Materials with hierarchical porosity and structures have been heavily involved in newly developed energy storage and conversion systems. Because of meticulous design and ingenious hierarchical ...structuration of porosities through the mimicking of natural systems, hierarchically structured porous materials can provide large surface areas for reaction, interfacial transport, or dispersion of active sites at different length scales of pores and shorten diffusion paths or reduce diffusion effect. By the incorporation of macroporosity in materials, light harvesting can be enhanced, showing the importance of macrochannels in light related systems such as photocatalysis and photovoltaics. A state‐of‐the‐art review of the applications of hierarchically structured porous materials in energy conversion and storage is presented. Their involvement in energy conversion such as in photosynthesis, photocatalytic H2 production, photocatalysis, or in dye sensitized solar cells (DSSCs) and fuel cells (FCs) is discussed. Energy storage technologies such as Li‐ions batteries, supercapacitors, hydrogen storage, and solar thermal storage developed based on hierarchically porous materials are then discussed. The links between the hierarchically porous structures and their performances in energy conversion and storage presented can promote the design of the novel structures with advanced properties.
Hierarchically structured porous materials have been heavily involved in newly developed energy storage and conversion systems because of their high surface area, tunable chemical compositions, excellent mechanical and chemical resistance, controllable micro‐, meso‐, and macroporosities at different length scales, desired multifunctionalities, reduced diffusion effect, light harvesting properties, and confinement effects.
In this paper, the edge caching problem in fog radio access network (F-RAN) is investigated. By maximizing the overall cache hit rate, the edge caching optimization problem is formulated to find the ...optimal policy. Content popularity in terms of time and space is considered from the perspective of regional users. We propose an online content popularity prediction algorithm by leveraging the content features and user preferences, and an offline user preference learning algorithm by using the online gradient descent (OGD) method and the follow the (proximally) regularized leader (FTRL-Proximal) method. Our proposed edge caching policy not only can promptly predict the future content popularity in an online fashion with low complexity, but also can track the content popularity with spatial and temporal popularity dynamic in time without delay. Furthermore, we design two learning-based edge caching architectures. Moreover, we theoretically derive the upper bound of the popularity prediction error, the lower bound of the cache hit rate, and the regret bound of the overall cache hit rate of our proposed edge caching policy. Simulation results show that the overall cache hit rate of our proposed policy is superior to those of the traditional policies and asymptotically approaches the optimal performance.
With the help of quantum key distribution (QKD), two distant peers are able to share information-theoretical secure key bits. Increasing the key rate is ultimately significant for the applications of ...QKD in the lossy channel. However, it has been proven that there is a fundamental rate-distance limit, called the linear bound, which restricts the performance of all existing repeaterless protocols and realizations. Surprisingly, a recently proposed protocol, called twin-field (TF) QKD, can beat the linear bound with no need for quantum repeaters. Here, we present one of the first implementations of the TF-QKD protocol and demonstrate its advantage of beating the linear bound at a channel distance of 300 km. In our experiment, a modified TF-QKD protocol that does not assume phase postselection is considered, and thus a higher key rate than the original one is expected. After controlling the phase evolution of the twin fields traveling through hundreds of kilometers of optical fibers, the implemented system achieves high-visibility single-photon interference and allows stable and high-rate measurement-device-independent QKD. Our experimental demonstration and results confirm the feasibility of the TF-QKD protocol and its prominent superiority in long-distance key distribution services.
This paper investigates an unmanned aerial vehicle (UAV) enabled full-duplex relaying system. By assuming that the UAV follows a circular trajectory and applies decode-and-forward relaying strategy, ...we study the joint design of beamforming and power allocation to maximize the instantaneous data rate, under both the individual and the sum power constraints over the source and relay nodes. As the problem is non-convex, we propose an efficient sub-optimal solution based on block-coordinate descent method by decomposing the problem into two sub-problems: a beamforming optimization sub-problem with given power allocation and a power allocation sub-problem with fixed beamforming. For the beamforming design sub-problem, the optimal solution is obtained based on the semi-definite relaxation technique. For the power allocation sub-problem, the optimal solution is obtained in closed form. Then, the closed-form cumulative distribution function and outage probability expressions for sub-optimal beamforming with both uniform power allocation and optimal power allocation are derived. In addition, simple and informative high signal-to-noise ratio (SNR) approximations for outage probability expressions are presented to gain insights. Finally, the optimal flying altitude that minimizes the average outage probability is obtained via one-dimensional search.
Quantum key distribution (QKD) provides a promising solution for sharing information-theoretic secure keys between remote peers with physics-based protocols. According to the law of quantum physics, ...the photons carrying signals cannot be amplified or relayed via classical optical techniques to maintain quantum security. As a result, the transmission loss of the channel limits its achievable distance, and this has been a huge barrier towards building large-scale quantum-secure networks. Here we present an experimental QKD system that could tolerate a channel loss beyond 140 dB and obtain a secure distance of 833.8 km, setting a new record for fibre-based QKD. Furthermore, the optimized four-phase twin-field protocol and high-quality set-up make its secure key rate more than two orders of magnitude greater than previous records over similar distances. Our results mark a breakthrough towards building reliable and efficient terrestrial quantum-secure networks over a scale of 1,000 km.Twin-field (TF) quantum key distribution (QKD) over a secure distance of 833.8 km is demonstrated even in the finite-size regime. To this end, an optimized four-phase TF-QKD protocol and a high-speed low-noise TF-QKD system are developed.
We report a robust synthesis of Ag@Au core–shell nanocubes by directly depositing Au atoms on the surfaces of Ag nanocubes as conformal, ultrathin shells. Our success relies on the introduction of a ...strong reducing agent to compete with and thereby block the galvanic replacement between Ag and HAuCl4. An ultrathin Au shell of 0.6 nm thick was able to protect the Ag in the core in an oxidative environment. Significantly, the core–shell nanocubes exhibited surface plasmonic properties essentially identical to those of the original Ag nanocubes, while the SERS activity showed a 5.4-fold further enhancement owing to an improvement in chemical enhancement. The combination of excellent SERS activity and chemical stability may enable a variety of new applications.
The hybrid beamforming strategy that applies a combination of analog and digital precoders has attracted much attention recently for its ability to reduce both hardware complexity and energy ...consumption. However due to the large number of antennae, the determination of hybrid precoders usually involves a large amount of computation, which may take much time and potentially risk the low-latency demand. In this paper we propose a novel divide-and-conquer precoding scheme where the precoding problem for the sub-connected architecture is divided into a series of independent subproblems. These subproblems can be solved simultaneously to save time. To deal with the subproblems, we propose a semidefinite relaxation based approach. By dividing the precoding problem, computational complexity can be reduced, and simulation results show its comparable performance with existing works, and robustness against potential saddle points with poor performance.
A wide area quantum key distribution (QKD) network deployed on communication infrastructures provided by China Mobile Ltd. is demonstrated. Three cities and two metropolitan area QKD networks were ...linked up to form the Hefei-Chaohu-Wuhu wide area QKD network with over 150 kilometers coverage area, in which Hefei metropolitan area QKD network was a typical full-mesh core network to offer all-to-all interconnections, and Wuhu metropolitan area QKD network was a representative quantum access network with point-to-multipoint configuration. The whole wide area QKD network ran for more than 5000 hours, from 21 December 2011 to 19 July 2012, and part of the network stopped until last December. To adapt to the complex and volatile field environment, the Faraday-Michelson QKD system with several stability measures was adopted when we designed QKD devices. Through standardized design of QKD devices, resolution of symmetry problem of QKD devices, and seamless switching in dynamic QKD network, we realized the effective integration between point-to-point QKD techniques and networking schemes.
Oxygen‐redox of layer‐structured metal‐oxide cathodes has drawn great attention as an effective approach to break through the bottleneck of their capacity limit. However, reversible oxygen‐redox can ...only be obtained in the high‐voltage region (usually over 3.5 V) in current metal‐oxide cathodes. Here, we realize reversible oxygen‐redox in a wide voltage range of 1.5–4.5 V in a P2‐layered Na0.7Mg0.2Fe0.2Mn0.6□0.2O2 cathode material, where intrinsic vacancies are located in transition‐metal (TM) sites and Mg‐ions are located in Na sites. Mg‐ions in the Na layer serve as “pillars” to stabilize the layered structure during electrochemical cycling, especially in the high‐voltage region. Intrinsic vacancies in the TM layer create the local configurations of “□–O–□”, “Na–O–□” and “Mg–O–□” to trigger oxygen‐redox in the whole voltage range of charge–discharge. Time‐resolved techniques demonstrate that the P2 phase is well maintained in a wide potential window range of 1.5–4.5 V even at 10 C. It is revealed that charge compensation from Mn‐ and O‐ions contributes to the whole voltage range of 1.5–4.5 V, while the redox of Fe‐ions only contributes to the high‐voltage region of 3.0–4.5 V. The orphaned electrons in the nonbonding 2p orbitals of O that point toward TM‐vacancy sites are responsible for reversible oxygen‐redox, and Mg‐ions in Na sites suppress oxygen release effectively.
Na0.7Mg0.2Fe0.2Mn0.6□0.2O2 with native transitional metal (TM) vacancies is designed as a novel cathode material for sodium‐ion batteries. The TM vacancies lead to nonbonding O 2p orbitals in this material, pointing toward these vacancies triggering reversible whole‐voltage‐range oxygen redox during charge and discharge processes. This work provides new ideals for design of cathode materials in anionic redox chemistry.
The vision for smart city imperiously appeals to the implementation of Internet-of-Things (IoT), some features of which, such as massive access and bursty short packet transmissions, require new ...methods to enable the cellular system to seamlessly support its integration. Rigorous theoretical analysis is indispensable to obtain constructive insight for the networking design of massive access. In this paper, we propose and define the notion of massive and sporadic access (MSA) to quantitatively describe the massive access of IoT devices. We evaluate the temporal correlation of interference and successful transmission events, and verify that such correlation is negligible in the scenario of MSA. In view of this, in order to resolve the difficulty in any precise spatio-temporal analysis where complex interactions persist among the queues, we propose an approximation that all nodes are moving so fast that their locations are independent at different time slots. Furthermore, we compare the original static network and the equivalent network with high mobility to demonstrate the effectiveness of the proposed approximation approach. The proposed approach is promising for providing a convenient and general solution to evaluate and design the IoT network with massive and sporadic access.
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