In this study, the new source of O(1D) in the mesopause
region due to the process OH(ν≥5)+O(3P)→OH(0≤ν′≤ν-5)+O(1D) is applied to SABER data to
estimate the nighttime O(1D) distributions for the years ...2003–2005. It
is found that O(1D) evolutions in these years are very similar to each
other. Depending on the month, monthly averaged O(1D) distributions
show two to four maxima with values up to 340 cm−3 which are localized in height (at ∼92–96 km) and latitude (at ∼20–40 and ∼60–80∘ S, N). Annually averaged distributions in 2003–2005 have one weak maximum at ∼93 km and ∼65∘ S with values
of 150–160 cm−3 and three pronounced maxima (with values up to 230 cm−3) at ∼95 km and ∼35∘ S, at ∼94 km and ∼40∘ N and at ∼93 km and ∼65–75∘ N, correspondingly. In general, there is slightly more O(1D) in the
Northern Hemisphere than in the Southern Hemisphere. The obtained results are a useful data set for subsequent estimation of nighttime O(1D)
influence on the chemistry of the mesopause region.
The assumption of nighttime ozone chemical equilibrium (NOCE) is widely employed for retrieving the Ox-HOx components in the mesopause from rocket and satellite measurements. In this work, the ...recently developed analytical criterion of determining the NOCE boundary is used (i) to study the connection of this boundary with O and H spatiotemporal variability based on 3D modeling of chemical transport and (ii) to retrieve and analyze the spatiotemporal evolution of the NOCE boundary in 2002–2021 from the SABER/TIMED dataset. It was revealed, first, that the NOCE boundary reproduces well the transition zone dividing deep and weak photochemical oscillations of O and H caused by the diurnal variations of solar radiation. Second, the NOCE boundary is sensitive to sporadic abrupt changes in the middle-atmosphere dynamics, in particular due to powerful sudden stratospheric warmings leading to the events of an elevated (up to ∼ 80 km) stratopause, which took place in January–March 2004, 2006, 2009, 2010, 2012, 2013, 2018, and 2019. Third, the space–time evolution of this characteristic expressed via pressure altitude contains a clear signal of an 11-year solar cycle in the 55∘ S–55∘ N range. In particular, the mean annual NOCE boundary averaged in this range of latitudes anticorrelates well with the F10.7 index with the coefficient of −0.95. Moreover, it shows a weak linear trend of 56.2±42.2 m per decade.
The precise calculation of atmospheric absorption in a microwave band is highly important for atmospheric remote-sensing with ground-based and satellite-borne radiometers, as it is a key element in ...procedures for temperature, humidity or trace gas concentration retrieval. The accuracy of the absorption model directly affects the accuracy of the retrieved information and reliability of the resulting forecasts. In this study, we analyze the difference between observed and simulated microwave spectra obtained from more than four years of microwave and radiosonde observations over Nizhny Novgorod (56.2°N, 44°E). We focus on zenith-measured microwave data in the 20–60 GHz frequency range in clear-sky conditions. The use of a conventional absorption model in simulations leads to a significant difference in frequency channels within the 51–54 GHz range, while calculations employing a more accurate model based on the Energy Corrected Sudden (ECS) formalism for molecular oxygen absorption reduces the difference several-fold.
Atomic oxygen (O) and atomic hydrogen (H) in the mesopause region are critical species, governing chemistry, airglow, and energy budget. However, they cannot be directly measured by satellite remote ...sensing techniques and so inference techniques, by airglow observations, are used. In this work, we retrieved daytime O and H distributions at ~ 77 km–100 km from the data of observations by the SABER (Sounding of the Atmosphere using Broadband Emission Radiometry) instrument at the TIMED (Thermosphere Ionosphere Mesosphere Energetics and Dynamics) satellite in 2003–2015. The retrieval approach considered the reaction H + O
3
→ O
2
+ OH in the ozone balance equation. Moreover, we revised all quenching and spontaneous emission coefficients according to latest published data. We then calculated daytime distributions of OH and HO
2
at these altitudes with the use of their conditions of photochemical equilibrium.
Graphical Abstract
Abstract
We report the results of laboratory measurements of H
2
O
2
production inside thin (50 nm thickness) H
2
O and H
2
O:O
2
ice samples irradiated by 121.6 nm photons at different temperatures. ...In the case of H
2
O ice, H
2
O
2
is formed at the temperatures below 60 К. In the case of H
2
O:O
2
ice, H
2
O
2
is formed in the 20–140 К range. For H
2
O:O
2
= 9:1 ice, we derived H
2
O
2
photochemical quantum yield as a function of sample irradiation temperature. The obtained data can be used for evaluation of H
2
O
2
photoproduction at the surface of astrophysical water ice bodies and inside the particles of Noctilucent Clouds in the Earth’s atmosphere.
Ground-based passive measurements of downwelling atmospheric radiation at ~110.836 GHz allow extracting the spectra of ozone self-radiation (rotational transition J = 61,5–60,6) coming from the low ...stratosphere–mesosphere and retrieving vertical profiles of ozone concentration at these altitudes. There is a notable (several hundred kHz) ambiguity in the determination of the resonance frequency of this important ozone line. We carried out long-term ground-based measurements of atmospheric microwave radiation in this range using upgraded apparatus with high technical accuracy and spectral resolution (~12 kHz). The obtained brightness temperature spectra allowed us to determine the frequency of this ozone line to be 110,835.909 ± 0.016 MHz. We verified that the Doppler frequency shift by horizontal wind as well as the variations of the tropospheric absorption had little effect on the obtained result. The found value was 131 ± 16 kHz less than that measured in the laboratory and differed from modern model calculations. At the same time, it was close to the results of early semiempirical calculations made more than 40 years ago. The applications where precise knowledge about the resonance frequency of this ozone line can be important were discussed in this paper.
The novelty of the work lies in the creation and study of the physical and biological properties of biodegradable polymer coatings for stents based on poly(lactic-co-glycolic acid) (PLGA). Polymer ...coatings are capable of prolonged and directed release of molecules with a high molecular weight, in particular, protein molecules of prourokinase (m.w. 54 kDa). A technology has been developed to create coatings having a relative elongation of 40% to 165% and a tensile strength of 25-65 MPa. Coatings are biodegradable; the rate of degradation of the polymer in an isotonic solution varies in the range of 0.05%-1.0% per day. The created coatings are capable of controlled release of the protein of prourokinase, while about 90% of the molecules of prourokinase retain their enzymatic activity. The rate of release of prourokinase can vary from 0.01 to 0.08 mg/day/cm
2
. Coatings do not have a short-term toxic effect on mammalian cells. The mitotic index of cells growing on coatings is approximately 1.5%. When implanting the developed polymers in animals in the postoperative period, there are no complications. Histological examination did not reveal pathological processes. When implanting individual polymers 60 days after surgery, only traces of PLGA are detected. Thus, a biodegradable composite mechanically resistant polymer capable of prolonged release of the high molecular weight prourokinase enzyme has been developed.
Ground-based microwave radiometers are increasingly used in operational meteorology and nowcasting. These instruments continuously measure the spectra of downwelling atmospheric radiation in the ...range 20–60 GHz used for the retrieval of tropospheric temperature and water vapor profiles. Spectroscopic uncertainty is an important part of the retrieval error budget, as it leads to systematic bias. In this study, we analyze the difference between observed and simulated microwave spectra obtained from more than four years of microwave and radiosonde observations over Nizhny Novgorod (56.2° N, 44° E). We focus on zenith-measured and elevation-scanning data in clear-sky conditions. The simulated spectra are calculated by a radiative transfer model with the use of radiosonde profiles and different absorption models, corresponding to the latest spectroscopy research. In the case of zenith-measurements, we found a systematic bias (up to ~2 K) of simulated spectra at 51–54 GHz. The sign of bias depends on the absorption model. A thorough investigation of the error budget points to a spectroscopic nature of the observed differences. The dependence of the results on the elevation angle and absorption model can be explained by the basic properties of radiative transfer and by cloud contamination at elevation angles.
In this work, we compare the values of 15 convective indices obtained from radiosonde and microwave temperature and water vapor profiles simultaneously measured over Nizhny Novgorod (56.2°N, 44°E) ...during 5 convective seasons of 2014–2018. A good or moderate correlation (with coefficients of ~0.7–0.85) is found for most indices. We assess the thunderstorm prediction skills with a lead time of 12 h for each radiosonde and microwave index. It is revealed that the effectiveness of thunderstorm prediction by microwave indices is much better than by radiosonde ones. Moreover, a good correlation between radiosonde and microwave values of a certain index does not necessarily correspond to similar prediction skills. Eight indices (Showalter Index, Maximum Unstable Convective Available Potential Energy (CAPE), Total Totals index, TQ index, Jefferson Index, S index, K index, and Thompson index) are regarded to be the best predictors from both the true skill statistics (TSS) maximum and Heidke skill score (HSS) maximum points of view. In the case of radiosonde data, the best indices are the Jefferson Index, K index, S index, and Thompson index. Only TSS and HSS maxima for these indices are close to the microwave ones, whereas the prediction skills of other radiosonde indices are essentially worse than in the case of microwave data. The analysis suggests that the main possible reason of this discrepancy is an unexpectedly low quality of radiosonde data.
The influence of the effect of combining different types of processing based on the physical force acting on the surface of conductive materials and the electrochemical active action of electrolytes ...acting as a cutting fluid is considered. The experiments carried out and show a significant effect of these types of processing on the surface quality and the provision of the initial various physical and mechanical properties of the processed materials. The article presents various dependencies of qualitative parameters for the implementation of shaping processes using such blade processing operations as turning, threading in holes of small diameter and expanding the holes. With combined processing methods, the process of forming the finish surface is due to the combined action of the cutting tool and the anodic dissolution of the metal under the influence of an electric current in the electrolyte solution. The application of this method allows obtain higher quality parameters when machining aluminum and copper alloys, the surface formed during processing, including the preservation of such special characteristics of certain materials, such as porosity.
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