The kinetics of oxidation of allyl alcohol to glycidol in the presence of extruded titanium silicalite was investigated. Based on the experimental data obtained, a kinetic model of the process was ...developed and the activation energies of the target and side reactions, the rate constants and the adsorption equilibrium were determined. Testing of the process of allyl alcohol epoxidation was carried out and the adequacy of the proposed kinetic model was evaluated at the bench laboratory installation of continuous action. Graphic
The article reviews the weed species composition of oat, sunflower, wheat, buckwheat, rapeseed and flax agrophytocenoses on 390 fields in 21 districts of Altai Krai: Aleyskiy, Bistroistokskiy, ...Baevskiy, Burlinskiy, Kamenskiy, Kosikhinskiy, Krutikhinskiy, Kytmanovskiy, Loktevskiy, Mamontovskiy, Novichikhinskiy, Pankrushikhinskiy, Rebrikhinskiy, Rubtsovskiy, Shipunovskiy, Sovetskiy, Tretyakovskiy, Troitskiy, Tyumentsevskiy, Zarinskiy, and Zonalniy. The studied fields were surveyed by the route method, which involved the study of the plot by examining it along two diagonals and four sides, when the area did not exceed 20.0 hectares. Larger fields were divided into plots of 20.0 hectares before the survey. The areas adjacent to roads were examined most carefully, since it is often from the road that the field becomes infested. We used the ArcGis program to compile original maps for the main weed plant species. It was found that out of 45 species encountered, only 10 play a significant role in weed infestation and have a high frequency rate: aboriginal
Convolvulus arvensis, Amaranthus retroflexus, Euphorbia virgata, Lathyrus tuberosus, Chenopodium album
, as well as such adventive species as
Fallopia convolvulus, Setaria pumila, Panicum miliaceum
subsp.
ruderale, Avena fatua
and
Echinochloa crusgalli
. The largest number of species accounts for the Poaceae family (33.3%). The Brassicaceae family is characterized by a slightly lower percentage of participation in the adventitious flora (27.7%). Other families are not so well represented (by 1-2 species each).
A
bstract
Results are reported from a search for supersymmetric particles in the final state with multiple jets and large missing transverse momentum. The search uses a sample of proton-proton ...collisions at
s
= 13 TeV collected with the CMS detector in 2016–2018, corresponding to an integrated luminosity of 137 fb
−
1
, representing essentially the full LHC Run 2 data sample. The analysis is performed in a four-dimensional search region defined in terms of the number of jets, the number of tagged bottom quark jets, the scalar sum of jet transverse momenta, and the magnitude of the vector sum of jet transverse momenta. No significant excess in the event yield is observed relative to the expected background contributions from standard model processes. Limits on the pair production of gluinos and squarks are obtained in the framework of simplified models for supersymmetric particle production and decay processes. Assuming the lightest supersymmetric particle to be a neutralino, lower limits on the gluino mass as large as 2000 to 2310 GeV are obtained at 95% confidence level, while lower limits on the squark mass as large as 1190 to 1630 GeV are obtained, depending on the production scenario.
In this study, the effect of epinephrine on the biofilm formation of Micrococcus luteus C01 isolated from human skin was investigated in depth for the first time. This hormone has a complex effect on ...biofilms in various systems. In a system with polytetrafluoroethylene (PTFE) cubes, treatment with epinephrine at a physiological concentration of 4.9 × 10−9 M increased the total amount of 72-h biofilm biomass stained with crystal violet and increased the metabolic activity of biofilms, but at higher and lower concentrations, the treatment had no significant effect. On glass fiber filters, treatment with the hormone decreased the number of colony forming units (CFUs) and changed the aggregation but did not affect the metabolic activity of biofilm cells. In glass bottom plates examined by confocal microscopy, epinephrine notably inhibited the growth of biofilms. RNA-seq analysis and RT–PCR demonstrated reproducible upregulation of genes encoding Fe–S cluster assembly factors and cyanide detoxification sulfurtransferase, whereas genes encoding the co-chaperone GroES, the LysE superfamily of lysine exporters, short-chain alcohol dehydrogenase and the potential c-di-GMP phosphotransferase were downregulated. Our results suggest that epinephrine may stimulate matrix synthesis in M. luteus biofilms, thereby increasing the activity of NAD(H) oxidoreductases. Potential c-di-GMP pathway proteins are essential in these processes.
•Physiological blood concentration of epinephrine affected M. luteus C01 biofilms.•Epinephrine stimulated biofilm growth assessed with crystal violet.•Epinephrine affected the CFU and cell aggregation depend on incubation time.•4.912 × 10−9 M epinephrine changed the biofilm biomass assessed by CLSM.•RNA-seq and RT-qPCR showed altered expression levels in seven M. luteus C01 genes.
A search for anomalous electroweak production of WW, WZ, and ZZ boson pairs in association with two jets in proton-proton collisions at s=13TeV at the LHC is reported. The data sample corresponds to ...an integrated luminosity of 35.9fb−1 collected with the CMS detector. Events are selected by requiring two jets with large rapidity separation and invariant mass, one or two leptons (electrons or muons), and a W or Z boson decaying hadronically. No excess of events with respect to the standard model background predictions is observed and constraints on the structure of quartic vector boson interactions in the framework of dimension-8 effective field theory operators are reported. Stringent limits on parameters of the effective field theory operators are obtained. The observed 95% confidence level limits for the S0, M0, and T0 operators are −2.7<fS0/Λ4<2.7, −1.0<fM0/Λ4<1.0, and −0.17<fT0/Λ4<0.16, in units of TeV−4. Constraints are also reported on the product of the cross section and branching fraction for vector boson fusion production of charged Higgs bosons as a function of mass from 600 to 2000 GeV. The results are interpreted in the context of the Georgi–Machacek model.
The state of silicotungstic acid (STA) in the presence of inorganic salts (Fe
2
(SO
4
)
3
, SnCl
2
, and SnSO
4
) in aqueous solutions was studied by
183
W NMR spectroscopy. Silicotungstic acid was ...found to retain its structure, and no new heteropoly compounds were formed. This finding proves the enhanced stability of STA toward complex formation at high acidities.
A search for supersymmetry is presented based on multijet events with large missing transverse momentum produced in proton-proton collisions at a center-of-mass energy of s=13 TeV. The data, ...corresponding to an integrated luminosity of 35.9 fb−1, were collected with the CMS detector at the CERN LHC in 2016. The analysis utilizes four-dimensional exclusive search regions defined in terms of the number of jets, the number of tagged bottom quark jets, the scalar sum of jet transverse momenta, and the magnitude of the vector sum of jet transverse momenta. No evidence for a significant excess of events is observed relative to the expectation from the standard model. Limits on the cross sections for the pair production of gluinos and squarks are derived in the context of simplified models. Assuming the lightest supersymmetric particle to be a weakly interacting neutralino, 95% confidence level lower limits on the gluino mass as large as 1800 to 1960 GeV are derived, and on the squark mass as large as 960 to 1390 GeV, depending on the production and decay scenario.
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