The Pioneer and Voyager spacecraft made close-up measurements of Saturn's ionosphere and upper atmosphere in the 1970s and 1980s that suggested a chemical interaction between the rings and ...atmosphere. Exploring this interaction provides information on ring composition and the influence on Saturn's atmosphere from infalling material. The Cassini Ion Neutral Mass Spectrometer sampled in situ the region between the D ring and Saturn during the spacecraft's Grand Finale phase. We used these measurements to characterize the atmospheric structure and material influx from the rings. The atmospheric He/H
ratio is 10 to 16%. Volatile compounds from the rings (methane; carbon monoxide and/or molecular nitrogen), as well as larger organic-bearing grains, are flowing inward at a rate of 4800 to 45,000 kilograms per second.
Saturn's Dusty Ionosphere Morooka, M. W.; Wahlund, J.‐E.; Hadid, L. Z. ...
Journal of geophysical research. Space physics,
March 2019, Letnik:
124, Številka:
3
Journal Article
Recenzirano
Odprti dostop
Measurements of electrons and ions in Saturn's ionosphere down to 1,500‐km altitudes as well as the ring crossing region above the ionosphere obtained by the Langmuir probe onboard the Cassini ...spacecraft are presented. Five nearly identical deep ionosphere flybys during the Grand Finale orbits and the Final plunge orbit revealed a rapid increase in the plasma densities and discrepancies between the electrons and ions densities (Ne and Ni) near the closest approach. The small Ne/Ni ratio indicates the presence of a dusty plasma, a plasma which charge carrier is dominated by negatively charged heavy particles. Comparison of the Langmuir probe obtained density with the light ion density obtained by the Ion and Neutral Mass Spectrometer confirmed the presence of heavy ions. An unexpected positive floating potential of the probe was also observed when Ne/Ni ≪ 1. This suggests that Saturn's ionosphere near the density peak is in a dusty plasma state consisting of negatively and positively charged heavy cluster ions. The electron temperature (Te) characteristics in the ionosphere are also investigated and unexpectedly high electron temperature value, up to 5000 K, has been observed below 2,500‐km altitude in a region where electron‐neutral collisions should be prominent. A well‐defined relationship between Te and Ne/Ni ratio was found, implying that the electron heating at low altitudes is related to the dusty plasma state of the ionosphere.
Plain Language Summary
Cassini Langmuir probe measurements revealed ion densities in excess of the electron densities, indicative of a dusty plasma, in Saturn's ionosphere below 2,500‐km altitude. Comparison of the Langmuir probe measurements with those of the Ion and Neutral Mass Spectrometer, sensitive to only lighter ions during this period, showed that heavy ions dominate in this region. Positive spacecraft potentials were also found, suggesting that Saturn's ionosphere contains dusty plasma of negatively and positively charged heavy ions.
Key Points
In situ measurements of Saturn's ionospheric plasma densities down to 1,500 km and the ring above the ionosphere is presented
Charge imbalance in the ions and electrons, evidence of the negatively charged heavy particles, has been observed below 2,500 km
Observations suggest that Saturn's ionosphere consists of a significant amount of negatively and positively charged heavy ions
The MAss Spectrometer for Planetary EXploration (MASPEX) is a high-mass-resolution, high-sensitivity, multi-bounce time-of-flight mass spectrometer (MBTOF) capable of measuring minor species with ...abundances of sub-parts-per-million in Europa’s sputter-produced and radiolytically modified exosphere and in its oceanic plumes. The goal of the MASPEX-Europa investigation is to determine, through in-situ measurement of the exosphere and plume composition, whether the conditions for habitability exist or have existed on Europa. As conventionally defined, based on our knowledge of Earth life, the three fundamental conditions for habitability are: (1) the presence of liquid water; (2) the presence of organic compounds and the biogenic elements CHNOPS; and (3) a source of energy available for metabolic processes, which for Europa will most probably be chemosynthetic rather than photosynthetic. Condition (1) is already established by previous indirect (magnetic field) measurements, while MASPEX will contribute directly to the evaluation of condition (2) through highly specific compositional measurements in the Europan exosphere and plumes. The composition measurements will also contribute to the test of condition (3) through disequilibrium states of chemical reactions. Thus, the primary goal of MASPEX for Europa Clipper is to assess the habitability of Europa and specifically of its interior ocean. MASPEX has been developed successfully, and its calibration has demonstrated that it meets its specified requirements for sensitivity, dynamic range, and mass resolution. This paper reports the development of the MASPEX scientific investigation, the instrument, its performance, and calibration.
During Cassini's final, spectacular months, in situ instruments made the first direct measurements of nanoparticles, finding an exceptionally large flow from the rings into Saturn's atmosphere. ...Cassini's Ion and Neutral Mass Spectrometer measured material in three altitude bands and found a global‐integrated flux of 2–20 × 104 kg/s that is dominated by hydrocarbon material <104u. Ranging from clusters of a few molecules to radii of several nanometers, nanoparticles are ubiquitous throughout Saturn's rings but embedded in the regolith of larger particles and not detectable as independent particles using remote observations. The smallest nanoparticles are susceptible to atmosphere drag by Saturn's tenuous exosphere that reaches the inner edge of the D ring. The unsustainable large flux suggests a recent disturbance of Saturn's inner ring material, possibly associated with the clumping that appeared in the D68 ringlet in 2015.
Plain Language Summary
For 40 years, calculations based on remote observations indicated that Saturn's magnetic field carries ions and charged particles from the rings to the midlatitudes of Saturn. In Cassini's last few months of life, direct, in situ measurements found that 10 tons/s of molecules and particles smaller than two nanometers are streaming along the plane of the rings into Saturn's atmosphere by another process: atmospheric drag. Saturn's extended atmosphere reaches the inner edge of Saturn's rings and extracts neutral particles less than one thousandth the thickness of a human hair by slowing them down until they fall into Saturn. Surprisingly, the flux is a hundred times larger than past predictions, and at least half of the material is hydrocarbon, which comprises less than 5% of the water ice‐dominated rings. Cassini's data also show that the influx varies at least a factor of 4 and may be linked to clumps that appeared in 2015 on D68, the ringlet on the inner edge of the rings. These newly discovered particles and processes alter the evolutionary landscape of the rings and provide an exciting, rich field for future research aimed at understanding the origin and history of the rings.
Key Points
Atmospheric drag, an interaction newly applied to Saturn and its rings, extracts >104 kg/s of neutral nanoparticles from Saturn's rings
Molecules and particles <2 nm in radius are preferentially transported by atmospheric drag
Neutral, nanometer‐sized hydrocarbon material is currently the largest mass loss from Saturn's rings
Analysis of measurements of the H2 density in Saturn's equatorial thermosphere indicates temperatures from 340 to 370 K. The deepest measurements, obtained during Cassini's final plunge into the ...atmosphere, measure the thermospheric temperature profile. The measurements are well fit by a Bates profile with an exospheric temperature of 354 K and a temperature gradient at 1.2 × 10−4 Pa of 0.4 K/km, corresponding to a thermal conduction flux of 7.3 × 10−5 W/m2. The helium profiles are consistent with diffusive equilibrium. The CH4 profiles are not in diffusive equilibrium but instead have a roughly constant mixing ratio relative to H2. We interpret this as the signature of a downward external flux of ∼1013 m−2 s−1. Saturn's rings are the most likely source of this external material.
Plain Language Summary
The mass spectrometer on the Cassini spacecraft measured the densities of molecular hydrogen, helium, and methane, among other species, along the spacecraft track through the atmosphere. Analyzing these data determines the temperature structure of the upper atmosphere. We find temperatures of 340 to 370 K. We also find that the methane in the upper atmosphere comes from Saturn's rings rather than the lower atmosphere.
Key Points
Cassini INMS measured the distribution of H2, He, and CH4 in Saturn's equatorial thermosphere
The exospheric temperature varies from 340 to 370 K
The CH4 distribution indicates an external flux of ∼1013 m−2 s−1
•We provide INMS density data for six Enceladus encounters.•Ice grains affect INMS measurements and their uncertainty.•Mass-dependent thermal velocity modifies jet composition.
During six encounters ...between 2008 and 2013, the Cassini Ion and Neutral Mass Spectrometer (INMS) made in situ measurements deep within the Enceladus plumes. Throughout each encounter, those measurements contained density variations that reflected the nature of the source, particularly of the high-velocity jets. Since the dominant constituent of the vapor, H2O, interacted with the walls of the INMS inlet, we track changes in the external vapor density by using more-volatile species that responded promptly to those changes. However, the most-abundant volatiles, at 28u and 44u, behaved differently from each other in the plume. At least a portion of their differences may be attributed to mass-dependent thermal velocity that affects Mach number in the high-velocity jets. Variations between volatiles place an emphasis on modeling as a means to construct overall plume density from the volatile densities and to investigate the velocity, gas temperature, and location of the jets. Ice grains, entering the INMS aperture add complexity and uncertainty to the physical interpretation of the data because the grains modified the INMS measurements. A comparison of data from the last three encounters, E14, E17, and E18, are consistent with the VIMS observation of variability in jet production and a slower, more diffuse gas flux from the four sulci or tiger stripes. We provide and describe the INMS data, its processing, and its uncertainty.
Molecular docking is a powerful tool used in drug discovery and structural biology for predicting the structures of ligand–receptor complexes. However, the accuracy of docking calculations can be ...limited by factors such as the neglect of protein reorganization in the scoring function; as a result, ligand screening can produce a high rate of false positive hits. Although absolute binding free energy methods still have difficulty in accurately rank-ordering binders, we believe that they can be fruitfully employed to distinguish binders from nonbinders and reduce the false positive rate. Here we study a set of ligands that dock favorably to a newly discovered, potentially allosteric site on the flap of HIV-1 protease. Fragment binding to this site stabilizes a closed form of protease, which could be exploited for the design of allosteric inhibitors. Twenty-three top-ranked protein–ligand complexes from AutoDock were subject to the free energy screening using two methods, the recently developed binding energy analysis method (BEDAM) and the standard double decoupling method (DDM). Free energy calculations correctly identified most of the false positives (≥83%) and recovered all the confirmed binders. The results show a gap averaging ≥3.7 kcal/mol, separating the binders and the false positives. We present a formula that decomposes the binding free energy into contributions from the receptor conformational macrostates, which provides insights into the roles of different binding modes. Our binding free energy component analysis further suggests that improving the treatment for the desolvation penalty associated with the unfulfilled polar groups could reduce the rate of false positive hits in docking. The current study demonstrates that the combination of docking with free energy methods can be very useful for more accurate ligand screening against valuable drug targets.
Cassini Ion Neutral Mass Spectrometer (INMS) measurements from roughly a hundred Titan encounters over the Cassini mission yield neutral and ion densities systematically lower, by factors ...approximately 2 to 3, than estimates from several other spacecraft systems, including the Attitude and Articulation Control System, and Navigation system. In this paper we present a new INMS instrument sensitivity model, obtained by re-analyzing (1) the capture and transmission of neutral gas through the instrument, and (2) the detector gain reduction during pre-launch testing. By correcting for an under-estimation of gas leakage out of the instrument into space by the original calibration model, and adjusting for the gain change, the new model brings INMS densities into much closer agreement with the other Cassini systems. Accordingly, the INMS ion densities are revised upward by a constant detector sensitivity correction factor of 1.55±21 %, while the neutral sensitivities have a complex instrument pointing direction dependence, due (mostly) to the effect of the INMS vent and antechamber-to-closed source tube. In the special case of on-ram pointing the neutral densities are revised upward by a constant factor of 2.2±23 %. The corrected neutral and ion sensitivities given here are applicable to all previously published INMS results at Titan, Enceladus and elsewhere in the Saturn system. The new model gives reliable densities at high ram angles, in some cases above 90 degrees, thereby expanding the list of Titan flybys from which INMS densities may be extracted. We apply the model to obtain accurate densities from several off-ram Titan flybys which gave unusual neutral density vs. altitude profiles, or unreasonably high densities, with the original calibration.
During Cassini's Grand Finale, the spacecraft flew between Saturn's upper atmosphere and its innermost ring, the D ring. Throughout these final orbits, Cassini encountered material flowing from the D ...ring into Saturn's atmosphere. Here, we present a compositional analysis of this material using data collected by Cassini's Ion Neutral Mass Spectrometer. We confirm the identification of CH4, CO2, CO, N2, H2O, NH3, and organics in the ring material, and provide upper limits for organic compounds of interest. The H/C, O/C, N/C, and S/C ratios of ring material are constrained using three different kinds of model spectra: automated fits, hand fits of inorganics + hydrocarbons, and hand fits of inorganics + organics with priority given to O-, N-, and S-bearing organics. Additionally, we compare data from the final plunge to earlier orbits, and find that ring material can be divided into gas and dust constituents, with CO2 at the volatility boundary between the two phases. At increasing distance above the equatorial plane, the gas/dust molar ratio increases.
•INMS measured complex material from the D ring during the Cassini Grand Finale.•This material is ~20% water and ~35% non-methane organics by mass.•Constraints on elemental ratios of the ring material are presented.•Ring material is latitudinally fractionated according to gas and dust components.
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