Great advances in precision measurements in the quantum regime have been achieved with trapped ions and atomic gases at the lowest possible temperatures1–3. These successes have inspired ideas to ...merge the two systems4. In this way, we can study the unique properties of ionic impurities inside a quantum fluid5–12 or explore buffer gas cooling of a trapped-ion quantum computer13. Remarkably, in spite of its importance, experiments with atom–ion mixtures have remained firmly confined to the classical collision regime14. We report a collision energy of 1.15(±0.23) times the s-wave energy (or 9.9(±2.0) μK) for a trapped ytterbium ion in an ultracold lithium gas. We observed a deviation from classical Langevin theory by studying the spin-exchange dynamics, indicating quantum effects in the atom–ion collisions. Our results open up numerous opportunities, such as the exploration of atom–ion Feshbach resonances15,16, in analogy to neutral systems17.Cooling an atom–ion hybrid system and bringing it into the quantum regime is challenging owing to the unavoidable heating caused by atom–ion collisions. Here a new record low is achieved in such a system, and the quantum effect starts to manifest.
We experimentally demonstrate a quantum walk on a line in phase space using one and two trapped ions. A walk with up to 23 steps is realized by subjecting an ion to state-dependent displacement ...operations interleaved with quantum coin tossing operations. To analyze the ion's motional state after each step we apply a technique that directly maps the probability density distribution onto the ion's internal state. The measured probability distributions and the position's second moment clearly show the nonclassical character of the quantum walk. To further highlight the difference between the classical (random) and the quantum walk, we demonstrate the reversibility of the latter. Finally, we extend the quantum walk by using two ions, giving the walker the additional possibility to stay instead of taking a step.
The Dirac equation successfully merges quantum mechanics with special relativity. It provides a natural description of the electron spin, predicts the existence of antimatter and is able to reproduce ...accurately the spectrum of the hydrogen atom. The realm of the Dirac equation-relativistic quantum mechanics-is considered to be the natural transition to quantum field theory. However, the Dirac equation also predicts some peculiar effects, such as Klein's paradox and 'Zitterbewegung', an unexpected quivering motion of a free relativistic quantum particle. These and other predicted phenomena are key fundamental examples for understanding relativistic quantum effects, but are difficult to observe in real particles. In recent years, there has been increased interest in simulations of relativistic quantum effects using different physical set-ups, in which parameter tunability allows access to different physical regimes. Here we perform a proof-of-principle quantum simulation of the one-dimensional Dirac equation using a single trapped ion set to behave as a free relativistic quantum particle. We measure the particle position as a function of time and study Zitterbewegung for different initial superpositions of positive- and negative-energy spinor states, as well as the crossover from relativistic to non-relativistic dynamics. The high level of control of trapped-ion experimental parameters makes it possible to simulate textbook examples of relativistic quantum physics.
A digital quantum simulator is an envisioned quantum device that can be programmed to efficiently simulate any other local system. We demonstrate and investigate the digital approach to quantum ...simulation in a system of trapped ions. With sequences of up to 100 gates and 6 qubits, the full time dynamics of a range of spin systems are digitally simulated. Interactions beyond those naturally present in our simulator are accurately reproduced, and quantitative bounds are provided for the overall simulation quality. Our results demonstrate the key principles of digital quantum simulation and provide evidence that the level of control required for a full-scale device is within reach.
We theoretically investigate the trap-assisted formation of complexes in atom-ion collisions and their impact on the stability of the trapped ion. The time-dependent potential of the Paul trap ...facilitates the formation of temporary complexes by reducing the energy of the atom, which gets temporarily stuck in the atom-ion potential. As a result, those complexes significantly impact termolecular reactions leading to molecular ion formation via three-body recombination. We find that complex formation is more pronounced in systems with heavy atoms, but the mass has no influence on the lifetime of the transient state. Instead, the complex formation rate strongly depends on the amplitude of the ion's micromotion. We also show that complex formation persists even in the case of a time-independent harmonic trap. In this case, we find higher formation rates and longer lifetimes than in Paul traps, indicating that the atom-ion complex plays an essential role in atom-ion mixtures in optical traps.
We measure chemical reactions between a single trapped ^{174}Yb^{+} ion and ultracold Li_{2} dimers. This produces LiYb^{+} molecular ions that we detect via mass spectrometry. We explain the ...reaction rates by modeling the dimer density as a function of the magnetic field and obtain excellent agreement when we assume the reaction to follow the Langevin rate. Our results present a novel approach towards the creation of cold molecular ions and point to the exploration of ultracold chemistry in ion molecule collisions. What is more, with a detection sensitivity below molecule densities of 10^{14} m^{-3}, we provide a new method to detect low-density molecular gases.
Abstract
Reaching ultracold temperatures within hybrid atom–ion systems is a major limiting factor for control and exploration of the atom–ion interaction in the quantum regime. In this work, we ...present results on numerical simulations of trapped ion buffer gas cooling using an ultracold atomic gas in a large number of experimentally realistic scenarios. We explore the suppression of micromotion-induced heating effects through optimization of trap parameters for various radio-frequency (rf) traps and rf driving schemes including linear and octupole traps, digital Paul traps, rotating traps and hybrid optical/rf traps. We find that very similar ion energies can be reached in all of them even when considering experimental imperfections that cause so-called excess micromotion. Moreover we look into a quantum description of the system and show that quantum mechanics cannot save the ion from micromotion-induced heating in an atom–ion collision. The results suggest that buffer gas cooling can be used to reach close to the ion’s groundstate of motion and is even competitive when compared to some sub-Doppler cooling techniques such as Sisyphus cooling. Thus, buffer gas cooling is a viable alternative for ions that are not amenable to laser cooling, a result that may be of interest for studies into cold controlled quantum chemistry and charged impurity physics.
We report on the observation of interactions between ultracold Rydberg atoms and ions in a Paul trap. The rate of observed inelastic collisions, which manifest themselves as charge transfer between ...the Rydberg atoms and ions, exceeds that of Langevin collisions for ground state atoms by about 3 orders of magnitude. This indicates a huge increase in interaction strength. We study the effect of the vacant Paul trap's electric fields on the Rydberg excitation spectra. To quantitatively describe the exhibited shape of the ion loss spectra, we need to include the ion-induced Stark shift on the Rydberg atoms. Furthermore, we demonstrate Rydberg excitation on a dipole-forbidden transition with the aid of the electric field of a single trapped ion. Our results confirm that interactions between ultracold atoms and trapped ions can be controlled by laser coupling to Rydberg states. Adding dynamic Rydberg dressing may allow for the creation of spin-spin interactions between atoms and ions, and the elimination of collisional heating due to ionic micromotion in atom-ion mixtures.
We propose and theoretically investigate a hybrid system composed of a crystal of trapped ions coupled to a cloud of ultracold fermions. The ions form a periodic lattice and induce a band structure ...in the atoms. This system combines the advantages of high fidelity operations and detection offered by trapped ion systems with ultracold atomic systems. It also features close analogies to natural solid-state systems, as the atomic degrees of freedom couple to phonons of the ion lattice, thereby emulating a solid-state system. Starting from the microscopic many-body Hamiltonian, we derive the low energy Hamiltonian, including the atomic band structure, and give an expression for the atom-phonon coupling. We discuss possible experimental implementations such as a Peierls-like transition into a period-doubled dimerized state.
We theoretically study trapped ions that are immersed in an ultracold gas of Rydberg-dressed atoms. By off-resonant coupling on a dipole-forbidden transition, the adiabatic atom-ion potential can be ...made repulsive. We study the energy exchange between the atoms and a single trapped ion and find that Langevin collisions are inhibited in the ultracold regime for these repulsive interactions. Therefore, the proposed system avoids recently observed ion heating in hybrid atom-ion systems caused by coupling to the ion's radio frequency trapping field and retains ultracold temperatures even in the presence of excess micromotion.
PDF
