We measured the gas abundance profiles in a sample of 122 face-on spiral galaxies observed by the CALIFA survey and included all spaxels whose line emission was consistent with star formation. This ...type of analysis allowed us to improve the statistics with respect to previous studies, and to properly estimate the oxygen distribution across the entire disc to a distance of up to 3−4 disc effective radii (re). We confirm the results obtained from classical H ii region analysis. In addition to the general negative gradient, an outer flattening can be observed in the oxygen abundance radial profile. An inner drop is also found in some cases. There is a common abundance gradient between 0.5 and 2.0 re of αO / H = − 0.075 dex /re with a scatter of σ = 0.016 dex /re when normalising the distances to the disc effective radius. By performing a set of Kolmogorov-Smirnov tests, we determined that this slope is independent of other galaxy properties, such as morphology, absolute magnitude, and the presence or absence of bars. In particular, barred galaxies do not seem to display shallower gradients, as predicted by numerical simulations. Interestingly, we find that most of thegalaxies in the sample with reliable oxygen abundance values beyond ~2 effective radii (57 galaxies) present a flattening of the abundance gradient in these outer regions. This flattening is not associated with any morphological feature, which suggests that it is a common property of disc galaxies. Finally, we detect a drop or truncation of the abundance in the inner regions of 27 galaxies in the sample; this is only visible for the most massive galaxies.
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Nitrogen-doped ordered mesoporous carbons were synthesized by chemical vapor deposition, using acetonitrile as carbon and nitrogen source and SBA-15 as mesoporous silica template. ...Their porous texture, structural order and surface chemistry were studied as a function of the experimental conditions (acetonitrile stream concentration and deposition time). A non-doped ordered mesoporous carbon was also prepared by the same procedure using propylene as carbon source. Methylene blue, methyl orange and fuchsin acid were selected as probe molecules to investigate the dye adsorption behavior on the ordered mesoporous carbons. Both N-doped and non-doped ordered mesoporous carbons adsorbed large amounts of these three dyes demonstrating the importance of mesoporosity, especially for the adsorption of larger dyes (e.g. fuchsin acid). The presence of nitrogen functional groups was detrimental for the adsorption of the basic dye (methylene blue). On the other hand, the nitrogen functionalities improved the adsorption kinetics for both acid and basic dyes, and the N-doped samples achieved 100% of their maximum adsorption capacities in less than 15min.
We demonstrate the feasibility and potential of using large integral field spectroscopic surveys to investigate the prevalence of galactic-scale outflows in the local Universe. Using integral field ...data from the Sydney-AAO Multi-object Integral field spectrograph (SAMI) and the Wide Field Spectrograph, we study the nature of an isolated disc galaxy, SDSS J090005.05+000446.7 (z = 0.053 86). In the integral field data sets, the galaxy presents skewed line profiles changing with position in the galaxy. The skewed line profiles are caused by different kinematic components overlapping in the line-of-sight direction. We perform spectral decomposition to separate the line profiles in each spatial pixel as combinations of (1) a narrow kinematic component consistent with H ii regions, (2) a broad kinematic component consistent with shock excitation, and (3) an intermediate component consistent with shock excitation and photoionization mixing. The three kinematic components have distinctly different velocity fields, velocity dispersions, line ratios, and electron densities. We model the line ratios, velocity dispersions, and electron densities with our mappings iv shock and photoionization models, and we reach remarkable agreement between the data and the models. The models demonstrate that the different emission line properties are caused by major galactic outflows that introduce shock excitation in addition to photoionization by star-forming activities. Interstellar shocks embedded in the outflows shock-excite and compress the gas, causing the elevated line ratios, velocity dispersions, and electron densities observed in the broad kinematic component. We argue from energy considerations that, with the lack of a powerful active galactic nucleus, the outflows are likely to be driven by starburst activities. Our results set a benchmark of the type of analysis that can be achieved by the SAMI Galaxy Survey on large numbers of galaxies.
STATCONT is a python-based tool designed to determine the continuum emission level in spectral data, in particular for sources with a line-rich spectrum. The tool inspects the intensity distribution ...of a given spectrum and automatically determines the continuum level by using different statistical approaches. The different methods included in STATCONT are tested against synthetic data. We conclude that the sigma-clipping algorithm provides the most accurate continuum level determination, together with information on the uncertainty in its determination. This uncertainty can be used to correct the final continuum emission level, resulting in the here called ‘corrected sigma-clipping method’ or c-SCM. The c-SCM has been tested against more than 750 different synthetic spectra reproducing typical conditions found towards astronomical sources. The continuum level is determined with a discrepancy of less than 1% in 50% of the cases, and less than 5% in 90% of the cases, provided at least 10% of the channels are line free. The main products of STATCONT are the continuum emission level, together with a conservative value of its uncertainty, and datacubes containing only spectral line emission, i.e., continuum-subtracted datacubes. STATCONT also includes the option to estimate the spectral index, when different files covering different frequency ranges are provided.
•Chitosan oligosaccharides (COS) were prepared by an enzymatic one-step process (P1).•COS P2 were prepared by two-step process combining chemical and enzymatic reaction.•COS P2 was composed of a ...great proportion of fully deacetylated sequences (63%).•COS P1 showed the strongest growth inhibition for E. coli and L. monocytogenes.•N-acetyl-glucosamine sequences are necessary to exert good antibacterial capacity.
The bioactivities of chitooligosaccharides are markedly influenced by the degree of acetylation, degree of polymerization or molecular weight and pattern of acetylation. Thus, it is crucial to identify reproducible processes that will give rise to well-defined chitooligosaccharides and establish methods for their posterior physicochemical characterization in order to advance in the knowledge of their bioactivity. Chitooligosaccharides were prepared by two different processes. The first used chitosanase enzymatic hydrolysis and the second consisted of a two-step procedure based on chemical hydrolysis followed by chitosanase hydrolysis. Chitooligosaccharides produced in the second process were composed of 63 % of fully deacetylated sequences and inhibited the growth of Escherichia coli and Listeria monocytogenes. Better antibacterial activity was found for those obtained in the first process composed of 27 % of fully deacetylated sequences. Therefore, a low percentage of free amino groups and the presence of acetylated sequences are necessary in these molecules to exert good antibacterial capacity.
ABSTRACT The "main sequence of galaxies"-defined in terms of the total star formation rate versus the total stellar mass M*-is a well-studied tight relation that has been observed at several ...wavelengths and at different redshifts. All earlier studies have derived this relation from integrated properties of galaxies. We recover the same relation from an analysis of spatially resolved properties, with integral field spectroscopic (IFS) observations of 306 galaxies from the CALIFA survey. We consider the SFR surface density in units of log(M yr−1 Kpc−2) and the stellar mass surface density in units of log(M Kpc−2) in individual spaxels that probe spatial scales of 0.5-1.5 Kpc. This local relation exhibits a high degree of correlation with small scatter ( = 0.23 dex), irrespective of the dominant ionization source of the host galaxy or its integrated stellar mass. We highlight (i) the integrated star formation main sequence formed by galaxies whose dominant ionization process is related to star formation, for which we find a slope of 0.81 0.02; (ii) for the spatially resolved relation obtained with the spaxel analysis, we find a slope of 0.72 0.04; and (iii) for the integrated main sequence, we also identified a sequence formed by galaxies that are dominated by an old stellar population, which we have called the retired galaxies sequence.
We demonstrate a novel technology that combines the power of the multi-object spectrograph with the spatial multiplex advantage of an integral field spectrograph (IFS). The Sydney-AAO (Australian ...Astronomical Observatory) Multi-object IFS (SAMI) is a prototype wide-field system at the Anglo-Australian Telescope (AAT) that allows 13 imaging fibre bundles ('hexabundles') to be deployed over a 1-degree diameter field of view. Each hexabundle comprises 61 lightly fused multi-mode fibres with reduced cladding and yields a 75 per cent filling factor. Each fibre core diameter subtends 1.6 arcsec on the sky and each hexabundle has a field of view of 15 arcsec diameter. The fibres are fed to the flexible AAOmega double-beam spectrograph, which can be used at a range of spectral resolutions (R=λ/δλ≈ 1700-13 000) over the optical spectrum (3700-9500 Å). We present the first spectroscopic results obtained with SAMI for a sample of galaxies at z≈ 0.05. We discuss the prospects of implementing hexabundles at a much higher multiplex over wider fields of view in order to carry out spatially resolved spectroscopic surveys of 104-105 galaxies.
We present the largest and most homogeneous catalog of H ii regions and associations compiled so far. The catalog comprises more than 7000 ionized regions, extracted from 306 galaxies observed by the ...CALIFA survey. We describe the procedures used to detect, select, and analyze the spectroscopic properties of these ionized regions. In the current study we focus on characterizing of the radial gradient of the oxygen abundance in the ionized gas, based on the study of the deprojecteddistribution of H ii regions. We found that all galaxies without clear evidence of an interaction present a common gradient in the oxygen abundance, with a characteristic slope of αO/H = −0.1 dex/re between 0.3 and 2 disk effective radii (re), and a scatter compatible with random fluctuations around this value, when the gradient is normalized to the disk effective radius. The slope is independent of morphology, the incidence of bars, absolute magnitude, or mass. Only those galaxies with evidence of interactions and/or clear merging systems present a significantly shallower gradient, consistent with previous results. The majority of the 94 galaxies with H ii regions detected beyond two disk effective radii present a flattening in the oxygen abundance. The flattening is statistically significant. We cannot provide a conclusive answer regarding the origin of this flattening. However, our results indicate that its origin is most probably related to the secular evolution of galaxies. Finally, we find a drop/truncation of the oxygen abundance in the inner regions for 26 of the galaxies. All of them are non-interacting, mostly unbarred Sb/Sbc galaxies. This feature is associated with a central star-forming ring, which suggests that both features are produced by radial gas flows induced by resonance processes. Our result suggests that galaxy disks grow inside-out, with metal enrichment driven by the local star formation history and with a small variation galaxy-by-galaxy. At a certain galactocentric distance, the oxygen abundance seems to be correlated well with the stellar mass density and total stellar mass of the galaxies, independently of other properties of the galaxies. Other processes, such as radial mixing and inflows/outflows seem to have a limited effect on shaping of the radial distribution of oxygen abundances, although they are not ruled out.
We use deep integral field spectroscopy data from the CALIFA survey to study the warm interstellar medium (wim) over the entire extent and optical spectral range of 32 nearby early-type galaxies ...(ETGs). We find that faint nebular emission is extended in all cases, and its surface brightness decreases roughly as ∝ r−α. The large standard deviation in the derived α (1.09 ± 0.67) argues against a universal power-law index for the radial drop-off of nebular emission in ETGs. Judging from the properties of their extranuclear component, our sample ETGs span a broad, continuous sequence with respect to their α, Hα equivalent width (EW) and Lyman continuum (Lyc) photon leakage fraction (plf). We propose a tentative subdivision into two groups: Type i ETGs are characterized by rather steep Hα profiles (α ≃ 1.4), comparatively large (≳1 Å), nearly radially constant EWs, and plf ≃ 0. Photoionization by post-AGB stars appears to be the main driver of extended nebular emission in these systems, with nonthermal sources being potentially important only in their nuclei. Typical properties of type ii ETGs are shallower Hα profiles (α ≃ 0.8), very low (≲0.5 Å) EWs with positive radial gradients, and a mean plf ≳ 0.7, rising to ≳0.9 in their centers. Such properties point to a low, and inwardly decreasing wim density and/or volume filling factor. We argue that, because of extensive Lyc photon leakage, emission-line luminosities and EWs are reduced in type ii ETG nuclei by at least one order of magnitude. Consequently, the line weakness of these ETGs is by itself no compelling evidence for their containing merely “weak”(sub-Eddington accreting) active galactic nuclei (AGN). In fact, Lyc photon escape, which has heretofore not been considered, may constitute a key element in understanding why many ETGs with prominent signatures of AGN activity in radio continuum and/or X-ray wavelengths show only faint emission lines and weak signatures of AGN activity in their optical spectra. The Lyc photon escape, in conjunction with dilution of nuclear EWs by line-of-sight integration through a triaxial stellar host, can systematically impede detection of AGN in gas-poor galaxy spheroids through optical emission-line spectroscopy, thereby leading to an observational bias. We further find that type i&ii ETGs differ little (≲0.4 dex) in their mean BPT line ratios, which in both cases are characteristic of LINERs and are, within their uncertainties, almost radius-independent. This potentially hints at a degeneracy of the projected, luminosity-weighted BPT ratios in the LINER regime, for the specific 3D properties of the wim and the ionizing photon field in ETGs.
Spiral arms are the most singular features in disc galaxies. These structures can exhibit different patterns, namely grand design and flocculent arms, with easily distinguishable characteristics. ...However, their origin and the mechanisms shaping them are unclear. The overall role of spirals in the chemical evolution of disc galaxies is another unsolved question. In particular, it has not been fully explored if the H ii regions of spiral arms present different properties from those located in the interarm regions. Here we analyse the radial oxygen abundance gradient of the arm and interarm star forming regions of 63 face-on spiral galaxies using CALIFA Integral Field Spectroscopy data. We focus the analysis on three characteristic parameters of the profile: slope, zero-point, and scatter. The sample is morphologically separated into flocculent versus grand design spirals and barred versus unbarred galaxies. We find subtle but statistically significant differences betweenthe arm and interarm distributions for flocculent galaxies, suggesting that the mechanisms generating the spiral structure in these galaxies may be different to those producing grand design systems, for which no significant differences are found. We also find small differences in barred galaxies, not observed in unbarred systems, hinting that bars may affect the chemical distribution of these galaxies but not strongly enough as to be reflected in the overall abundance distribution. In light of these results, we propose bars and flocculent structure as two distinct mechanisms inducing differences in the abundance distribution between arm and interarm star forming regions.
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