The sizes and shapes of ice crystals influence the radiative properties of clouds, as well as precipitation initiation and aerosol scavenging. However, ice crystal growth mechanisms remain only ...partially characterized. We present the growth processes of two complex ice crystal habits observed in Arctic mixed‐phase clouds during the Ny‐Ålesund AeroSol Cloud ExperimeNT campaign. First, are capped‐columns with multiple columns growing out of the plates' corners that we define as columns on capped‐columns. These ice crystals originated from cycling through the columnar and plate temperature growth regimes, during their vertical transport by in‐cloud circulation. Second, is aged rime on the surface of ice crystals having grown into faceted columns or plates depending on the environmental conditions. Despite their complexity, the shapes of these ice crystals allow to infer their growth history and provide information about the in‐cloud conditions. Additionally, these ice crystals exhibit complex shapes and could enhance aggregation and secondary ice production.
Plain Language Summary
Snowflakes formed in the atmosphere have a wide variety of shapes and sizes and no two snowflakes are identical. The reason for this infinite number of shapes is that the environmental temperature and relative humidity prevailing during the snowflakes' growth determine their exact aspects. Thus, the prevailing environmental conditions can be determined from the shape of snowflakes, and become more complicated with increased shape complexity. During a measurement campaign in the Arctic, we identified two complex snowflake types and the history of environmental conditions in which they grew in. We inferred that some snowflakes were recirculating to higher or lower parts of the clouds and that others had collided with cloud droplets that froze on their surface at the early stage of their growth. These snowflakes may enhance the formation of new snowflakes and the initiation of precipitation.
Key Points
A large variety of ice crystal sizes and shapes were observed in Arctic mixed‐phase clouds with a holographic imager
The growth history of two types of complex ice crystals was inferred from their shapes
These ice crystals could enhance aggregation and secondary ice production
Using the 1-D atmospheric chemistry transport model SOSAA, we have investigated the atmospheric reactivity of a boreal forest ecosystem during the HUMPPA-COPEC-10 campaign (summer 2010, at SMEAR II ...in southern Finland). For the very first time, we present vertically resolved model simulations of the NO3 and O3 reactivity (R) together with the modelled and measured reactivity of OH. We find that OH is the most reactive oxidant (R∼3 s-1) followed by NO3 (R∼0.07 s-1) and O3 (R∼2×10-5 s-1). The missing OH reactivity was found to be large in accordance with measurements (∼65 %) as would be expected from the chemical subset described in the model. The accounted OH radical sinks were inorganic compounds (∼41 %, mainly due to reaction with CO), emitted monoterpenes (∼14 %) and oxidised biogenic volatile organic compounds (∼44 %). The missing reactivity is expected to be due to unknown biogenic volatile organic compounds and their photoproducts, indicating that the true main sink of OH is not expected to be inorganic compounds. The NO3 radical was found to react mainly with primary emitted monoterpenes (∼60 %) and inorganic compounds (∼37 %, including NO2). NO2 is, however, only a temporary sink of NO3 under the conditions of the campaign (with typical temperatures of 20–25 ∘C) and does not affect the NO3 concentration. We discuss the difference between instantaneous and steady-state reactivity and present the first boreal forest steady-state lifetime of NO3 (113 s). O3 almost exclusively reacts with inorganic compounds (∼91 %, mainly NO, but also NO2 during night) and less with primary emitted sesquiterpenes (∼6 %) and monoterpenes (∼3 %). When considering the concentration of the oxidants investigated, we find that OH is the oxidant that is capable of removing organic compounds at a faster rate during daytime, whereas NO3 can remove organic molecules at a faster rate during night-time. O3 competes with OH and NO3 during a short period of time in the early morning (around 5 a.m. local time) and in the evening (around 7–8 p.m.). As part of this study, we developed a simple empirical parameterisation for conversion of measured spectral irradiance into actinic flux. Further, the meteorological conditions were evaluated using radiosonde observations and ground-based measurements. The overall vertical structure of the boundary layer is discussed, together with validation of the surface energy balance and turbulent fluxes. The sensible heat and momentum fluxes above the canopy were on average overestimated, while the latent heat flux was underestimated.
Abstract The Arctic is warming at more than twice the rate of the global average. This warming is influenced by clouds, which modulate the solar and terrestrial radiative fluxes and, thus, determine ...the surface energy budget. However, the interactions among clouds, aerosols, and radiative fluxes in the Arctic are still poorly understood. To address these uncertainties, the Ny-Ålesund Aerosol Cloud Experiment (NASCENT) study was conducted from September 2019 to August 2020 in Ny-Ålesund, Svalbard. The campaign’s primary goal was to elucidate the life cycle of aerosols in the Arctic and to determine how they modulate cloud properties throughout the year. In situ and remote sensing observations were taken on the ground at sea level, at a mountaintop station, and with a tethered balloon system. An overview of the meteorological and the main aerosol seasonality encountered during the NASCENT year is introduced, followed by a presentation of first scientific highlights. In particular, we present new findings on aerosol physicochemical and molecular properties. Further, the role of cloud droplet activation and ice crystal nucleation in the formation and persistence of mixed-phase clouds, and the occurrence of secondary ice processes, are discussed and compared to the representation of cloud processes within the regional Weather Research and Forecasting Model. The paper concludes with research questions that are to be addressed in upcoming NASCENT publications.
New particle formation (NPF) is an important atmospheric phenomenon. During an NPF event, particles first form by nucleation and then grow further in size. The growth step is crucial because it ...controls the number of particles that can become cloud condensation nuclei. Among various physical and chemical processes contributing to particle growth, condensation by organic vapors has been suggested as important. In order to better understand the influence of biogenic emissions on particle growth, we carried out modeling studies of NPF events during the BEACHON-ROCS (Bio-hydro-atmosphere interactions of Energy, Aerosol, Carbon, H2O, Organics & Nitrogen - Rocky Mountain Organic Carbon Study) campaign at Manitou Experimental Forest Observatory in Colorado, USA. The site is representative of the semi-arid western USA. With the latest Criegee intermediate reaction rates implemented in the chemistry scheme, the model underestimates sulfuric acid concentration by 50 %, suggesting either missing sources of atmospheric sulfuric acid or an overestimated sink term. The results emphasize the contribution from biogenic volatile organic compound emissions to particle growth by demonstrating the effects of the oxidation products of monoterpenes and 2-Methyl-3-buten-2-ol (MBO). Monoterpene oxidation products are shown to influence the nighttime particle loadings significantly, while their concentrations are insufficient to grow the particles during the day. The growth of ultrafine particles in the daytime appears to be closely related to the OH oxidation products of MBO.
Abstract
Two commercial large-aperture scintillometers, Scintec BLS900, were tested on pathlengths of 1840 and 4200 m at about 45–65 m above ground in Helsinki, Finland. From July 2011 through June ...2012, large variability in diurnal and annual cycles of both the temperature structure parameter and sensible heat flux were observed. Scintillometer data were compared with data from two eddy-covariance stations. A robust method was developed for the calculation of from raw sonic-anemometer data. In contrast to many earlier studies that solely present the values of , the main focus here is on comparisons of itself. This has advantages, because optical-wavelength scintillometers measure with few assumptions, while the determination of implies the applicability of the Monin–Obukhov similarity theory, which has several inherent limitations. The histograms of compare well between sonic and scintillometer. In-depth analysis is focused on one of the scintillometer paths: both and comparisons gave similar and surprisingly high correlation coefficients (0.85 for and 0.84–0.95 for in unstable conditions), given the differences between the two measurement techniques, substantial sensor separation, and different source areas.
Low-level mixed-phase clouds (MPCs) are common in the Arctic. Both local and large-scale phenomena influence the properties and lifetime of MPCs. Arctic fjords are characterized by complex terrain ...and large variations in surface properties. Yet, not many studies have investigated the impact of local boundary layer dynamics and their relative importance on MPCs in the fjord environment. In this work, we used a combination of ground-based remote sensing instruments, surface meteorological observations, radiosoundings, and reanalysis data to study persistent low-level MPCs at Ny-Ålesund, Svalbard, for a 2.5-year period. Methods to identify the cloud regime, surface coupling, and regional and local wind patterns were developed. We found that persistent low-level MPCs were most common with westerly winds, and the westerly clouds had a higher mean liquid (42 g m−2) and ice water path (16 g m−2) compared to those with easterly winds. The increased height and rarity of persistent MPCs with easterly free-tropospheric winds suggest the island and its orography have an influence on the studied clouds. Seasonal variation in the liquid water path was found to be minimal, although the occurrence of persistent MPCs, their height, and their ice water path all showed notable seasonal dependency. Most of the studied MPCs were decoupled from the surface (63 %–82 % of the time). The coupled clouds had 41 % higher liquid water path than the fully decoupled ones. Local winds in the fjord were related to the frequency of surface coupling, and we propose that katabatic winds from the glaciers in the vicinity of the station may cause clouds to decouple. We concluded that while the regional to large-scale wind direction was important for the persistent MPC occurrence and properties, the local-scale phenomena (local wind patterns in the fjord and surface coupling) also had an influence. Moreover, this suggests that local boundary layer processes should be described in models in order to present low-level MPC properties accurately.
The Arctic is very susceptible to climate change and thus is warming much faster than the rest of the world. Clouds influence terrestrial and solar radiative fluxes and thereby impact the amplified ...Arctic warming. The partitioning of thermodynamic phases (i.e., ice crystals and water droplets) within mixed-phase clouds (MPCs) especially influences their radiative properties. However, the processes responsible for ice crystal formation remain only partially characterized. In particular, so-called secondary ice production (SIP) processes, which create supplementary ice crystals from primary ice crystals and the environmental conditions that they occur in, are poorly understood. The microphysical properties of Arctic MPCs were measured during the Ny-Ålesund AeroSol Cloud ExperimENT (NASCENT) campaign to obtain a better understanding of the atmospheric conditions favorable for the occurrence of SIP processes. To this aim, the in situ cloud microphysical properties retrieved by a holographic cloud imager mounted on a tethered balloon system were complemented by ground-based remote sensing and ice-nucleating particle measurements. During the 6 d investigated in this study, SIP occurred during about 40 % of the in-cloud measurements, and high SIP events with number concentrations larger than 10 L−1 of small pristine ice crystals occurred in 4 % of the in-cloud measurements. This demonstrates the role of SIP for Arctic MPCs. The highest concentrations of small pristine ice crystals were produced at temperatures between −5 and −3 ∘C and were related to the occurrence of supercooled large droplets freezing upon collision with ice crystals. This suggests that a large fraction of ice crystals in Arctic MPCs are produced via the droplet-shattering mechanism. From evaluating the ice crystal images, we could identify ice–ice collision as a second SIP mechanism that dominated when fragile ice crystals were observed. Moreover, SIP occurred over a large temperature range and was observed in up to 80 % of the measurements down to −24 ∘C due to the occurrence of ice–ice collisions. This emphasizes the importance of SIP at temperatures below −8 ∘C, which are currently not accounted for in most numerical weather models. Although ice-nucleating particles may be necessary for the initial freezing of water droplets, the ice crystal number concentration is frequently determined by secondary production mechanisms.
A multi-layer ozone (O3) dry deposition model has been implemented into SOSAA (a model to Simulate the concentrations of Organic vapours, Sulphuric Acid and Aerosols) to improve the representation of ...O3 concentration and flux within and above the forest canopy in the planetary boundary layer. We aim to predict the O3 uptake by a boreal forest canopy under varying environmental conditions and analyse the influence of different factors on total O3 uptake by the canopy as well as the vertical distribution of deposition sinks inside the canopy. The newly implemented dry deposition model was validated by an extensive comparison of simulated and observed O3 turbulent fluxes and concentration profiles within and above the boreal forest canopy at SMEAR II (Station to Measure Ecosystem–Atmosphere Relations II) in Hyytiälä, Finland, in August 2010. In this model, the fraction of wet surface on vegetation leaves was parametrised according to the ambient relative humidity (RH). Model results showed that when RH was larger than 70 % the O3 uptake onto wet skin contributed ∼ 51 % to the total deposition during nighttime and ∼ 19 % during daytime. The overall contribution of soil uptake was estimated about 36 %. The contribution of sub-canopy deposition below 4.2 m was modelled to be ∼ 38 % of the total O3 deposition during daytime, which was similar to the contribution reported in previous studies. The chemical contribution to O3 removal was evaluated directly in the model simulations. According to the simulated averaged diurnal cycle the net chemical production of O3 compensated up to ∼ 4 % of dry deposition loss from about 06:00 to 15:00 LT. During nighttime, the net chemical loss of O3 further enhanced removal by dry deposition by a maximum ∼ 9 %. Thus the results indicated an overall relatively small contribution of airborne chemical processes to O3 removal at this site.
We present a comprehensive quality-controlled 15-month dataset of remote sensing observations of low-level mixed-phase clouds (LLMPCs) taken at the high Arctic site of Ny-Ålesund, Svalbard, Norway. ...LLMPCs occur frequently in the Arctic region and extensively affect the energy budget. However, our understanding of the ice microphysical processes taking place in these clouds is incomplete. The dual-wavelength and polarimetric Doppler cloud radar observations, which are the cornerstones of the dataset, provide valuable fingerprints of ice microphysical processes, and the high number of cases included allows for the compiling of robust statistics for process studies. The radar data are complemented with thermodynamic retrievals from a microwave radiometer, liquid base height from a ceilometer, and wind fields from large-eddy simulations. All data are quality controlled, especially the cloud radar data, which are accurately calibrated, matched, and corrected for gas and liquid-hydrometeor attenuation, ground clutter, and range folding. We finally present an analysis of the temperature dependence of Doppler, dual-wavelength, and polarimetric radar variables, to illustrate how the dataset can be used for cloud microphysical studies. The dataset has been published in Chellini et al. (2023) and is freely available at: https://doi.org/10.5281/zenodo.7803064.
Abstract
Background
Western Balkan region holds coal power plants that are old, inefficient and substandard. In 2016, the region’s 16 plants emitted more SO2 than the entire 250 European coal power ...plants. In this study we modelled the transboundary nature of air pollution affecting this region and EU.
Methods
We calculated health impacts and costs from Western Balkan coal plants by the following steps: (1) Identify coal power plants in the Western Balkans in 2016; (2) Source 2016 coal power plant emissions data; (3) Model the pollutant exposure resulting from the emissions from Western Balkan coal power plants; (4) Calculate health impacts associated with modelled pollutant exposures; (5) Attribute the health impacts to individual coal power plants; (6) Calculate the cost of the health impacts.
Results
The modeling shows that every year Western Balkans’ plants cause 3,000 premature deaths, 8,000 cases of bronchitis in children, and other chronic illnesses costing both health systems and economies a total of € 6.1-11.5 billion. The EU bears the majority of health cost, more than half of these health costs relate to the EU (€ 3.1 to 5.8 billion), a third (32%) to Western Balkan countries (€ 1.9 to 3.6 billion) and around 17% in other countries. Moreover, Bulgaria and Croatia’s health budgets are the most heavily impacted. Costs needed to cover the health impacts of Western Balkan coal pollution amount to € 0.3-0.7 billion. For Bulgaria this is the same as 10%-18% of the country’s total health expenditure in 2016. For Croatia (costs of € 0.2-0.4 billion), it amounts to 8%-14% of total health expenditure in 2016.
Discussion
These results imply an coal phase out to protect public health. Strong enforcement of the existing pollution control measures are needed. Political processes such as EU accession of Balkan countries may be a door to prioritise pollution control and air quality, in particular by excluding companies planning new coal power capacity from EU financing.
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