Measurements of aerosol chemical composition made on the island of Lampedusa, south of the Sicily channel, during years 2004–2008, are used to identify the influence of heavy fuel oil (HFO) ...combustion emissions on aerosol particles in the Central Mediterranean. Aerosol samples influenced by HFO are characterized by elevated Ni and V soluble fraction (about 80% for aerosol from HFO combustion, versus about 40% for crustal particles), high V and Ni to Si ratios, and values of Vsol>6 ng m−3. Evidence of HFO combustion influence is found in 17% of the daily samples. Back trajectories analysis on the selected events show that air masses prevalently come from the Sicily channel region, where an intense ship traffic occurs. This behavior suggests that single fixed sources like refineries are not the main responsible for the elevated V and Ni events, which are probably mainly due to ships emissions. Vsol, Nisol, and non-sea salt SO42− (nssSO42−) show a marked seasonal behaviour, with an evident summer maximum. Such a pattern can be explained by several processes: (i) increased photochemical activity in summer, leading to a faster production of secondary aerosols, mainly nssSO42−, from the oxidation of SO2 (ii) stronger marine boundary layer (MBL) stability in summer, leading to higher concentration of emitted compounds in the lowest atmospheric layers. A very intense event in spring 2008 was studied in detail, also using size segregated chemical measurements. These data show that elements arising from heavy oil combustion (V, Ni, Al, Fe) are distributed in the sub-micrometric fraction of the aerosol, and the metals are present as free metals, carbonates, oxides hydrates or labile complex with organic ligands, so that they are dissolved in mild condition (HNO3, pH1.5). Data suggest a characteristic nssSO42−/V ratio in the range 200–400 for HFO combustion aerosols in summer at Lampedusa. By using the value of 200 a lower limit for the HFO contribution to total sulphates is estimated. HFO combustion emissions account, as a summer average, at least for 1.2 μg m−3, representing about 30% of the total nssSO42−, 3.9% of PM10, 8% of PM2.5, and 11% of PM1. Within the used dataset, sulphate from HFO combustion emissions reached the peak value of 6.1 μg m−3 on 26 June 2008, when it contributed by 47% to nssSO42−, and by 15% to PM10.
The Mediterranean basin is characterized by large concentrations of aerosols from both natural and anthropogenic sources. These aerosols affect tropospheric photochemistry by modulating the ...photolytic rates. Three simulations of the atmospheric composition at basin scale have been performed with the CHIMERE chemistry-transport model for the period from 6 June to 15 July 2013 covered by the ADRIMED campaign, a campaign of intense measurements in the western Mediterranean basin. One simulation takes into account the radiative effect of the aerosols on photochemistry, the second one does not, and the third one is designed to quantify the model sensitivity to a bias in the ozone column. These simulations are compared to satellite and ground-based measurements, with a particular focus on the area of Lampedusa. Values of the aerosol optical depth (AOD) are obtained from the MODIS instrument on the AQUA and TERRA satellites as well as from stations in the AERONET network and from the MFRSR sun photometer deployed at Lampedusa. Additional measurements from instruments deployed at Lampedusa either permanently or exceptionally are used for other variables: MFRSR sun photometer for AOD, diode array spectrometer for actinic fluxes, LIDAR for the aerosol backscatter, sequential sampler for speciation of aerosol and Brewer spectrophotometer for the total ozone column. It is shown that CHIMERE has a significant ability to reproduce observed peaks in the AOD, which in Lampedusa are mainly due to dust outbreaks during the ADRIMED period, and that taking into account the radiative effect of the aerosols in CHIMERE considerably improves the ability of the model to reproduce the observed day-to-day variations of the photolysis rate of ozone to O2 and O(1D), J(O1D), and that of NO2 to NO and O(3P), J(NO2). While in the case of J(O1D) other variation factors such as the stratospheric ozone column are very important in representing correctly the day-to-day variations, the day-to-day variations of J(NO2) are captured almost completely by the model when the optical effects of the aerosols are taken into account. Finally, it is shown that the inclusion of the direct radiative effect of the aerosols in the CHIMERE model leads to reduced J(O1D) and J(NO2) values over all the simulation domain, which range from a few percents over continental Europe and the north-east Atlantic Ocean to about 20 % close to and downwind from Saharan dust sources. The effect on the modelled ozone concentration is 2-fold: the effect of aerosols leads to reduced ozone concentrations over the Mediterranean Sea and continental Europe, close to the sources of NOx, but it also leads to increased ozone concentrations over remote areas such as the Sahara and the tropical Atlantic Ocean.
The Mediterranean Basin atmosphere is influenced by both strong natural and anthropogenic aerosol emissions and is also subject to important climatic forcings. Several programs have addressed the ...study of the Mediterranean basin; nevertheless important pieces of information are still missing. In this framework, PM10 samples were collected on a daily basis on the island of Lampedusa (35.5 degree N, 12.6 degree E; 45 m a.s.l.), which is far from continental pollution sources (the nearest coast, in Tunisia, is more than 100 km away). After mass gravimetric measurements, different portions of the samples were analyzed to determine the ionic content by ion chromatography (IC), the soluble metals by inductively coupled plasma atomic emission spectrometry (ICP-AES), and the total (soluble + insoluble) elemental composition by particle-induced x-ray emission (PIXE). Data from 2007 and 2008 are used in this study. The Positive Matrix Factorization (PMF) model was applied to the 2-year long data set of PM10 mass concentration and chemical composition to assess the aerosol sources affecting the central Mediterranean basin. Seven sources were resolved: sea salt, mineral dust, biogenic emissions, primary particulate ship emissions, secondary sulfate, secondary nitrate, and combustion emissions. Source contributions to the total PM10 mass were estimated to be about 40 % for sea salt, around 25 % for mineral dust, 10 % each for secondary nitrate and secondary sulfate, and 5 % each for primary particulate ship emissions, biogenic emissions, and combustion emissions. Large variations in absolute and relative contributions are found and appear to depend on the season and on transport episodes. In addition, the secondary sulfate due to ship emissions was estimated and found to contribute by about one-third to the total sulfate mass. Results for the sea-salt and mineral dust sources were compared with estimates of the same contributions obtained from independent approaches, leading to an estimate of the water content bound to the sea salt in the marine source.
Multi-filter rotating shadowband radiometer (MFRSR) measurements have been carried out at Lampedusa (35.52°N, 12.63°E) in 1999, and continuously since 2001. This study describes the Saharan dust (SD) ...events at Lampedusa on the basis of daily average optical depth at 500
nm,
τ, and Ångström exponent,
α, derived from these observations. Back-trajectories ending at Lampedusa at 2000 and 4000
m altitude were calculated by means of the HYSPLIT model. SD events are identified as those for which the trajectories interact with the mixed layer in places where the surface wind exceeds 7
m
s
−1, or spend a large fraction of time over the Sahara. The SD days display values of
α+Δ
α⩽1, with Δ
α equal to the standard deviation of the daily
α. Out of 911 days with cloud-free intervals, 233 (26%) are classified as SD, and correspond to 111 episodes of various duration, from 1 to 13 consecutive days. The occurrence of SD events is maximum in summer (33%), when also the largest seasonal average of
τ (0.40) is measured, and minimum in winter (7%), when the smallest seasonal average of
α (0.08) is found. SD days have been identified from the back-trajectories also in days lacking of observations, due to either cloudiness or measurement interruptions. The frequency of occurrence of SD days shows little change with respect to the cloud-free periods (24%). The seasonal distribution shows a peak in May (38%), followed by July (37%). Regions of SD production were derived from the HYSPLIT trajectories and NCEP-reanalysis surface winds. Finally, the MFRSR measurements at the solar zenith angle of 60° have been used to derive the single scattering albedo (SSA) for cases clearly dominated by dust (
τ⩾0.40 and
α+Δ
α⩽0.5). The average SSA for the whole period is 0.77±0.04 at 415.6
nm and 0.94±0.04 at 868.7
nm.
Desert dust interacts with shortwave (SW) and longwave (LW) radiation, influencing the Earth radiation budget and the atmospheric vertical structure. Uncertainties on the dust role are large in the ...LW spectral range, where few measurements are available and the dust optical properties are not well constrained. The first airborne measurements of LW irradiance vertical profiles over the Mediterranean were carried out during the Ground‐based and Airborne Measurements of Aerosol Radiative Forcing (GAMARF) campaign, which took place in spring 2008 at the island of Lampedusa. The experiment was aimed at estimating the vertical profiles of the SW and LW aerosol direct radiative forcing (ADRF) and heating rates (AHR), taking advantage of vertically resolved measurements of irradiances, meteorological parameters, and aerosol microphysical and optical properties. Two cases, characterized respectively by the presence of a homogeneous dust layer (3 May, with aerosol optical depth, AOD, at 500 nm of 0.59) and by a low aerosol burden (5 May, with AOD of 0.14), are discussed. A radiative transfer model was initialized with the measured vertical profiles and with different aerosol properties, derived from measurements or from the literature. The simulation of the irradiance vertical profiles, in particular, provides the opportunity to constrain model‐derived estimates of the AHR. The measured SW and LW irradiances were reproduced when the model was initialized with the measured aerosol size distributions and refractive indices. For the dust case, the instantaneous (solar zenith angle, SZA, of 55.1°) LW‐to‐SW ADRF ratio was 23% at the surface and 11% at the top of the atmosphere (TOA), with a more significant LW contribution on a daily basis (52% at the surface and 26% at TOA), indicating a relevant reduction of the SW radiative effects. The AHR profiles followed the aerosol extinction profile, with comparable peaks in the SW (0.72 ± 0.11 K d−1) and in the LW (−0.52 ± 0.12 K d−1) for the considered SZA. On a daily basis, the absolute value of the heating rate was larger in the LW than in the SW, producing a net cooling effect at specific levels. These are quite unexpected results, emphasizing the important role of LW radiation.
Key Points
First measurements of longwave irradiance profiles in the Mediterranean
Dust radiative forcing and heating rate are constrained by airborne observations
Daily average shortwave and longwave dust heating rates are nearly compensated
The seasonal evolution of the aerosol vertical distribution in the Central Mediterranean is studied using measurements made in the period 1999–2008 at Lampedusa with an aerosol Lidar and a multi ...filter rotating shadowband radiometer (MFRSR). Measurements show that the aerosol vertical distribution is largely influenced by Saharan dust, which produces a strong annual cycle both in aerosol vertical extension and optical depth. Dust layers are present in the profile in 38% of the cases throughout the year, and in 57% in summer. The dust top altitude peaks in late spring, up to 9 km. The monthly average optical depth at 500 nm for dust cases shows a main peak in July (0.38), and values exceeding 0.2 throughout March–September. Conversely, non‐dust cases show a very limited seasonality, both in vertical distribution and aerosol optical depth. The monthly average optical depth for non‐dust cases is smaller than 0.17 throughout the year. During winter, the vertical distribution and optical depth are very similar for both dust and non‐dust cases. The seasonal average extinction coefficient profiles for dust and non‐dust cases show remarkable differences in spring and summer, when values of the extinction coefficient exceed 0.5 × 10−4 m−1 throughout the altitude range 0–4.5 km for dust cases, and 0–1 km altitude for non‐dust cases, respectively. Estimates of the Lidar Ratio are derived by combining Lidar and MFRSR measurements. The average Lidar Ratio at 532 nm is about 30 sr.
Saharan dust (SD) episodes occurring at the Mediterranean island of Lampedusa (35.52° N, 12.63° E) from May 1999 to December 2005 have been shown to occur in the 26% of the cloud-free days Meloni, ...D., di Sarra, A., Biavati, G., DeLuisi, J.J., Monteleone, F., Pace, G., Piacentino, S., Sferlazzo, D.M., 2007. Seasonal behavior of Saharan dust events at the Mediterranean island of Lampedusa in the period 1999–2005, Atmos. Environ. 41, 3041–3056. In this paper we focus on intense SD events detected until September 2006, characterized by large values of the Saharan Dust Event Index (SDEI), the sum of the daily average aerosol optical depth at 500 nm,
τ, over the duration of the dust episode. The SDEI index provides an indication about the intensity of SD events, due either to a long duration and/or to high dust optical depth. A total of 24 episodes characterized by large values of SDEI are examined. The NCEP-based maps of geopotential height and temperature at 700 mbar are used to identify the main circulation patterns driving SD to the Central Mediterranean and Lampedusa.
Dust transport episodes in summer last for several days, and the corresponding SDEI values are the highest of the year. These episodes are mainly governed by two circulation patterns: the trough extending near the Atlantic coast of Europe and the high pressure system present in North Africa, generally above 25° N. This configuration causes strong south-westerly flows from the Sahara towards Southern Italy. The time evolution of
τ for these long SD events shows that the largest values (>
0.3) are usually observed when the two patterns are present simultaneously, while low (<
0.3)
τ values are measured when the Atlantic trough influence is weak. Moreover, the most probable loading region typically shows a warm kernel in North-Western Sahara, with a tongue extending north-eastward towards Sicily.
In spring, moderate to high
τ are measured, and SD episodes last as long as 13 days. Two synoptic configurations can be distinguished. Days with large
τ are associated with the 700 mbar geopotential height features typical of summer. Days with moderate
τ are found to be characterized by the Saharan high, but with the close low replaced by the Atlantic trough descending West of Africa or above the Iberian peninsula.
In winter the typical meteorological conditions are determined by the presence of westerly cyclones. Depressions centered over Portugal, Central/Northern Europe, and Western Mediterranean have been shown to drive dust transport to Lampedusa.
This study aims to determine the mineral contribution to PM10 in the central Mediterranean Sea, based on 7 yr of daily PM10 samplings made on the island of Lampedusa (35.5° N, 12.6° E). The chemical ...composition of the PM10 samples was determined by ion chromatography for the main ions, and, on selected samples, by particle-induced X-ray emission (PIXE) for the total content of crustal markers. Aerosol optical depth measurements were carried out in parallel to the PM10 sampling. The average PM10 concentration at Lampedusa over the period June 2004–December 2010 is 31.5 μg m−3, with low interannual variability. The annual means are below the EU annual standard for PM10, but 9.9% of the total number of daily data exceeds the daily threshold value established by the European Commission for PM (50 μg m−3, European Community, EC/30/1999). The Saharan dust contribution to PM10 was derived by calculating the contribution of Al, Si, Fe, Ti, non-sea-salt (nss) Ca, nssNa, and nssK oxides in samples in which PIXE data were available. Cases in which crustal content exceeded the 75th percentile of the crustal oxide content distribution were identified as elevated dust events. Using this threshold, we obtained 175 events. Fifty-five elevated dust events (31.6%) displayed PM10 higher than 50 μg m−3, with dust contributing by 33% on average. The crustal contribution to PM10 has an annual average value of 5.42 μg m−3, and reaches a value as high as 67.9 μg m−3 (corresponding to 49% of PM10) during an intense Saharan dust event. The crustal content estimated from a single tracer, such as Al or Ca, is in good agreement with the one calculated as the sum of the metal oxides. Conversely, larger crustal contents are derived by applying the EU guidelines for demonstration and subtraction of exceedances in PM10 levels due to high background of natural aerosol. The crustal aerosol amount and contribution to PM10 showed a very small seasonal dependence; conversely, the dust columnar burden displays an evident annual cycle, with a strong summer maximum (monthly average aerosol optical depth at 500 nm up to 0.28 in June–August). We found that 71.3% of the dust events identified from optical properties over the atmospheric column display a high dust content at the ground level. Conversely, the remaining 28.7% of cases present a negligible or small impact on the surface aerosol composition due to the transport processes over the Mediterranean Sea, where dust frequently travels above the marine boundary layer, especially in summer. Based on backward trajectories, two regions, one in Algeria–Tunisia, and one in Libya, are identified as main source areas for intense dust episodes occurring mainly in autumn and winter. Data on the bulk composition of mineral aerosol arising from these two source areas are scarce; results on characteristic ratios between elements show somewhat higher values of Ca / Al and (Ca + Mg) / Fe (2.5 ± 1.0, and 4.7 ± 2.0, respectively) for Algeria–Tunisia than for Libyan origin (Ca / Al = 1.9 ± 0.7 and (Ca + Mg) / Fe = 3.3 ± 1.1).
The coupling between oceanic and atmospheric sulfur cycles is fundamental for the understanding of the role of sulfate particles as potential climate regulators. We discuss existing relationships ...among methanesulfonate (MS− – one of the end products of oxidation of biogenic dimethylsulfide – DMS) in the atmospheric particulate, phytoplankton biomass, and remotely-sensed activity in the central Mediterranean. The MS− concentration in the aerosol particles is based on PM10 sampling (from 2005 to 2008) of atmospheric aerosols at the island of Lampedusa (35.5°N, 12.6°E) in the central Mediterranean Sea.
The marine primary production in the sea sector surrounding the sampling site is obtained by using Ocean Color remote sensed data (SeaWiFS, MODIS-Aqua). In particular, primary production is calculated using a bio-optical model of sea reflectance and a Wavelength-Depth-Resolved Model (WDRM), fed by elaborated satellite data (chlorophyll concentration in the euphotic layer – Chl, sea surface temperature) and daily solar surface irradiance measurements.
The multi-year evolution of MS− atmospheric concentration shows a well-defined seasonal cycle with a summer maximum, corresponding to the annual peak of solar radiation and a minimum of phytoplankton biomass (expressed as Chl).
Statistically significant linear relationships between monthly means of atmospheric MS− and both the phytoplankton productivity index PB (r2 = 0.84, p < 0.001) and the solar radiation dose (SRD; r2 = 0.87, p < 0.001) in the upper mixed layer of the sea around Lampedusa are found. These correlations are mainly driven by the common seasonal pattern and suggest that DMS production in the marine surface layer is mainly related to the phytoplankton physiology. High values of PB are also the expression of stressed cells. The main stress factors in Mediterranean Sea during summer are high irradiance and shallow depth of the upper mixed layer, which lead to enhanced DMS emissions and higher MS− amounts in the atmosphere.
During spring 2005 high biomass and primary productivity values are observed in February and April, just one month before the peaks of atmospheric MS− (March and May). The occurrence of anomalously high values at this time is hypothesized to be related to the negative phase of the North Atlantic Oscillation, and to related oceanic and atmospheric processes. The possible role of the taxonomic composition of phytoplankton assemblages is also discussed.
•Primary production is calculated for the sea around Lampedusa by bio-optical and WDRM models.•Significant relationship between atmospheric MS− and productivity index is found.•Significant relationship between atmospheric MS− and solar radiation dose is found.•MS− is related to the phytoplankton physiology, in turn related to variation of stress factors.•High MS− concentrations in spring 2005 could be related to NAO negative phase.
Analysis of time series and trends of nitrous oxide (N
2O) and halocompounds weekly monitored at the Mediterranean island of Lampedusa are discussed. Atmospheric N
2O levels showed a linear upward ...growth rate of 0.78
ppb yr
−1 and mixing ratios comparable with Northern Hemisphere global stations. CFC-11 and CFC-12 time series displayed a decline consistent with their phase-out. Chlorofluorocarbons (CFCs) replacing compounds and SF
6 exhibited an increasing temporal behaviour. The most rapid growth rate was recorded for HFC-134a with a value of 9.6% yr
−1. The industrial solvents CCl
4 and CH
3CCl
3, banned by the Montreal Protocol, showed opposite trends. While CH
3CCl
3 reported an expected decay of −1.8
ppt yr
−1, an increasing rate of 5.7
ppt yr
−1 was recorded for CCl
4 and it is probably related to its relatively long lifetime and persisting emissions. Chlorinated halomethanes showed seasonality with a maximum in early April and a minimum at the end of September. Halon-1301 and Halon-1211 displayed a decreasing trend consistent with industry emission estimates.
An interspecies correlation analysis gave positive high correlations between HCFC-22 and HFC-134a (+0.84) highlighting the common extensive employment as refrigerants. Sharing sources inferred the high coupling between CH
3Cl and CH
3Br (+0.73) and between CHCl
3 and CH
2Cl
2 (+0.77). A singular strong relationship (+0.55) between HFC-134a and CH
3I suggested the influence of an unknown anthropogenic source of CH
3I.
Constraining of source and sink distribution was carried out by transport studies. Results were compared with the European Environment Agency (EEA) emission database. In contrast with the emission database results, our back trajectory analysis highlighted the release of large amounts of HFC-134a and SF
6 from Eastern Europe. Observations also showed that African SF
6 emissions may be considerable. Leakages from SF
6 insulated electrical equipments located in the industrialized Northern African areas justify our observations.
PDF
