We have synthesized a metal-free composite ink that contains graphene dots (GDs) and poly(3,4-ethylenedioxythiophene):polystyrene sulfonate (PEDOT:PSS) that can be used on paper to serve as the ...counter electrode in a flexible dye-sensitized solar cell (DSSC). This paper-based GD/PEDOT:PSS electrode is low-cost, light-weight, flexible, environmentally friendly, and easy to cut and process for device fabrication. We determined the GD/PEDOT:PSS composite effectively fills the dense micro-pores in the paper substrate, which leads to improved carrier transport in the electrode and a 3-fold enhanced cell efficiency as compared to the paper electrode made with sputtered Pt. Moreover, the DSSC with the paper electrode featuring the GD/PEDOT:PSS composite did not fail in photovoltaic tests even after bending the electrode 150 times, whereas the device made with the Pt-based paper electrode decreased in efficiency by 45% after such manipulation. These exceptional properties make the metal-free GD/PEDOT:PSS composite ink a promising electrode material for a wide variety of flexible electronic applications.
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•Water–soluble GDs and PEDOT:PSS are used for preparing Pt–free counter electrode.•GD/PEDOT:PSS–coated paper electrode exhibits higher performance than that with the paper with sputtered Pt.•GD/PEDOT:PSS–coated paper electrode shows unfailing performance after 150 bending cycles.•GD/PEDOT:PSS–coated paper electrode is low–cost, light–weight, and environmental friendly.
Transport of nonreactive (tritium, HTO) and anion radionuclides through two columns with different diameters was experimentally and mathematically examined for three inflow rates. One-dimensional ...advective–dispersive experiments were effectively designed to investigate radionuclide transport through a numerical calibration/validation nonequilibrium model. The two columns were filled with crushed granite, and transport of HTO and two iodine species—iodate (IO
3
−
) and iodide (I
−
)—through them was studied to obtain breakthrough curves for a water-saturated condition. The significance of I
−
was found in the smaller column for an input flow rate of 5 mL/min. The accelerated transport of I
−
may have resulted from anion exclusion, and its relatively stronger Coulomb repulsive force was probably because of its smaller hydration radius than IO
3
−
.
This paper presents a technique to scan neural network based AI models to determine if they are trojaned. Pre-trained AI models may contain back-doors that are injected through training or by ...transforming inner neuron weights. These trojaned models operate normally when regular inputs are provided, and mis-classify to a specific output label when the input is stamped with some special pattern called trojan trigger. We develop a novel technique that analyzes inner neuron behaviors by determining how output activations change when we introduce different levels of stimulation to a neuron. The neurons that substantially elevate the activation of a particular output label regardless of the provided input is considered potentially compromised. Trojan trigger is then reverse-engineered through an optimization procedure using the stimulation analysis results, to confirm that a neuron is truly compromised. We evaluate our system ABS on 177 trojaned models that are trojaned with various attack methods that target both the input space and the feature space, and have various trojan trigger sizes and shapes, together with 144 benign models that are trained with different data and initial weight values. These models belong to 7 different model structures and 6 different datasets, including some complex ones such as ImageNet, VGG-Face and ResNet110. Our results show that ABS is highly effective, can achieve over 90% detection rate for most cases (and many 100%), when only one input sample is provided for each output label. It substantially out-performs the state-of-the-art technique Neural Cleanse that requires a lot of input samples and small trojan triggers to achieve good performance.
Over-the-Air Statistical Estimation Lee, Chuan-Zheng; Barnes, Leighton Pate; Ozgur, Ayfer
IEEE journal on selected areas in communications,
02/2022, Letnik:
40, Številka:
2
Journal Article
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Odprti dostop
We study schemes and lower bounds for distributed minimax statistical estimation over a Gaussian multiple-access channel (MAC) under squared error loss. Our framework combines statistical estimation ...and wireless communication. First, we develop "analog" joint estimation-communication schemes that exploit the superposition property of the Gaussian MAC. We characterize their risk in terms of the number of nodes and dimension of the parameter space. Then, we derive information-theoretic lower bounds on the minimax risk of any estimation scheme that is restricted to communicate the samples over a given number of uses of the channel. This shows that the risk achieved by our proposed schemes is within a logarithmic factor of these lower bounds. We compare both achievability and lower bound results to previous "digital" lower bounds, where nodes transmit errorless bits at the Shannon capacity of the MAC. Our key finding is that analog estimation schemes that leverage the physical layer offer a drastic reduction in estimation error over digital schemes relying on a physical-layer abstraction.
The existing contradictory findings on the contribution of trading volume to volatility forecasting prompt us to seek new solutions to test the sequential information arrival hypothesis (SIAH). ...Departing from other empirical analyses that mainly focus on sophisticated testing methods, this research offers new insights into the volume‐volatility nexus by decomposing and reconstructing the trading activity into short‐run components that typically represent irregular information flow and long‐run components that denote extreme information flow in the stock market. We are the first to attempt at incorporating an improved empirical mode decomposition (EMD) method to investigate the volatility forecasting ability of trading volume along with the Heterogeneous Autoregressive (HAR) model. Previous trading volume is used to obtain the decompositions to forecast the future volatility to ensure an ex ante forecast, and both the decomposition and forecasting processes are carried out by the rolling window scheme. Rather than trading volume by itself, the results show that the reconstructed components are also able to significantly improve out‐of‐sample realized volatility (RV) forecasts. This finding is robust both in one‐step ahead and multiple‐step ahead forecasting horizons under different estimation windows. We thus fill the gap in studies by (1) extending the literature on the volume‐volatility linkage to EMD‐HAR analysis and (2) providing a clear view on how trading volume helps improve RV forecasting accuracy.
To determine the association between combined lifestyle factors, including healthy diet, moderate alcohol consumption, non-smoking, physical activity, and optimal weight, and cardiovascular disease ...(CVD) risk among younger and older adults. We conducted a literature search using PubMed, EMBASE, Cochrane Library, and EBSCO databases up to November 30, 2019 and performed dose-response analysis, subgroup analysis and meta-regression with odds ratios and 95% confidence intervals (CIs). Twenty cohort studies involving 1,090,261 participants with 46,288 cardiovascular events and mean follow-up duration of 12.33 years were included. Compared with the group with the lowest number of healthy lifestyle factors, the group with the highest number had lower CVD risk pooled hazard ratio, 0.37 (95% CI 0.31-0.43). With age as an effect modifier, the lifetime risk of CVD was 0.31 (95% CI 0.24-0.41) at age 37.1-49.9 years, 0.36 (95% CI 0.30-0.45) at age 50.0-59.9 years and 0.49 (95% CI 0.38-0.63) at age 60.0-72.9 years. The hazard ratio of CVD significantly increased from 37.1 to 72.9 years of age slope in multivariate meta-regression: 0.01 (95% CI < 0.001-0.03; p = 0.042). Younger adults have more cardiovascular benefits from combined healthy lifestyle factors.
Photosynthetic efficiency might be a key factor determining plant resistance to abiotic stresses. Plants can sense when growing conditions are not favorable and trigger an internal response at an ...early stage before showing external symptoms. When a high amount of salt enters the plant cell, the membrane system and function of thylakoids in chloroplasts could be destroyed and affect photosynthetic performance if the salt concentration is not regulated to optimal values. Oryza species have salt-tolerant and salt-sensitive genotypes; however, very few studies have investigated the genetic architecture responsible for photosynthetic efficiency under salinity stress in cultivated rice.
We used an imaging-based chlorophyll fluorometer to monitor eight rice varieties that showed different salt tolerance levels for four consecutive days under control and salt conditions. An analysis of the changes in chlorophyll fluorescence parameters clearly showed the maximum quantum efficiency of PSII in sensitive varieties was significantly reduced after NaCl treatment when compared to tolerant varieties. A panel of 232 diverse rice accessions was then analyzed for chlorophyll fluorescence under salt conditions, the results showed that chlorophyll fluorescence parameters such as F
and NPQ were higher in Japonica subspecies, ΦPSII of Indica varieties was higher than that in other subgroups, which suggested that the variation in photosynthetic efficiency was extensively regulated under salt treatment in diverse cultivated rice. Two significant regions on chromosome 5 were identified to associate with the fraction of open PSII centers (qL) and the minimum chlorophyll fluorescence (F
). These regions harbored genes related to senescence, chloroplast biogenesis and response to salt stress are of interest for future functional characterization to determine their roles in regulating photosynthesis.
Rice plant is very sensitive to salinity stress, especially at young seedling stage. Our work identified the distribution pattern of chlorophyll fluorescence parameters in seedlings leaf and their correlations with salt tolerance level in a diverse gene pool. We also revealed the complexity of the genetic architecture regulating rice seedling photosynthetic performance under salinity stress, the germplasm analyzed in this study and the associated genetic information could be utilized in rice breeding program.
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•Pressing/sintering method was used to solidify secondary solid wastes.•The kegging structure of AMP had no effect for formation of stable ceramic solid form.•Crystal phase of ...Cs4Al4Si20O48 was formed and decreased by 300°C compared with zeolite.•The ceramic solid form exhibited excellent leaching resistance properties.
Silica-based ammonium molybdophosphate (AMP/SiO2) is an absorbent material that can effectively remove Cs from radioactive-contaminated wastewater (RCW) generated by Fukushima nuclide accident. Pressing/sintering method was used for final disposal of secondary waste (spent absorbent) to achieve the volume reduction of AMP–Cs/SiO2 (AMP/SiO2 saturation adsorption of Cs) and stable solidification of Cs by adding natural allophane. The structure of AMP–Cs completely collapsed at approximately 700°C, and most Mo and P species in AMP sublimed. The optimal sintering temperature was estimated as 900°C. The stable crystalline phase of Cs4Al4Si20O48 was recrystallized by the reaction of Cs2O, Al2O3, and SiO2, and the immobilization ratio of Cs was approximately 100%. The leachability of Cs from the sintered product in distilled water was approximately 0.41%. The high immobilization and low leachability of Cs were attributed to the excellent solidification properties of the sintered products of AMP–Cs/SiO2–allophane.
Abstract
Sodium-glucose cotransporter 2 (SGLT2) inhibitors have shown impressive effects in reducing major vascular events in several randomized controlled trials (RCTs). The purpose of this study ...was to perform a meta-analysis to evaluate the effect of SGLT2 inhibitors on the risk of stroke and its subtypes. All data from prospective RCTs up to 20 October 2020 involving SGLT2 inhibitors that reported stroke events as the primary endpoint or safety in subjects with type 2 diabetes were subjected to meta-analysis. Five eligible RCTs (EMPA-REG, CANVAS, DECLARE-TIMI 58, CREDENCE and VERTIS CV) involving 46,969 participants were included. Pooled analysis of the RCTs showed no significant effect of SGLT2 inhibitors on total stroke risk ratio (RR) = 0.95; 95% confidence interval (CI) 0.79–1.13, P = 0.585. Subgroup analysis indicated that SGLT2 inhibitors had no significant effect against fatal stroke, non-fatal stroke, ischemic stroke or transient ischemic attack. When only hemorrhagic stroke was included, SGLT2 inhibitors were associated with a significant 50% reduction compared with placebo (RR = 0.49, 95% CI 0.30–0.82, P = 0.007). This meta-analysis shows that SGLT2 inhibitors have a neutral effect on the risk of stroke and its subtypes but a potential protective effect against hemorrhagic stroke.
A series of new metal free organic dyes containing carbazole as donor and π-linker have been synthesized and characterized as effective sensitizers for dye sensitized solar cells (DSSCs). The ...carbazole functionalized at C-2 and C-7 served as electron-rich bridge. The donor property of the carbazole is substantially enhanced on introduction of tert-butyl groups at C-3 and C-6 positions and the oxidation propensity of the dyes increased on insertion of thiophene unit in the conjugation pathway. These structural modifications fine-tuned the optical and electrochemical properties of the dyes. Additionally, the presence of tert-butyl groups on the carbazole nucleus minimized the intermolecular interactions which benefited the performance of DSSCs. The dyes served as efficient sensitizers in DSSCs owing to their promising optical and electrochemical properties. The efficiency of DSSCs utilizing these dyes as sensitizers ranged from 4.22 to 6.04%. The tert-butyl groups were found to suppress the recombination of injected electrons which contributed to the increment in the photocurrent generation (J SC) and open circuit voltage (V OC). A dye with carbazole donor functionalized with tert-butyl groups and the conjugation bridge composed of 2,7-disubstituted carbazole and thiophene fragments exhibited higher V OC value. However, the best device efficiency was observed for a dye with unsubstituted carbazole donor and the π-linker featuring carbazole and bithiophene units due to the high photocurrent generation arising from the facile injection of photogenerated electrons into the conduction band of titanium dioxide (TiO2) facilitated by the low-lying LUMO.