This study examines a natural, rapid, fivefold increase in dissolved organic carbon (DOC) concentrations in a temperate shallow lake, describing the processes by which increased DOC resulted in ...anoxic conditions and altered existing carbon cycling pathways. High precipitation for two consecutive years led to rising water levels and the flooding of adjacent degraded peatlands. Leaching from the flooded soils provided an initial increase in DOC concentrations (from a 2010 mean of 12 ± 1 mg L−1 to a maximum concentration of 53 mg L−1 by June 2012). Increasing water levels, DOC, and phytoplankton concentrations reduced light reaching the sediment surface, eliminating most benthic primary production and promoting anoxia in the hypolimnion. From January to June 2012 there was a sudden increase in total phosphorus (from 57 μg L−1 to 216 μg L−1), DOC (from 24.6 mg L−1 to 53 mg L−1), and iron (from 0.12 mg L−1 to 1.07 mg L−1) concentrations, without any further large fluxes in water levels. We suggest that anoxic conditions at the sediment surface and flooded soils produced a dramatic release of these chemicals that exacerbated brownification and eutrophication, creating anoxic conditions that persisted roughly 6 months below a water depth of 1 m and extended periodically to the water surface. This brownification-anoxia feedback loop resulted in a near-complete loss of macroinvertebrate and fish populations, and increased surface carbon dioxide (CO₂) emissions by an order of magnitude relative to previous years.
Ponds and “pondscapes” (networks of ponds) are crucial habitats for biodiversity and for delivering multiple benefits to humans, so-called “Nature’s Contribution to People”, such as climate ...mitigation and adaptation to climate change, creation, and maintenance of habitat for biodiversity, water purification, flood mitigation and cultural benefits (e.g., recreational possibilities). However, ponds are not often considered as Nature-based Solutions to provide all these benefits. In addition, there is insufficient knowledge on how to manage and restore ponds to maximise their role to increase the resilience of ecosystems and society to climate change. To facilitate improved implementation of ponds as Nature-based Solutions for the delivery of a wide range of Nature Contributions to People, it is important to generate and integrate biodiversity, ecosystems, societal, economic and policy knowledge. Hence, there is a need for evidence-based guidance to support the broader use of ponds. Here, we review the role of ponds and pondscapes in delivering Nature’s Contributions to People and provide an overview of the challenges and opportunities for their broader implementation as Nature-based Solutions. Finally, we propose a conceptual framework that can help the implementation of pond Nature-based Solutions, and that outlines future research needs.
Quenching and partitioning (Q&P) treatments result in promising mechanical properties of advanced high-strength steels. However, recent studies indicate that Q&P steels are very susceptible to ...hydrogen embrittlement (HE). Using slow strain-rate tests, the effects of hydrogen charging in different media without and with recombination poison were investigated for Fe-0.38C-1.92Si-0.66Mn-1.39Cr in quenched and tempered as well as Q&P conditions. In addition, corrosion tests and Zn electroplating of tensile specimens were performed. In both heat-treatment states, it was found that the intensified hydrogen-charging conditions using a recombination poison strongly impact the result of HE investigations: HE only occurs when a recombination poison is present. In addition, the negative influence of hydrogen formed during Zn electroplating can be limited by using proper electrolytes and electrical parameters. This allows keeping the HE susceptibility of the Q&P steel low in practical applications when recombination poisons are absent.
The austenitic stainless steel 316L is used for numerous components due to its excellent corrosion resistance. However, forming of components influences the microstructure and can thus change the ...corrosion resistance of the steel. In this context, the corrosion rate of the steel 316L is determined for the case of uniform corrosion of various cold-rolled conditions by ageing tests in 0.5 M H
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SO
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. The microstrain, the martensite fraction, and the residual stress state are quantified using X-ray diffraction. The surface roughness is measured by laser scanning microscopy. Three different model equations are derived by means of multiple regression to predict the corrosion rate as a function of the specimen properties. The analysis shows that a particularly simple model equation, which predicts the corrosion rate only via the plastic strain, shows insufficiently large deviations from the experimentally determined corrosion rates. However, a low divergence to the experimental results with a mean deviation of less than 4% is achieved by using a model equation that takes microstructural parameters and the surface ratio into account. Within this model equation, an increased corrosion rate is achieved with higher microstrain and residual compressive stress of the austenite phase as well as a higher surface-area ratio. A higher fraction of martensite is found to lower the corrosion rate.
Many ecosystems are linked to their adjacent ecosystems by movements of organisms. For instance, aquatic and terrestrial ecosystems are linked via emerging aquatic insects that serve as prey for ...terrestrial consumers. However, the role of these organisms in returning recycled carbon to the ecosystem from which it originated is not well known. This is due to the fact that values of carbon isotope signatures from terrestrial leaves and aquatic resources are usually similar and hence results of isotope mixing models need to be considered with caution. We overcame this problem by adding isotopically distinct terrestrial particulate organic carbon (tPOC) as a tracer to the experimental sides of two lakes that were divided in two equal halves with plastic curtains. We focused on aquatic insect larvae (Chironomidae) that fed on maize Zea mays leaves experimentally added to the lakes, and subsequently became prey for terrestrial predators (spiders) after emergence. The carbon isotope values of Chironomidae and spiders were significantly elevated in the lake treatment sides as compared to reference sides, whereas the values of all autochthonous resources were not affected by maize additions. Estimates from stable isotope mixing models indicated a low but demonstrable contribution of maize leaves to the diet of Chironomidae. Overlap between the isotope values of alder leaves, the major natural tPOC source, and autochthonous resources prevented a reliable quantification of allochthony of Chironomidae. However, we qualitatively demonstrated the flow of terrestrial particulate organic carbon to lakes, as leaf fall, and back to terrestrial surroundings via emerging insects. This 'boomerang' carbon flux between land and lakes blurs the distinction between autochthonous and allochthonous carbon sources.
Abstract
The surface integrity of parts is strongly impacted by the surface-layer properties, which are modified by machining processes. In particular, it is advantageous if the finish machining ...process generates a resilient residual-stress state without additional post-treatment. Thus, this paper describes relationships between the forces and temperature which are measured in-situ/during the process and the residual-stress profile for the turning of the aluminum alloy EN AW-2017. The residual-stress depth profiles are measured by X-ray diffraction after electrochemical removal of material by means of jet-electrochemical machining. The characteristic features of the residual-stress profile (value and depth under the surface of the local minimum of the residual stress) are determined and modeled using multiple regression. The predictions of the models are validated by test samples. An excellent agreement between experiments and the model is achieved. Thus, the models can be applied to predict the expected residual-stress profiles during the machining process, which allows for an in-process adjustment of the machining parameters in order to generate an advantageous residual-stress state.
Ecosystems are generally linked via fluxes of nutrients and energy across their boundaries. For example, freshwater ecosystems in temperate regions may receive significant inputs of terrestrially ...derived carbon via autumnal leaf litter. This terrestrial particulate organic carbon (POC) is hypothesized to subsidize animal production in lakes, but direct evidence is still lacking. We divided two small eutrophic lakes each into two sections and added isotopically distinct maize litter to the treatment sections to simulate increased terrestrial POC inputs via leaf litter in autumn. We quantified the reliance of aquatic consumers on terrestrial resources (allochthony) in the year subsequent to POC additions by applying mixing models of stable isotopes. We also estimated lake-wide carbon (C) balances to calculate the C flow to the production of the major aquatic consumer groups: benthic macroinvertebrates, crustacean zooplankton, and fish. The sum of secondary production of crustaceans and benthic macroinvertebrates supported by terrestrial POC was higher in the treatment sections of both lakes. In contrast, total secondary and tertiary production (supported by both autochthonous and allochthonous C) was higher in the reference than in the treatment sections of both lakes. Average aquatic consumer allochthony per lake section was 27–40%, although terrestrial POC contributed less than about 10% to total organic C supply to the lakes. The production of aquatic consumers incorporated less than 5% of the total organic C supply in both lakes, indicating a low ecological efficiency. We suggest that the consumption of terrestrial POC by aquatic consumers facilitates a strong coupling with the terrestrial environment. However, the high autochthonous production and the large pool of autochthonous detritus in these nutrient-rich lakes make terrestrial POC quantitatively unimportant for the C flows within food webs.
The use of the CEN (European Committee for Standardization) standard method for sampling fish in lakes using multi-mesh gillnets allowed the collection of fish assemblages of 445 European lakes in 12 ...countries. The lakes were additionally characterised by environmental drivers and eutrophication proxies. Following a site-specific approach including a validation procedure, a fish index including two abundance metrics (catch per unit effort expressed as fish number and biomass) and one functional metric of composition (abundance of omnivorous fish) was developed. Correlated with the proxy of eutrophication, this index discriminates between heavily and moderately impacted lakes. Additional analyses on a subset of data from Nordic lakes revealed a stronger correlation between the new fish index and the pressure data. Despite an uneven geographical distribution of the lakes and certain shortcomings in the environmental and pressure data, the fish index proved to be useful for ecological status assessment of lakes applying standardised protocols and thus supports the development of national lake fish assessment tools in line with the European Water Framework Directive.
The destruction of CH+ ions in collisions with H atoms has been studied in a temperature-variable 22 pole ion trap (22PT) combined with a cold effusive H-atom beam. The stored ions are relaxed to ...temperatures of T 22PT >= 12 K. The hydrogen atoms, produced in a radio frequency discharge, are slowed down to various temperatures of T ACC >= 7 K. They are formed into an effusive beam. The effective density of the hydrogen atoms in the trap as well as the H2 background are determined in situ using chemical probing with CO2 +. The experimental arrangement allows us not only to measure thermal rate coefficients (T 22PT = T ACC), but also to extract state-specific rate coefficients k(J,T t) at selected translational temperatures T t and for the CH+ rotational states J = 0, 1, and 2. The measured thermal rate coefficients have a maximum at 60 K, k = (1.2 ? 0.5)X10--9 cm3 s--1. Toward higher temperatures, they fall off in accordance with previous measurements and the trend predicted by phase space theory. Toward lower temperatures, the rate coefficients decrease significantly, especially if the rotation of the ions is cooled. At the coldest conditions achieved (beam: 7.3 K; trap: 12.2 K), a value as low as (5 ? 4) X 10--11 cm3 s--1 has been measured. This leads to the conclusion that non-rotating CH+ is protected against attacks of H atoms. This surprising result is not yet understood. It is most probably due to quantum-dynamical effects already occurring at large distances.
Abstract
The plasma electrolytic oxidation (PEO) is an innovative method for providing light metals and their alloys with protective ceramic surfaces. However, for iron-based materials, the process ...requires very high current densities and results in the formation of coatings which consist of less stable iron compounds. Therefore, it was the aim of this study to design a PEO procedure on low-carbon steel at moderate current densities, which allows for the formation of ceramic coatings whose chemical composition is dominated by the electrolyte constituents. The electrolyte used was based on aluminate and preselected by systematic electrochemical passivation experiments. The PEO treatment was monitored by electrical and optical process diagnostics. As a result of this, it was possible to obtain alumina layers of 80 micrometers in thickness, with a high corundum content of approximately 50 to 90%, after 37 minutes of treatment time, at a current density below 25 A/dm
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on C8C-steel. However, the coating’s microstructure was inhomogeneous and showed poor substrate bonding. Based on the results of the experimental work, explanatory approaches were provided and a course of action is suggested for counteracting these problems.
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