► Novel combined application of recently developed analytical techniques. ► New analytical methodology for the study of complex polychrome structures. ► First article devoted to the study of ...sculpture cross-sections using laboratory-made micro-XRD systems. ► Study of paint layers on sculptures restored/repainted several times across centuries. ► Identification of pigments used in ancient and recent times on a Gothic polychromed wood sculpture.
This paper presents the novel application of recently developed analytical techniques to the study of paint layers on sculptures that have been restored/repainted several times across centuries. Analyses were performed using portable XRF, μ-XRD and μ-Raman instruments. Other techniques, such as optical microscopy, SEM-EDX and μ-FTIR, were also used. Pigments and other materials including vermilion, minium, red lac, ivory black, lead white, barium white, zinc white (zincite), titanium white (rutile and anatase), lithopone, gold and brass were detected. Pigments from both ancient and modern times were found due to the different restorations/repaintings carried out. μ-Raman was very useful to characterise some pigments that were difficult to determine by μ-XRD. In some cases, pigments identification was only possible by combining results from the different analytical techniques used in this work. This work is the first article devoted to the study of sculpture cross-section samples using laboratory-made μ-XRD systems.
Illuminated Arabic manuscripts have been studied, employing two laboratory-made X-ray diffraction (XRD) systems developed recently in the C2RMF laboratory. The validity of the µ-XRD and XRD portable ...systems for the study of this type of artworks has been demonstrated. A common observation in all the analyses is the presence of calcite and rutile; also, hematite, goethite, cinnabar, brass, anatase and barite were detected in the various colours. Differences between the results obtained by both techniques due to acquisition mode are discussed. In addition, other techniques such as X-ray fluorescence (XRF) and micro-Raman were used for the complete characterization of the manuscripts.
In this paper, a novel three-dimensional (3-D) space-vector algorithm for four-leg multilevel converters is presented. It can be applied to active power filters or neutral-current compensator ...applications for mitigating harmonics and zero-sequence components using abc coordinates (referred from now on this paper as natural coordinates). This technique greatly simplifies the selection of the 3-D region where a given voltage vector is supposed to be found. Compared to a three-level modulation algorithm for three-leg multilevel converters, this algorithm does not increase its complexity and the calculations of the active vectors with the corresponding switching time that generate the reference voltage vector. In addition, the low-computational cost of the proposed algorithm is always the same and it is independent of the number of levels of the converter.
This paper describes one of the first case studies using micro-diffraction laboratory-made systems to analyse painting cross-sections. Pigments, such as lead white, vermilion, red ochre, red lac, ...lapis lazuli, smalt, lead tin yellow type I, massicot, ivory black, lamp black and malachite, were detected in cross-sections prepared from six Bartolomé Esteban Murillo paintings by micro-Raman and micro-XRD combined with complementary techniques (optical microscopy, SEM-EDS, and FT-IR). The use of micro-XRD was necessary due to the poor results obtained with conventional XRD. In some cases, pigment identification was only possible by combining results from the different analytical techniques utilised in this study.
An extensive overview of the complementary use of micro-FTIR and micro-Raman spectroscopy in the Cultural Heritage studies is described in this work.
The samples have been prepared using the ...cross-section technique. This technique allows the examination of a large portion of a single paint layer in its original condition. A variety of pigments from samples belonging principally to the Cultural Heritage of Southern Spain were characterized by micro-Raman spectroscopy using visible excitation sources and micro-FTIR spectroscopy. The pigments studied comprise blue (azurite, ultramarine blue, Prussian blue), red (vermilion, haematite, red ochre, red lead, etc.), ochre and yellow (goethite, orpiment, realgar, etc.), green (malachite, copper resinate), and white (calcite, gypsum, white lead, titanium white, barite, lithopone) pigments, among others. An orientation is given for their appropriate and unequivocal characterization. Characterization by micro-FTIR and micro-Raman presents difficulties with some pigments. In these cases, analysis by EDX solves most of these doubts. The combined use of both spectroscopic techniques, together with SEM–EDX microanalysis, provides one of the most useful methods in the characterization (and possible dating) of materials used in Cultural Heritage.
Multilevel converters have been under research and development for more than three decades and have found successful industrial application. However, this is still a technology under development, and ...many new contributions and new commercial topologies have been reported in the last few years. The aim of this paper is to group and review these recent contributions, in order to establish the current state of the art and trends of the technology, to provide readers with a comprehensive and insightful review of where multilevel converter technology stands and is heading. This paper first presents a brief overview of well-established multilevel converters strongly oriented to their current state in industrial applications to then center the discussion on the new converters that have made their way into the industry. In addition, new promising topologies are discussed. Recent advances made in modulation and control of multilevel converters are also addressed. A great part of this paper is devoted to show nontraditional applications powered by multilevel converters and how multilevel converters are becoming an enabling technology in many industrial sectors. Finally, some future trends and challenges in the further development of this technology are discussed to motivate future contributions that address open problems and explore new possibilities.
Energy storage systems (ESSs) are enabling technologies for well-established and new applications such as power peak shaving, electric vehicles, integration of renewable energies, etc. This paper ...presents a review of ESSs for transport and grid applications, covering several aspects as the storage technology, the main applications, and the power converters used to operate some of the energy storage technologies. Special attention is given to the different applications, providing a deep description of the system and addressing the most suitable storage technology. The main objective of this paper is to introduce the subject and to give an updated reference to nonspecialist, academic, and engineers in the field of power electronics.
The use of distributed energy resources is increasingly being pursued as a supplement and an alternative to large conventional central power stations. The specification of a power-electronic ...interface is subject to requirements related not only to the renewable energy source itself but also to its effects on the power-system operation, especially where the intermittent energy source constitutes a significant part of the total system capacity. In this paper, new trends in power electronics for the integration of wind and photovoltaic (PV) power generators are presented. A review of the appropriate storage-system technology used for the integration of intermittent renewable energy sources is also introduced. Discussions about common and future trends in renewable energy systems based on reliability and maturity of each technology are presented
Multilevel converters are considered today as the state-of-the-art power-conversion systems for high-power and power-quality demanding applications. This paper presents a tutorial on this technology, ...covering the operating principle and the different power circuit topologies, modulation methods, technical issues and industry applications. Special attention is given to established technology already found in industry with more in-depth and self-contained information, while recent advances and state-of-the-art contributions are addressed with useful references. This paper serves as an introduction to the subject for the not-familiarized reader, as well as an update or reference for academics and practicing engineers working in the field of industrial and power electronics.
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