An understanding of the high-temperature copper oxide (cuprate) superconductors has eluded the physics community for over thirty years and represents one of the greatest unsolved problems in ...condensed matter physics. Particularly enigmatic is the normal state from which superconductivity emerges, so much so that this phase has been dubbed a "strange metal." In this article, we review recent research into this strange metallic state as realized in the electron-doped cuprates with a focus on their transport properties. The electron-doped compounds differ in several ways from their more thoroughly studied hole-doped counterparts, and understanding these asymmetries of the phase diagram may prove crucial to developing a final theory of the cuprates. Most of the experimental results discussed in this review have yet to be explained and remain an outstanding challenge for theory.
An understanding of the high-temperature copper oxide (cuprate) superconductors has eluded the physics community for over thirty years, and represents one of the greatest unsolved problems in ...condensed matter physics. Particularly enigmatic is the normal state from which superconductivity emerges, so much so that this phase has been dubbed a "strange metal." In this article, we will review recent research into this strange metallic state as realized in the electron-doped cuprates with a focus on their transport properties. The electron-doped compounds differ in several ways from their more thoroughly studied hole-doped counterparts, and understanding these asymmetries of the phase diagram may prove crucial to developing a final theory of the cuprates. Most of the experimental results discussed in this review have yet to be explained and remain an outstanding challenge for theory.
The influence of disorder on the critical electron states in a quasiperiodic lattice is a subject of intense research. In this work, we report the occurrence of Anderson localization in an ...icosahedral (i) polygrain quasicrystal Al-Pd-Re due to site disorder using hard x-ray photoemission spectroscopy, resistivity, and density functional theory (DFT). Photoemission spectroscopy shows that the density of states is enhanced at the Fermi level in polygrain i-Al-Pd-Re compared to single-grain i-Al-Pd-Re. In contrast, the conductivity of the former is an order of magnitude reduced compared to the latter, indicating that these electron states are localized. DFT shows that these states originate primarily from Re 5d-Pd 4d hybridization and are enhanced in polygrain i-Al-Pd-Re due to compositional difference, but are broadened because of disorder that brings about Anderson localization. This is established by the Mott variable range hopping behavior of conductivity, and the estimated localization length is 23 Å.