Abstract
We report the first measurement of polarized thermal dust emission toward the entire infrared dark cloud G11.11−0.12 taken by the polarimeter SOFIA/HAWC+ at 214
μ
m. The obtained magnetic ...fields (
B
-fields) from the polarized emission of the early-stage and massive filament tend to be perpendicular to its spine. We produce a map of
B
-field strengths for the center region of the filament. The strengths vary in the range of 100–600
μ
G and are strongest along the filament's spine. The central region is sub-Alfvénic and mostly subcritical, meaning that
B
-fields dominate over turbulence and are strong enough to resist gravitational collapse. The alignment and properties of dust grains in the filament are studied using radiative torque (RAT) theory. We find the decrease of polarization degree
P
with emission intensity
I
, i.e., depolarization effect, of the form
P
∝
I
−
α
with
α
∼ 0.8–0.9, implying a significant loss of grain alignment in the filament's spine. The depolarization can be explained by the decrease in RAT alignment efficiency toward the denser regions with weaker radiation field, which cannot be explained by
B
-field tangling. We study the effect of the enhanced magnetic relaxation by embedded iron inclusions on RAT alignment and find that the high polarization fraction
P
∼ 20%–30% in the outer layer of the filament is potential evidence for the magnetically enhanced RAT alignment mechanism. This is the first time this effect is evaluated in a filament. Based on the polarization fraction and RAT alignment theory, we also find evidence for grain growth in the filament.
Display omitted
•Recent pretreatment techniques for improving anaerobic digestion of sewage sludge were reviewed.•Sludge pretreatment ameliorates anaerobic digestion and increases the biogas ...yield.•Pretreatment technique efficiency depends on sewage sludge composition.•Microbes play a crucial role in sewage sludge stabilization.•Very few pretreatment techniques are suitable for full-scale implementation.
Anaerobic digestion (AD) of sewage sludge is one of the most efficient, effective, and environmentally sustainable remediation techniques; however, the presence of complex floc structures, hard cell walls, and large amounts of molecular organic matter in the sludge hinder AD hydrolysis. Consequently, sewage sludge pretreatment is a prerequisite to accelerate hydrolysis and improve AD efficiency. This review focuses on pretreatment techniques for improving sewage sludge AD, which include mechanical, chemical, thermal, and biological processes. The various pretreatment process effects are discussed in terms of advantages and disadvantages, including their effectiveness, and recent achievements are reviewed for improved biogas production.
Display omitted
•CuFe2O4@tetracarboxy-porphyrin nanofiber hybrid materials were synthesized.•Hybrid material exhibited good photoenergy-harvesting from solar fuel.•Hybrid material was magnetically ...separable and recyclable.•Self-assembly was used to produce efficient photocatalysts for water splitting.•Rhodamine B degradation mechanism using composite material is proposed.
The main aim of this study was to synthesize an innovative magnetic CuFe2O4@porphyrin nanofiber hybrid material via one-step re-precipitation self-assembly of freebase-tetracarboxy-porphyrin (TCPP), in the presence of CuFe2O4 nanoparticles. The resultant hybrid materials were thoroughly characterized using scanning electron microscopy, energy-dispersive X-ray mapping, X-ray diffractometry, and Fourier-transform infrared, and UV–vis spectroscopy. Results showed well-integration of CuFe2O4 nanoparticles into TCPP nanofiber network, with the average size of CuFe2O4 being less than 100 nm and diameter and length of TCPP aggregate being approximately 20 nm and several µm, respectively. The as-prepared hybrid material possessed strong magnetic properties with a saturated magnetization value of approximately 25 emu/g. This photocatalyst was highly efficient in the removal of rhodamine B (RhB) dye, with the rate constant reaching 2.1 × 10−2 min−1. This paper describes in detail a plausible photocatalytic mechanism for RhB removal by CuFe2O4@porphyrin nanofiber hybrid material.
For decades, there has been a strong interest in mitigating greenhouse gas (GHG) emissions from wastewater treatment plants (WWTPs). Numerous models were developed to measure the emissions and ...propose the quantification. Existing studies looked at the relationship between GHG emissions and operational cost (OCI), which is one of the most important indicators for decision-makers. Other parameters that can influence the control strategies include the effluent quality (EQI) and total environmental impacts. Plant-wide models are reliable methods to examine the OCI, EQI and GHG emissions while Life cycle assessment (LCA) works to assess the potential environmental impacts. A combined LCA and plant-wide model proved to be a valuable tool evaluating and comparing strategies for the best performance of WWTPs. For this study involving a WWTP, the benchmark model is used while LCA is the decision tool to find the most suitable treatment strategy. LCA adds extra criteria that complement the existing criteria provided by such models. Complementing the cost/performance criteria is proposed for plant-wide models, including environmental evaluation, based on LCA, which provides an overall better assessment of WWTPs. It can capture both the dynamic effects and potential environmental impacts. This study provides an overview of the integration between plant-wide models and LCA.
Display omitted
•It is beneficial to include GHG emissions when analysing environmental impacts.•Life cycle assessment combine with plant wide model offer better overall evaluation.•The output data of plant wide model will be used as the inventory data for LCA.
Vu Gia-Thu Bon (VGTB) river basin is an area where flash flood and heavy flood events occur frequently, negatively impacting the local community and socio-economic development of Quang Nam Province. ...In recent years, structural and non-structural solutions have been implemented to mitigate damages due to floods. However, under the impact of climate change, natural disasters continue to happen unpredictably day by day. It is, therefore, necessary to develop a spatial decision support system for real-time flood warnings in the VGTB river basin, which will support in ensuring the area's socio-economic development. The main purpose of this study is to develop an online flood warning system in real-time based on Internet-of-Things (IoT) technologies, GIS, telecommunications, and modeling (Soil and Water Assessment Tool (SWAT) and Hydrologic Engineering Center's River Analysis System (HEC-RAS)) in order to support the local community in the vulnerable downstream areas in the event of heavy rainfall upstream. The structure of the designed system consists of these following components: (1) real-time hydro-meteorological monitoring network, (2) IoT communication infrastructure (Global System for Mobile Communications (GSM), General Packet Radio Service (GPRS), wireless networks), (3) database management system (bio-physical, socio-economic, hydro-meteorological, and inundation), (4) simulating and predicting model (SWAT, HEC-RAS), (5) automated simulating and predicting module, (6) flood warning module via short message service (SMS), (7) WebGIS, application for providing and managing hydro-meteorological and inundation data, and (8) users (citizens and government officers). The entire operating processes of the flood warning system (i.e., hydro-meteorological data collecting, transferring, updating, processing, running SWAT and HEC-RAS, visualizing) are automated. A complete flood warning system for the VGTB river basin has been developed as an outcome of this study, which enables the prediction of flood events 5 h in advance and with high accuracy of 80%.
Display omitted
•A two-step constructed wetland system for sewage treatment and reuse was studied.•Excellent removal efficiencies of TSS (76%), BOD5 (74%), and NH4-N (90%) were achieved.•Hydraulic ...loading significantly affected the removal of NH4-N, TSS, and BOD5.•Optimal HLR of 0.04–0.06 m/d were suitable and practical for water recycling.
This study developed a unique system by combining the novel vertical flow (NVF) using expanded clay (ExC) and free flow surface constructed wetland (FWS) for dormitory sewage purification and reuse. The NVF tank consisted of filter layers of ExC, sandy soil, sand, and gravel. The FWS consisted of sandy soil substrate and was installed after the NVF. Colocasia esculenta and Dracaena sanderiana was planted in NVF and FWS, respectively. The treatment system was operated and tested for more than 21 weeks by increasing the hydraulic loading rate (HLR) from 0.02 m/d to 0.12 m/d. The results demonstrated that effluents in the system changed proportionally to the HLRs, except for nitrate nitrogen. Furthermore, the maximum removal efficiencies for TSS, BOD5, NH4-N, and Tcol were 76 ± 13%, 74 ± 11%, 90 ± 3%, and 59 ± 18% (0.37 ± 0.19 log10MPN/100 mL), respectively. At HLRs of 0.04–0.06 m/d, the treatment system satisfied the limits of agriculture irrigation.
In this study, nanocrystalline ZnNdxFe2−xO4 ferrites with x = 0.0, 0.01, 0.03 and 0.05 were fabricated and used as a catalyst for dye removal potential. The effect of Nd3+ ions substitution on the ...structural, optical and photo-Fenton activity of ZnNdxFe2−xO4 has been investigated. The addition of Nd3+ ions caused a decrease in the grain size of ferrites, the reduction of the optical bandgap energies and thus could be well exploited for the catalytic study. The photocatalytic activity of the ferrite samples was evaluated by the degradation of Rhodamine B (RhB) in the presence of H2O2 under visible light radiation. The results indicated that the ZnNdxFe2−xO4 samples exhibited higher removal efficiencies than the pure ZnFe2O4 ferrites. The highest degradation efficiency was 98.00%, attained after 210 min using the ZnNd0.03Fe1.97O4 sample. The enhanced photocatalytic activity of the ZnFe2O4 doped with Nd3+ is explained due to the efficient separation mechanism of photoinduced electron and holes. The effect of various factors (H2O2 oxidant concentration and catalyst loading) on the degradation of RhB dye was clarified.
This paper focuses on status age, which is a metric for measuring the freshness of a continually updated piece of information (i.e., status) as observed at a remote monitor. In paper, we study a ...system in which a sensor sends random status updates over a dynamic network to a monitor. For this system, we consider the impact of having messages take different routes through the network on the status age. First, we consider a network with plentiful resources (i.e., many nodes that can provide numerous alternate paths), so that packets need not wait in queues at each node in a multihop path. This system is modeled as a single queue with an infinite number of servers, specifically as an M/M/∞ queue. Packets routed over a dynamic network may arrive at the monitor out of order, which we account for in our analysis for the M/M/∞ model. We then consider a network with somewhat limited resources, so that packets can arrive out of order but also must wait in a queue. This is modeled as a single queue with two servers, specifically an M/M/2 queue. We present the exact approach to computing the analytical status age, and we provide an approximation that is shown to be close to the simulated age. We also compare both models with M/M/1, which corresponds to severely limited network resources, and we demonstrate the tradeoff between the status age and the unnecessary network resource consumption.
In light of the chemical exploitation of CO2, new reusable materials for efficiently catalyzing the cycloaddition of CO2 and epoxides under moderate conditions are needed. Herein, a new series of ...isostructural metal–organic frameworks (MOFs) M2(EDOB) EDOB4– = 4,4′-(ethyne-1,2-diyl)bis(2-oxidobenzoate), M = Mg, Ni, Co, Zn, Cu, Fe, known as M-MOF-184, analogous to a well-studied MOF-74 structure, were synthesized and fully characterized. The M-MOF-184 (M = Mg, Co, Ni, Zn) frameworks exhibit accessible mesopore channels (24 Å) and high porosity. Among them, Mg-MOF-184 demonstrated the most upper surface area (>4000 m2 g–1) in any reported MOF-74-type frameworks. Furthermore, Co-MOF-184 revealed the highest CO2 uptake (73 cm3 g–1, at 298 K), and Zn-MOF-184 showed the highest catalytic activity upon the cycloaddition of CO2 (96% conversion, 86% selectivity, and 82% yield) under mild conditions (1 atm CO2, 80 °C, 6 h, and solvent-free). Notably, the catalytic performance of Zn-MOF-184 outperformed that of the original M-MOF-74 (M = Mg, Co, Zn) materials and various Zn-based MOFs. To evaluate the acidity and basicity of a series of M-MOF-184 (M = Mg, Co, Ni, Zn) frameworks, the interaction of these MOFs with acetonitrile vapor was investigated by vapor adsorption and ATR-FTIR spectroscopy measurements. As such, Zn-MOF-184 showed the strongest Lewis acidity derived by Zn cations, which was correlated to the highest catalytic activity upon the cycloaddition of CO2. Interestingly, the 2-oxidobenzoate anions from Co-MOF-184 showed the strongest basicity among the series, which was associated with the highest saturated acetonitrile uptake (544 cm3 g–1 at 298 K). Our findings suggest that the integration of Lewis acidic and basic sites, high surface area, and large accessible pores into the framework can facilitate the CO2 fixation reaction.
PDF
