Entrepreneurship has been viewed as a critical contributor and an economic engine in a country for creating new jobs and it is crucial for graduates to alter their mindset to become self-employed. ...Thus, it is necessary to synthesize the factors that impact the entrepreneurial intentions (EI) of students at tertiary level. The aim of this research is twofold; first to identify the factors which have been most studied in the literature and second, to determine which factors are less explored to measure the EI of students. This research adopts the systematic review approach to identify various studies conducted between 2005 to June 2022. The paper further adopted citation analysis and identified the 36 most impactful studies in this area of research. Next, the thematic analysis was conducted and seven main themes (factors) (cognitive, personality, environmental, social, educational, contextual and demographic) of EI determinants were identified. The analysis of the papers clearly demonstrated that the TPB model and cognitive factors dominate this area of research. Furthermore, over half of the studies are conducted in Asia, hence it is important to explore other regions such as Africa, America and Europe and other comparative studies between various regions. The study offers avenues for future research and practical implications of the study for the practitioners.
To probe the role of the supramolecular steric effects and free volume on photoreactions, geometric isomerization of neutral azobenzenes (ABs) and their radical ions, generated by electron transfer ...with gold nanoparticles, included within an octa acid capsule, was investigated. A comparison of the isomerization of ABs that proceed by volume conserving pyramidalization and stilbene analogues that proceed by volume demanding one bond flip has indicated the differing influence of 4-alkyl groups on these two processes.
Abstract
We present numerical simulations of misaligned disks around a spinning black hole covering a range of parameters. Previous simulations have shown that disks that are strongly warped by a ...forced precession—in this case, the Lense–Thirring effect from the spinning black hole—can break apart into discrete disks or rings that can behave quasi-independently for short timescales. With the simulations we present here, we confirm that thin and highly inclined disks are more susceptible to disk tearing than thicker disks or those with lower inclination, and we show that lower values of the disk viscosity parameter lead to instability at lower warp amplitudes. This is consistent with detailed stability analysis of the warped disk equations. We find that the growth rates of the instability seen in the numerical simulations are similar across a broad range of parameters, and are of the same order as the predicted growth rates. However, we did not find the expected trend of growth rates with viscosity parameter. This may indicate that the growth rates are affected by numerical resolution, or that the wavelength of the fastest-growing mode is a function of local disk parameters. Finally, we also find that disk tearing can occur for disks with a viscosity parameter that is higher than predicted by a local stability analysis of the warped disk equations. In this case, the instability manifests differently, producing large changes in the disk tilt locally in the disk, rather than the large changes in disk twist that typically occur in lower-viscosity disks.
In the present work, superparamagnetic adsorbents based on 3-aminopropyltrimethoxy silane (APTMS)-coated maghemite (γFe2O3@SiO2–NH2) and cobalt ferrite (CoFe2O4@SiO2–NH2) nanoparticles were prepared ...and characterized using transmission-electron microscopy (TEM/HRTEM/EDXS), Fourier-transform infrared spectroscopy (FTIR), specific surface-area measurements (BET), zeta potential (ζ) measurements, thermogravimetric analysis (TGA), and magnetometry (VSM). The adsorption of Dy3+, Tb3+, and Hg2+ ions onto adsorbent surfaces in model salt solutions was tested. The adsorption was evaluated in terms of adsorption efficiency (%), adsorption capacity (mg/g), and desorption efficiency (%) based on the results of inductively coupled plasma optical emission spectrometry (ICP-OES). Both adsorbents, γFe2O3@SiO2–NH2 and CoFe2O4@SiO2–NH2, showed high adsorption efficiency toward Dy3+, Tb3+, and Hg2+ ions, ranging from 83% to 98%, while the adsorption capacity reached the following values of Dy3+, Tb3+, and Hg2+, in descending order: Tb (4.7 mg/g) > Dy (4.0 mg/g) > Hg (2.1 mg/g) for γFe2O3@SiO2–NH2; and Tb (6.2 mg/g) > Dy (4.7 mg/g) > Hg (1.2 mg/g) for CoFe2O4@SiO2–NH2. The results of the desorption with 100% of the desorbed Dy3+, Tb3+, and Hg2+ ions in an acidic medium indicated the reusability of both adsorbents. A cytotoxicity assessment of the adsorbents on human-skeletal-muscle derived cells (SKMDCs), human fibroblasts, murine macrophage cells (RAW264.7), and human-umbilical-vein endothelial cells (HUVECs) was conducted. The survival, mortality, and hatching percentages of zebrafish embryos were monitored. All the nanoparticles showed no toxicity in the zebrafish embryos until 96 hpf, even at a high concentration of 500 mg/L.
This teaching note presents an assignment in which students write an op-ed on a course-related issue and submit it to a newspaper. I argue that an op-ed assignment dovetails with pedagogical goals ...around democratic citizenship and public sociology. I explain the project’s objectives, instructions, and timeline. I present evidence from three courses showing that the assignment fostered understanding of op-eds’ form and function; deepened engagement with course-related issues; led many class members to apply their learning to a real-world civic setting; and generated high-quality work. I consider ways the project can be modified and used in other courses.
Phosphorescence from pyrene especially at room temperature is uncommon. This emission was recorded utilizing a supramolecular organic host and the effect due to the heavy atom. Poor intersystem ...crossing from S1 to T1, small radiative rate constant from T1, and large rate constant for oxygen quenching hinder the phosphorescence of aromatic molecules at room temperature in solution. In this study, these limitations are overcome by encapsulating a pyrene molecule within a water-soluble capsule (octa acid, OA) and purging with xenon. While OA suppressed oxygen quenching, xenon enabled the intersystem crossing from S1 to T1 and radiative process from T1 to S0 through the well-known heavy atom effect. The close interaction facilitated between the pyrene and the heavy atom perturber xenon in the three-component supramolecular assembly (OA, pyrene, and xenon) resulted in phosphorescence from pyrene. Computational modeling and NMR studies supported the postulate that pyrene and more than one molecule of xenon are present within a confined space of the OA capsule.
•Decide the optimum location and size of DSTATCOM and DG.•Diagnosis the dynamic issues in power system under various environments.•DSTATCOM and DG are detected using loss sensitivity factor ...(LSF).•Optimum location is determined by using Dwarf Mongoose Optimization.•DMO decide the optimum size of DSTATCOM and DG.
This manuscript proposes a novel method to decide the optimum location and size of Distribution static compensator (DSTATCOM) and Distribution Generation (DG) are examined. For lessening the loss of power, voltage profile improvement and operation costs of system, the objective function is used under the constraints of equality and inequality. The aim of proposed method is diagnosis the dynamic issues present in the power system under various environments, like healthy conditions and unhealthy conditions. The primary location of both Distribution Generation and Distribution static compensator are detected by using the loss sensitivity factor (LSF). The final optimum location is determined by using Dwarf Mongoose Optimization (DMO) method. The DMO is used to decide the optimum size of Distribution Generation and Distribution static compensator. The aim of the proposed method is an integrated approach of loss sensitivity factor and Dwarf Mongoose Optimization to decide the optimum location and size of Distribution Generation and DSTATCOM for diminishing the loss of power, voltage profile improvement and operation cost. The Distribution Generation and DSTATCOM are simultaneously placed in radial DG. The LSF is used earlier to detect the optimum location of Distribution Generation and Distribution static compensator. The proposed system is performed in MATLAB or Simulink site and the performance of dynamic stability is tested with IEEE standard bench mark systems.
A new silica-gel nanospheres (SiO2NPs) composition was formulated, followed by biochemical surface functionalization to examine its potential in urea biosensor development. The SiO2NPs were basically ...synthesized based on sol-gel chemistry using a modified Stober method. The SiO2NPs surfaces were modified with amine (-NH2) functional groups for urease immobilization in the presence of glutaric acid (GA) cross-linker. The chromoionophore pH-sensitive dye ETH 5294 was physically adsorbed on the functionalized SiO2NPs as pH transducer. The immobilized urease determined urea concentration reflectometrically based on the colour change of the immobilized chromoionophore as a result of the enzymatic hydrolysis of urea. The pH changes on the biosensor due to the catalytic enzyme reaction of immobilized urease were found to correlate with the urea concentrations over a linear response range of 50-500 mM (R2 = 0.96) with a detection limit of 10 mM urea. The biosensor response time was 9 min with reproducibility of less than 10% relative standard deviation (RSD). This optical urea biosensor did not show interferences by Na+, K+, Mg2+ and NH4+ ions. The biosensor performance has been validated using urine samples in comparison with a non-enzymatic method based on the use of p-dimethylaminobenzaldehyde (DMAB) reagent and demonstrated a good correlation between the two different methods (R2 = 0.996 and regression slope of 1.0307). The SiO2NPs-based reflectometric urea biosensor showed improved dynamic linear response range when compared to other nanoparticle-based optical urea biosensors.
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