•Curiosity’ ChemCam and CheMin instruments are used to assess alteration in sedimentary rocks.•The chemical alteration index indicates substantial weathering (CIA > 50).•Mineralogy indicates ...clay-rich, mafic mineral-free rocks consistent with substantial alteration.•Results support substantial open system weathering at Gale crater.
From Sol 750 to 1550, the Curiosity rover documented>100 m thick stack of fine-grained sedimentary rocks making up part of the Murray formation, at the base of Mt Sharp, Gale crater. Here, we use data collected by the ChemCam instrument to estimate the level of chemical weathering in these sedimentary rocks. Both the Chemical Index of Alteration (CIA) and the Weathering Index Scale (WIS) indicate a progressive increase in alteration up section, reaching values of CIA of 63 and WIS of 25%. The increase in CIA and WIS values is coupled with a decrease in calcium abundance, suggesting partial dissolution of Ca-bearing minerals (clinopyroxene and plagioclase). Mineralogy from the CheMin X-ray diffraction instrument indicates a decrease in mafic minerals compared with previously analyzed strata and a significant proportion of phyllosilicates consistent with this interpretation. These observations suggest that the sediments were predominantly altered in an open system, before or during their emplacement, contrasting with the rock-dominated conditions inferred in sedimentary deposits analyzed at Yellowknife Bay.
► Valleys feeding the Eberswalde fan crosscut Holden impact crater ejecta blanket. ► Holden crater formation likely postdates the Early Hesperian. ► Modeling shows Eberswalde fan can form at a ...geologically rapid rate. ► The role of Holden crater in Eberswalde fluvial activity is highlighted.
The fan deposit in Eberswalde crater has been interpreted as strong evidence for sustained liquid water on early Mars with a paleolake formed during the Noachian period (>3.7Gy). This location became a key region for understanding the Mars paleo-environment. Eberswalde crater is located 50km north of the rim of the 150km diameter crater Holden. Stratigraphic relationships and chronology obtained using recent Mars Express High Resolution Stereo Camera and Mars Reconnaissance Orbiter Context Camera images show that Eberswalde fluvial activity crosscuts Holden ejecta and thus postdates Holden crater, whose formation age is estimated from crater counts as Late Hesperian (∼3.5Gy, depending on models). Fluvial modeling shows that short term activity (over several years to hundreds of years) involving dense flows (with sediment:water ratio between 0.01 and 0.3) may be as good an explanation of the fluvial landforms as dilute flow over longer durations. Modeling of the thermal effect of the Holden impact in the Eberswalde watershed is used to evaluate its potential role in aqueous activity. The relative timing of the Holden impact and Eberswalde’s fan is a constraint for future studies about the origin of these landforms. Holden ejecta form a weak and porous substrate, which may be easy to erode by fluvial incision. In a cold climate scenario, impact heating could have produced runoff by melting snow or ground ice. Any attempt to model fluvial activity at Eberswalde should take into account that it may have formed as late as in the Late Hesperian, after the great majority of valley network formation and aqueous mineralization on Mars. This suggests that hypotheses for fan formation at Eberswalde by transient and/or localized processes (i.e. impact, volcanism, unusual orbital forcing) should be considered on a par with globally warmer climate.
We model the fluids involved in the alteration processes recorded in the Sheep bed Member mudstones of Yellowknife Bay (YKB), Gale crater, Mars, as revealed by the Mars Science Laboratory Curiosity ...rover investigations. We compare the Gale crater waters with fluids modeled for shergottites, nakhlites, and the ancient meteorite ALH 84001, as well as rocks analyzed by the Mars Exploration rovers, and with terrestrial ground and surface waters. The aqueous solution present during sediment alteration associated with phyllosilicate formation at Gale was high in Na, K, and Si; had low Mg, Fe, and Al concentrations relative to terrestrial ground waters such as the Deccan Traps and other modeled Mars fluids; and had near neutral to alkaline pH. Ca and S species were present in the 10(exp -3) to 10(exp -2) concentration range. A fluid local to Gale crater strata produced the alteration products observed by Curiosity and subsequent evaporation of this ground water- type fluid formed impure sulfate- and silica-rich deposits veins or horizons. In a second, separate stage of alteration, partial dissolution of this sulfate-rich layer in Yellowknife Bay,or beyond, led to the pure sulfate veins observed in YKB. This scenario is analogous to similar processes identified at a terrestrial site in Triassic sediments with gypsum veins of the Mercia Mudstone Group in Watchet Bay, UK.
The ChemCam instrument package on the Mars Science Laboratory rover, Curiosity, is the first planetary science instrument to employ laser-induced breakdown spectroscopy (LIBS) to determine the ...compositions of geological samples on another planet. Pre-processing of the spectra involves subtracting the ambient light background, removing noise, removing the electron continuum, calibrating for the wavelength, correcting for the variable distance to the target, and applying a wavelength-dependent correction for the instrument response. Further processing of the data uses multivariate and univariate comparisons with a LIBS spectral library developed prior to launch as well as comparisons with several on-board standards post-landing. The level-2 data products include semi-quantitative abundances derived from partial least squares regression.
A LIBS spectral library was developed using 69 rock standards in the form of pressed powder disks, glasses, and ceramics to minimize heterogeneity on the scale of the observation (350–550μm dia.). The standards covered typical compositional ranges of igneous materials and also included sulfates, carbonates, and phyllosilicates. The provenance and elemental and mineralogical compositions of these standards are described. Spectral characteristics of this data set are presented, including the size distribution and integrated irradiances of the plasmas, and a proxy for plasma temperature as a function of distance from the instrument. Two laboratory-based clones of ChemCam reside in Los Alamos and Toulouse for the purpose of adding new spectra to the database as the need arises. Sensitivity to differences in wavelength correlation to spectral channels and spectral resolution has been investigated, indicating that spectral registration needs to be within half a pixel and resolution needs to match within 1.5 to 2.6pixels. Absolute errors are tabulated for derived compositions of each major element in each standard using PLS regression. Sources of errors are investigated and discussed, and methods for improving the analytical accuracy of compositions derived from ChemCam spectra are discussed.
► We describe a LIBS spectral training set of 69 geological standards. ► ChemCam Mars LIBS data processing is described. Detection limits are given. ► Laser coupling, plasma temperature, accuracy, and precision are detailed.
We report maps of the concentrations of H, Si, Cl, K, Fe, and Th as determined by the Gamma Ray Spectrometer (GRS) on board the 2001 Mars Odyssey Mission for ±∼45° latitudes. The procedures by which ...the spectra are processed to yield quantitative concentrations are described in detail. The concentrations of elements determined over the locations of the various Mars landers generally agree well with the lander values except for Fe, although the mean of the GRS Fe data agrees well with that of Martian meteorites. The water‐equivalent concentration of hydrogen by mass varies from about 1.5% to 7.5% (by mass) with the most enriched areas being near Apollinaris Patera and Arabia Terra. Cl shows a distribution similar to H over the surface except that the Cl content over Medusae Fossae is much greater than elsewhere. The map of Fe shows enrichment in the northern lowlands versus the southern highlands. Silicon shows only very modest variation over the surface with mass fractions ranging from 19% to 22% over most of the planet, though a significant depletion in Si is noted in a region west of Tharsis Montes and Olympus Mons where the Si content is as low as 18%. K and Th show a very similar pattern with depletions associated with young volcanic deposits and enrichments associated with the TES Surface Type‐2 material. It is noted that there appears to be no evidence of significant globally distributed thick dust deposits of uniform composition.
•Martian soils are analyzed for the first time at sub millimeter scale.•Three different groups of coarse grains have been distinguished.•Fine particles seem to derive from one group of coarse ...grains.•Presence of amorphous component in fine particles and some coarse grains.•Fine particles have undergone limited interaction with water.
The ChemCam instrument onboard the Curiosity rover provides for the first time an opportunity to study martian soils at a sub-millimeter resolution. In this work, we analyzed 24 soil targets probed by ChemCam during the first 250sols on Mars. Using the depth profile capability of the ChemCam LIBS (Laser-Induced Breakdown Spectroscopy) technique, we found that 45% of the soils contained coarse grains (>500μm). Three distinct clusters have been detected: Cluster 1 shows a low SiO2 content; Cluster 2 corresponds to coarse grains with a felsic composition, whereas Cluster 3 presents a typical basaltic composition. Coarse grains from Cluster 2 have been mostly observed exposed in the vicinity of the landing site, whereas coarse grains from Clusters 1 and 3 have been detected mostly buried, and were found all along the rover traverse. The possible origin of these coarse grains was investigated. Felsic (Cluster 2) coarse grains have the same origin as the felsic rocks encountered near the landing site, whereas the origin of the coarse grains from Clusters 1 and 3 seems to be more global. Fine-grained soils (particle size<laser beam diameter which is between 300 and 500μm) show a homogeneous composition all along the traverse, different from the composition of the rocks encountered at Gale. Although they contain a certain amount of hydrated amorphous component depleted in SiO2, possibly present as a surface coating, their overall chemical homogeneity and their close-to-basaltic composition suggest limited, or isochemical alteration, and a limited interaction with liquid water. Fine particles and coarse grains from Cluster 1 have a similar composition, and the former could derive from weathering of the latter. Overall martian soils have a bulk composition between that of fine particles and coarse grains. This work shows that the ChemCam instrument provides a means to study the variability of soil composition at a scale not achievable by bulk chemical analyses.
Physical properties of terrains encountered by the Curiosity rover during the rst 360 sols of operations have been inferred from analysis of the scour zones produced by Sky Crane Landing System ...engine plumes, wheel touch down dynamics, pits produced by Chemical Camera (ChemCam) laser shots, rover wheel traverses over rocks, the extent of sinkage into soils, and the magnitude and sign of rover-based slippage during drives. Results have been integrated with morphologic, mineralogic, and thermophysical properties derived from orbital data, and Curiosity-based measurements, to understand the nature and origin of physical properties of traversed terrains. The hummocky plains (HP) landing site and traverse locations consist ofmoderately to well-consolidated bedrock of alluvial origin variably covered by slightly cohesive, hard-packedbasaltic sand and dust, with both embedded and surface-strewn rock clasts. Rock clasts have been addedthrough local bedrock weathering and impact ejecta emplacement and form a pavement-like surface in whichonly small clasts (5 to 10 cm wide) have been pressed into the soil during wheel passages. The beddedfractured (BF) unit, site of Curiositys rst drilling activity, exposes several alluvial-lacustrine bedrock unitswith little to no soil cover and varying degrees of lithication. Small wheel sinkage values (1 cm) for both HPand BF surfaces demonstrate that compaction resistance countering driven-wheel thrust has been minimaland that rover slippage while traversing across horizontal surfaces or going uphill, and skid going downhill,have been dominated by terrain tilts and wheel-surface material shear modulus values.
•We describe various imaging experiments made by ChemCam’s Remote Microscopic Imager.•RMI gives the LIBS geological context and serves for long distance reconnaissance.•RMI provides clues regarding ...the origin of rocks and their diagenetic evolution.
The Mars Science Laboratory rover, “Curiosity” landed near the base of a 5km-high mound of layered material in Gale crater. Mounted on the rover mast, the ChemCam instrument is designed to remotely determine the composition of soils and rocks located a few meters from the rover, using a Laser-Induced Breakdown Spectrometer (LIBS) coupled to a Remote Micro-Imager (RMI). We provide an overview of the diverse imaging investigations that were carried out by ChemCam’s RMI during the first year of operation on Mars. 1182 individual panchromatic RMI images were acquired from Sol 10 to Sol 360 to document the ChemCam LIBS measurements and to characterize soils, rocks and rover hardware. We show several types of derived imaging products, including mosaics of images taken before and after laser shots, difference images to enhance the most subtle laser pits, merges with color Mastcam-100 images, micro-topography using the Z-stack technique, and time lapse movies. The very high spatial resolution of RMI is able to resolve rock textures at sub-mm scales, which provides clues regarding the origin (igneous versus sedimentary) of rocks, and to reveal information about their diagenetic and weathering evolution. In addition to its scientific value over the range accessible by LIBS (1–7m), we also show that RMI can also serve as a powerful long distance reconnaissance tool to characterize the landscape at distances up to several kilometers from the rover.
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