The exactly solvable Kitaev model of two-dimensional honeycomb magnets has a quantum spin liquid phase characterized by the emergence of fractionalized Majorana fermion excitations. In the ...paramagnetic state of α-RuCl3 at high magnetic fields, a half-integer quantization of thermal Hall conductivity has been reported as a signature of edge currents carried by Majorana fermions, but the bulk nature of this state remains unconfirmed. Here, by measuring the heat capacity for different in-plane rotations of an applied magnetic field, we find strongly angle-dependent low-energy excitations in bulk α-RuCl3. The excitation gap has a sextuple node structure, and the gap amplitude increases with the field, as expected for itinerant Majorana fermions in the Kitaev model. Our thermodynamic observations of the opening and closing of the bulk gap according to the magnetic-field direction fully correspond with changes in the edge transport. Moreover, the behaviour at higher magnetic fields where the quantum thermal Hall effect vanishes is consistent with a nematic quantum spin liquid state with two-fold rotational symmetry.α-RuCl has a quantum magnetic phase that may be a spin liquid hosting Majorana fermion excitations. Heat capacity measurements show an anisotropic dependence on magnetic-field direction, consistent with predictions for the putative spin liquid.
•The Ni/Y-doped ZrO2 catalysts show highly catalytic activity for CO2 methanation.•Bidentate carbonate is a major adsorption spice on the Ni/Y-doped ZrO2 catalysts.•The oxide support of t-ZrO2 and/or ...c-ZrO2 with oxygen vacancies plays a key role.
The catalytic methanation of CO2 was carried out on Ni catalysts supported on Y-doped ZrO2 with various Y3+ concentrations and Ni/(Zr+Y) molar ratio=1. The catalysts were characterized by X-ray diffraction, scanning transmission electron microscopy, specific surface area, temperature-programmed desorption of CO2, and temperature-programmed reaction. In addition, operando diffuse-reflectance infrared Fourier-transform spectroscopy (DRIFT) was used to identify the adsorbed reaction intermediate. Catalysts supported on Y-doped ZrO2 show higher catalytic activity than the catalyst on Y-free ZrO2 with a monoclinic ZrO2 phase. The catalytic activity is also dependent upon the Y3+ concentration, and the highest activity was obtained for the catalyst with a Y/(Zr+Y) molar ratio of 0.333, which consists mainly of fcc Ni and cubic ZrO2 phase. Y3+ doping into ZrO2 introduces oxygen vacancies, which play an important role in enhancing the catalytic activity. The operando DRIFT study reveals that a CO adsorption intermediate is absent, and bidentate carbonate is an important intermediate for CH4 formation.
Glutamate, a major excitatory neurotransmitter, plays important roles in synaptic plasticity, such as long-term potentiation (LTP) and new synapse formation. Growing evidence suggests that glutamate ...signaling is involved in the neurobiology of psychiatric disorders, including schizophrenia, major depressive disorder (MDD) and bipolar disorder (BP). Postmortem brain studies demonstrated altered spine density in brains from patients with these psychiatric disorders, indicating that remodeled neuronal circuits may contribute to the pathobiology of these psychiatric diseases. Drugs targeting the glutamate system have typically attracted attention as they show efficacy in animal studies and potential therapeutic effects in the clinical setting. In particular, the Nmethyl- D-aspartate (NMDA) receptor antagonist, ketamine exerts a rapid and robust antidepressant effect in treatment-resistant patients with MDD and BP, whereas conventional antidepressants require several weeks for therapeutic onset. Animal studies showed that ketamine induced rapid synaptogenesis, suggestive of synaptic plasticity via NMDA receptor signaling being an essential event in the treatment of depression. Therefore, drugs modulating glutamate signaling could also be potential therapeutic drugs for psychiatric disorders. First, we summarize the role of glutamate signaling on dendritic spine formation, maintenance and remodeling. Then, we discuss the abnormalities identified in dendritic spine and glutamate signaling from postmortem brain studies and animal models of psychiatric disorders. Finally, we review the potential benefits of drugs acting on the NMDA receptor in clinical and animal models of psychiatric disorders.
Although the efficacy of racemate ketamine, a rapid onset and sustained antidepressant, for patients with treatment-resistant depression was a serendipitous finding, clinical use of ketamine is ...limited, due to psychotomimetic side effects and abuse liability. Behavioral and side-effect evaluation tests were applied to compare the two stereoisomers of ketamine. To elucidate their potential therapeutic mechanisms, we examined the effects of these stereoisomers on brain-derived neurotrophic factor (BDNF)-TrkB signaling, and synaptogenesis in selected brain regions. In the social defeat stress and learned helplessness models of depression, R-ketamine showed a greater potency and longer-lasting antidepressant effect than S-ketamine (esketamine). Furthermore, R-ketamine induced a more potent beneficial effect on decreased dendritic spine density, BDNF-TrkB signaling and synaptogenesis in the prefrontal cortex (PFC), CA3 and dentate gyrus (DG) of the hippocampus from depressed mice compared with S-ketamine. However, neither stereoisomer affected these alterations in the nucleus accumbens of depressed mice. In behavioral tests for side effects, S-ketamine, but not R-ketamine, precipitated behavioral abnormalities, such as hyperlocomotion, prepulse inhibition deficits and rewarding effects. In addition, a single dose of S-ketamine, but not R-ketamine, caused a loss of parvalbumin (PV)-positive cells in the prelimbic region of the medial PFC and DG. These findings suggest that, unlike S-ketamine, R-ketamine can elicit a sustained antidepressant effect, mediated by increased BDNF-TrkB signaling and synaptogenesis in the PFC, DG and CA3. R-ketamine appears to be a potent, long-lasting and safe antidepressant, relative to S-ketamine, as R-ketamine appears to be free of psychotomimetic side effects and abuse liability.
There are numerous research challenges that need to be addressed until a wide deployment of vehicular ad hoc networks (VANETs) becomes possible. One of the critical issues consists of the design of ...scalable routing algorithms that are robust to frequent path disruptions caused by vehicles' mobility. This paper argues the use of information on vehicles' movement information (e.g., position, direction, speed, and digital mapping of roads) to predict a possible link-breakage event prior to its occurrence. Vehicles are grouped according to their velocity vectors. This kind of grouping ensures that vehicles, belonging to the same group, are more likely to establish stable single and multihop paths as they are moving together. Setting up routes that involve only vehicles from the same group guarantees a high level of stable communication in VANETs. The scheme presented in this paper also reduces the overall traffic in highly mobile VANET networks. The frequency of flood requests is reduced by elongating the link duration of the selected paths. To prevent broadcast storms that may be intrigued during path discovery operation, another scheme is also introduced. The basic concept behind the proposed scheme is to broadcast only specific and well-defined packets, referred to as ldquobest packetsrdquo in this paper. The performance of the scheme is evaluated through computer simulations. Simulation results indicate the benefits of the proposed routing strategy in terms of increasing link duration, reducing the number of link-breakage events and increasing the end-to-end throughput.
Abstract
The recently discovered kagome superconductors
A
V
3
Sb
5
(
A
= K, Rb, Cs) exhibit unusual charge-density-wave (CDW) orders with time-reversal and rotational symmetry breaking. One of the ...most crucial unresolved issues is identifying the symmetry of the superconductivity that develops inside the CDW phase. Theory predicts a variety of unconventional superconducting symmetries with sign-changing and chiral order parameters. Experimentally, however, superconducting phase information in
A
V
3
Sb
5
is still lacking. Here we report the impurity effects in CsV
3
Sb
5
using electron irradiation as a phase-sensitive probe of superconductivity. Our magnetic penetration depth measurements reveal that with increasing impurities, an anisotropic fully-gapped state changes to an isotropic full-gap state without passing through a nodal state. Furthermore, transport measurements under pressure show that the double superconducting dome in the pressure-temperature phase diagram survives against sufficient impurities. These results support that CsV
3
Sb
5
is a non-chiral, anisotropic
s
-wave superconductor with no sign change both at ambient and under pressure.
Abstract
The interplay among magnetism, electronic nematicity, and superconductivity is the key issue in strongly correlated materials including iron-based, cuprate, and heavy-fermion ...superconductors. Magnetic fluctuations have been widely discussed as a pairing mechanism of unconventional superconductivity, but recent theory predicts that quantum fluctuations of nematic order may also promote high-temperature superconductivity. This has been studied in FeSe
1−
x
S
x
superconductors exhibiting nonmagnetic nematic and pressure-induced antiferromagnetic orders, but its abrupt suppression of superconductivity at the nematic end point leaves the nematic-fluctuation driven superconductivity unconfirmed. Here we report on systematic studies of high-pressure phase diagrams up to 8 GPa in high-quality single crystals of FeSe
1−
x
Te
x
. When Te composition
x
(Te) becomes larger than 0.1, the high-pressure magnetic order disappears, whereas the pressure-induced superconducting dome near the nematic end point is continuously found up to
x
(Te) ≈ 0.5. In contrast to FeSe
1−
x
S
x
, enhanced superconductivity in FeSe
1−
x
Te
x
does not correlate with magnetism but with the suppression of nematicity, highlighting the paramount role of nonmagnetic nematic fluctuations for high-temperature superconductivity in this system.
The transition temperature Tc of iron-based superconductors has a dome-shaped dependence on chemical doping, and the superconductivity that develops underneath may obscure a potential quantum ...critical point (QCP) residing at absolute zero. With the aim of detecting signatures of this quantum criticality, Hashimoto et al. (p 1554; see the Perspective by Sachdev ) measured the penetration depth of the pnictide series BaFe2(As1-x Px )2 as a function of x. A sharp peak right around the point where Tc has a maximum (x = 0.30) was observed, implying that the superfluid density diminishes sharply where one would expect it to be the most robust. This unusual finding is interpreted as a sign of a QCP at x = 0.30. In a superconductor, the ratio of the carrier density, n, to its effective mass, m*, is a fundamental property directly reflecting the length scale of the superfluid flow, the London penetration depth, λL. In two-dimensional systems, this ratio n/m* (~1/λL2) determines the effective Fermi temperature, TF. We report a sharp peak in the x-dependence of λL at zero temperature in clean samples of BaFe2(As1-xPx)2 at the optimum composition x = 0.30, where the superconducting transition temperature Tc reaches a maximum of 30 kelvin. This structure may arise from quantum fluctuations associated with a quantum critical point. The ratio of Tc/TF at x = 0.30 is enhanced, implying a possible crossover toward the Bose-Einstein condensate limit driven by quantum criticality. PUBLICATION ABSTRACT
The convection electric field increases during the growth phase of substorms, driving the DP 2 ionospheric currents at high‐to‐equatorial latitudes, intensifying the eastward equatorial electrojet ...(EEJ) on the dayside. During the expansion phase, the electric field is often reversed; i.e., overshielding occurs at subauroral‐to‐equatorial latitudes where the EEJ turns to the westward counterelectrojet (CEJ). In this paper, we show that the HF Doppler sounders detected the eastward overshielding electric field at low latitudes on the nightside simultaneously with the CEJ on the dayside. We also show that the overshielding often occurs during the substorm recovery due to the convection reduction, resulting in a two‐step form in both the dayside CEJ and nightside electric field. The opposite direction of the electric field on the dayside and nightside is consistent with the dusk‐to‐dawn potential electric field associated with the region 2 field‐aligned currents intensified by the substorm. The overshielding electric field was found to drive an eastward electrojet with appreciable magnitude in the nighttime equatorial ionosphere, which in turn causes an equatorial enhancement of the midnight positive bay.
Key Points
Eastward electric field is detected by HF Doppler sounders on the nightside with counterelectrojet on the dayside during substorms
Overshielding electric field drives nighttime equatorial electrojet
Substorm current circuits with region 2 field‐aligned currents are completed through the equatorial electrojet on the dayside and nightside
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