence of carrot; however, a lower FOSA degradation was observed in presence of the lettuce, which was dependent on the total organic carbon (TOC) content of the soil. The higher the TOC value, the higher the FOSA degradation observed. No degradation was observed in the crop absence.
In the case of the carrot experiments, different polymeric materials (polyethersulfone, PES, polyoxymethylene, and silicone rod) were tested to predict the concentration in the cultivation media. A high correlation (r2>0.63) was observed for the BCFs in the PES and in the carrot core and peel for PFOA and PFOS. It could be, concluded that the PES can be used as a first approach for the determination of the uptake of compounds such as PFOS and PFOA in carrot.
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•BCFLeaves>BCFPeel~BCFCore for PFOS and PFOA in carrot•Leaves PFOA concentrations were obtained higher than PFOS and FOSA.•In presence of crop FOSA was partially (lettuce) or totally (carrot) degraded.•Analytes presence in leaves was due to root uptake and not to foliar uptake.•Good correlation between BCF PES and BCF Peel was obtained for carrot.
Low-luminosity active galactic nuclei (LLAGN) are special among their kind due to the profound structural changes that the central engine experiences at low accretion rates (≲ 10
−3
in Eddington ...units). The disappearance of the accretion disc – the blue bump – leaves behind a faint optical nuclear continuum whose nature has been largely debated. This is mainly due to serious limitations on the observational side imposed by the starlight contamination from the host galaxy and the absorption by hydrogen, preventing the detection of these weak nuclei in the infrared (IR) to ultraviolet (UV) range. We addressed these challenges by combining multi-wavelength sub-arcsecond resolution observations – able to isolate the genuine nuclear continuum – with nebular lines in the mid-IR, which allowed us to indirectly probe the shape of the extreme UV continuum. We found that eight of the nearest prototype LLAGN are compatible with pure compact jet emission over more than ten orders of magnitude in frequency. This consists of self-absorbed synchrotron emission from radio to the UV plus the associated synchrotron self-Compton component dominating the emission in the UV to X-ray range. Additionally, the LLAGN continua show two particular characteristics when compared with the typical jet spectrum seen in radio galaxies: (i) a very steep spectral slope in the IR-to-optical/UV range (−3.7 <
α
0
< −1.3;
F
ν
∝
ν
α
0
); and (ii) a very high turnover frequency (0.2–30 THz; 1.3 mm–10 μm) that separates the optically thick radio emission from the optically thin continuum in the IR-to-optical/UV range. These attributes can be explained if the synchrotron continuum is mainly dominated by thermalised particles at the jet base or the corona with considerably high temperatures, whereas only a small fraction of the energy (∼20%) would be distributed along the high-energy power-law tail of accelerated particles. On the other hand, the nebular gas excitation in LLAGN is in agreement with photo-ionisation from inverse Compton radiation (
α
x
∼ −0.7), which would dominate the nuclear continuum shortwards of ∼3000 Å, albeit a possible contribution from low-velocity shocks (< 500 km s
−1
) to the line excitation cannot be discarded. No sign of a standard hot accretion disc is seen in our sample of LLAGN, nevertheless, a weak cold disc (< 3000 K) is detected at the nucleus of the Sombrero galaxy, though its contribution to the nebular gas excitation is negligible. Our results suggest that the continuum emission in LLAGN is dominated at all wavelengths by undeveloped jets, powered by a thermalised particle distribution with high energies, on average. This is in agreement with their compact morphology and their high turnover frequencies. This behaviour is similar to that observed in peaked-spectrum radio sources and also compact jets in quiescent black hole X-ray binaries. Nevertheless, the presence of extended jet emission at kiloparsec scales for some of the objects in the sample is indicative of past jet activity, suggesting that these nuclei may undergo a rejuvenation event after a more active phase that produced their extended jets. These results imply that the dominant channel for energy release in LLAGN is mainly kinetic via the jet, rather than the radiative one. This has important implications in the context of galaxy evolution, since LLAGN probably represent a major but underestimated source of kinetic feedback in galaxies.