Abstract
Perovskite light-emitting diodes (PeLEDs) based on three-dimensional (3D) polycrystalline perovskites suffer from ion migration, which causes overshoot of luminance over time during ...operation and reduces its operational lifetime. Here, we demonstrate 3D/2D hybrid PeLEDs with extremely reduced luminance overshoot and 21 times longer operational lifetime than 3D PeLEDs. The luminance overshoot ratio of 3D/2D hybrid PeLED is only 7.4% which is greatly lower than that of 3D PeLED (150.4%). The 3D/2D hybrid perovskite is obtained by adding a small amount of neutral benzylamine to methylammonium lead bromide, which induces a proton transfer from methylammonium to benzylamine and enables crystallization of 2D perovskite without destroying the 3D phase. Benzylammonium in the perovskite lattice suppresses formation of deep-trap states and ion migration, thereby enhances both operating stability and luminous efficiency based on its retardation effect in reorientation.
Organic-inorganic hybrid perovskites are emerging low-cost emitters with very high color purity, but their low luminescent efficiency is a critical drawback. We boosted the current efficiency (CE) of ...perovskite light-emitting diodes with a simple bilayer structure to 42.9 candela per ampere, similar to the CE of phosphorescent organic light-emitting diodes, with two modifications: We prevented the formation of metallic lead (Pb) atoms that cause strong exciton quenching through a small increase in methylammonium bromide (MABr) molar proportion, and we spatially confined the exciton in uniform MAPbBr₃ nanograins (average diameter = 99.7 nanometers) formed by a nanocrystal pinning process and concomitant reduction of exciton diffusion length to 67 nanometers. These changes caused substantial increases in steady-state photoluminescence intensity and efficiency of MAPbBr₃ nanograin layers.
Although several transparent conducting materials such as carbon nanotubes, graphene, and conducting polymers have been intensively explored as flexible electrodes in optoelectronic devices, their ...insufficient electrical conductivity, low work function, and complicated electrode fabrication processes have limited their practical use. Herein, a 2D titanium carbide (Ti3C2) MXene film with transparent conducting electrode (TCE) properties, including high electrical conductivity (≈11 670 S cm−1) and high work function (≈5.1 eV), which are achieved by combining a simple solution processing with modulation of surface composition, is described. A chemical neutralization strategy of a conducting‐polymer hole‐injection layer is used to prevent detrimental surface oxidation and resulting degradation of the electrode film. Use of the MXene electrode in an organic light‐emitting diode leads to a current efficiency of ≈102.0 cd A−1 and an external quantum efficiency of ≈28.5% ph/el, which agree well with the theoretical maximum values from optical simulations. The results demonstrate the strong potential of MXene as a solution‐processable electrode in optoelectronic devices and provide a guideline for use of MXenes as TCEs in low‐cost flexible optoelectronic devices.
A solution‐processed transparent conducting electrode with desirable properties including high electrical conductivity (≈11 668 S cm−1) and work function (≈5.1 eV) is achieved by using a 2D titanium carbide (Ti3C2) MXene thin film. Precise control of the surface chemical composition and a neutralized hole‐injection layer prevent detrimental surface/interface oxidation of the MXene and enable a high‐efficiency organic light‐emitting diode that uses the solution‐processed MXene electrode.
Abstract
Wearable medical devices are gaining popularity owing to their potential for seamless integration with the human body and long‐term monitoring of physiological activity. However, ...conventional adhesives were developed based on the assumption of healthy adult skin and may not account for variations in skin characteristics across different species, environments, and body parts. Consequently, the adhesive strength of wearable devices may significantly differ depending on the skin surface to which they are attached, potentially causing skin damage. In this study, we developed a customized wearable‐device adhesive without skin damage by analyzing the characteristics of the skin surface based on oil and water content and roughness according to different species and parts. Our findings demonstrated that increased root‐mean‐square roughness of the skin surface led to reduced contact area and decreased adhesion force between the polydimethylsiloxane (PDMS) pad and skin surface. Surprisingly, hairless skin exhibited 1.5 times higher adhesion strength than hairy skin due to stronger molecular forces resulting from the higher surface energy of the skin. Additionally, the hole‐patterned PDMS pad on sweaty skin displayed improved adhesion properties compared to the cylinder‐patterned PDMS pad. Therefore, customized wearable adhesives provide an effective strategy for developing skin‐damage‐free wearable devices.
The uniform growth of single-crystal graphene over wafer-scale areas remains a challenge in the commercial-level manufacturability of various electronic, photonic, mechanical, and other devices based ...on graphene. Here, we describe wafer-scale growth of wrinkle-free single-crystal monolayer graphene on silicon wafer using a hydrogen-terminated germanium buffer layer. The anisotropic twofold symmetry of the germanium (110) surface allowed unidirectional alignment of multiple seeds, which were merged to uniform single-crystal graphene with predefined orientation. Furthermore, the weak interaction between graphene and underlying hydrogen-terminated germanium surface enabled the facile etch-free dry transfer of graphene and the recycling of the germanium substrate for continual graphene growth.
This review outlines problems and progress in development of solution-processed organic light-emitting diodes (SOLEDs) in industry and academia. Solution processing has several advantages such as low ...consumption of materials, low-cost processing, and large-area manufacturing. However, use of a solution process entails complications, such as the need for solvent resistivity and solution-processable materials, and yields SOLEDs that have limited luminous efficiency, severe roll-off characteristics, and short lifetime compared to OLEDs fabricated using thermal evaporation. These demerits impede production of practical SOLED displays. This review outlines the industrial demands for commercial SOLEDs and the current status of SOLED development in industries and academia, and presents research guidelines for the development of SOLEDs that have high efficiency, long lifetime, and good processability to achieve commercialization.
Metal halide perovskites (MHPs) are emerging next-generation light emitters that have attracted attention in academia and industry owing to their low material cost, simple synthesis, and wide color ...gamut. Efficient strategies for MHP modification are being actively studied to attain high performance demonstrated by commercial light-emitting diodes (LEDs) based on organic emitters. Active studies have overcome the limitations of the external quantum efficiencies (EQEs) of green and red MHP LEDs (PeLEDs); therefore, the EQEs of PeLEDs (red: 21.3% at 649 nm; green: 23.4% at 530 nm) have nearly reached the theoretical limit for the light outcoupling of single-structured planar LEDs. However, the EQEs of blue PeLEDs (12.1% at 488 nm and 1.12% at 445 nm) are still lower than approximately half of those of green and red PeLEDs. To commercialize PeLEDs for future full-color displays, the EQEs of blue MHP emitters should be improved by approximately 2 times for sky-blue and more than 20 times for deep-blue MHP emitters to attain values comparable to the EQEs of red and green PeLEDs. Therefore, based on the reported effective approaches for the preparation of blue PeLEDs, a synergistic strategy for boosting the EQE of blue PeLEDs can be devised for commercialization in future full-color displays. This review covers efficient strategies for improving blue PeLEDs using fundamental approaches of material engineering, including compositional or dimensional engineering, thereby providing inspiration for researchers.
Highly efficient organic/inorganic hybrid perovskite light‐emitting diodes (PeLEDs) based on graphene anode are developed for the first time. Chemically inert graphene avoids quenching of excitons by ...diffused metal atom species from indium tin oxide. The flexible PeLEDs with graphene anode on plastic substrate show good bending stability; they provide an alternative and reliable flexible electrode for highly efficient flexible PeLEDs.
Making small nanograins in polycrystalline organic–inorganic halide perovskite (OIHP) films is critical to improving the luminescent efficiency in perovskite light‐emitting diodes (PeLEDs). 3D ...polycrystalline OIHPs have fundamental limitations related to exciton binding energy and exciton diffusion length. At the same time, passivating the defects at the grain boundaries is also critical when the grain size becomes smaller. Molecular additives can be incorporated to shield the nanograins to suppress defects at grain boundaries; however, unevenly distributed molecular additives can cause imbalanced charge distribution and inefficient local defect passivation in polycrystalline OIHP films. Here, a kinetically controlled polycrystalline organic‐shielded nanograin (OSN) film with a uniformly distributed organic semiconducting additive (2,2′,2′′‐(1,3,5‐benzinetriyl)‐tris(1‐phenyl‐1‐H‐benzimidazole), TPBI) is developed mimicking core–shell nanoparticles. The OSN film causes improved photophysical and electroluminescent properties with improved light out‐coupling by possessing a low refractive index. Finally, highly improved electroluminescent efficiencies of 21.81% ph el−1 and 87.35 cd A−1 are achieved with a half‐sphere lens and four‐time increased half‐lifetime in polycrystalline PeLEDs. This strategy to make homogeneous, defect‐healed polycrystalline core–shell‐mimicked nanograin film with better optical out‐coupling will provide a simple and efficient way to make highly efficient perovskite polycrystal films and their optoelectronics devices.
A novel strategy of core‐shell‐mimicked polycrystalline nanograins for perovskite light‐emitting diodes is developed by kinetically controlling the crystallization kinetics with additive‐based nanocrystal pinning. Organic semiconducting additives homogeneously shield nanograins and heal grain boundary. Our strategy causes improved photophysical properties and light out‐coupling with low optical losses of waveguide and substrate modes. Finally, a high electroluminescent efficiency of 21.81% is achieved.
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