The purpose of this work lies in the use of ionic liquids as corrosion inhibitors due to the difficulty in some oil fields with the solubility of corrosion inhibitors and these materials can be ...miscible with water and thus provide a solution to such problems in the industry. The second purpose is concerned with the lower toxicity of these compounds compared with the most common corrosion inhibitors. The study covered the corrosion inhibition performance of the ionic liquid 1-butyl-3-methylimidazolium trifluoromethyl sulfonate (BMImTfO) for carbon steel in 3.5% NaCl solutions. The study comprised electrochemical, adsorption, and quantum chemical investigations. The results manifested that BMImTfO can be considered a promising corrosion inhibitor and the inhibition efficacy intensifies as the concentration rises. The observed inhibitive effect can be correlated to the adsorption of the ionic liquid species and the creation of protecting films on the surface. The mode of adsorption follows the Langmuir adsorption isotherm. The polarization results showed that the ionic liquid BMImTfO functions as a mixed inhibitor. Reliance of the corrosion influence on the temperature in the existence and absence of BMImTfO was demonstrated in the temperature range of 303-333 K using polarization data. Activation parameters were determined and discussed. The observed inhibition performance of BMImTfO was correlated with the electronic properties of the ionic liquid using a quantum chemical study.
The 2018 update of the Canadian Stroke Best Practice Recommendations for Acute Stroke Management, 6th edition, is a comprehensive summary of current evidence-based recommendations, appropriate for ...use by healthcare providers and system planners caring for persons with very recent symptoms of acute stroke or transient ischemic attack. The recommendations are intended for use by a interdisciplinary team of clinicians across a wide range of settings and highlight key elements involved in prehospital and Emergency Department care, acute treatments for ischemic stroke, and acute inpatient care. The most notable changes included in this 6th edition are the renaming of the module and its integration of the formerly separate modules on prehospital and emergency care and acute inpatient stroke care. The new module, Acute Stroke Management: Prehospital, Emergency Department, and Acute Inpatient Stroke Care is now a single, comprehensive module addressing the most important aspects of acute stroke care delivery. Other notable changes include the removal of two sections related to the emergency management of intracerebral hemorrhage and subarachnoid hemorrhage. These topics are covered in a new, dedicated module, to be released later this year. The most significant recommendation updates are for neuroimaging; the extension of the time window for endovascular thrombectomy treatment out to 24 h; considerations for treating a highly selected group of people with stroke of unknown time of onset; and recommendations for dual antiplatelet therapy for a limited duration after acute minor ischemic stroke and transient ischemic attack. This module also emphasizes the need for increased public and healthcare provider’s recognition of the signs of stroke and immediate actions to take; the important expanding role of paramedics and all emergency medical services personnel; arriving at a stroke-enabled Emergency Department without delay; and launching local healthcare institution code stroke protocols. Revisions have also been made to the recommendations for the triage and assessment of risk of recurrent stroke after transient ischemic attack/minor stroke and suggested urgency levels for investigations and initiation of management strategies. The goal of this updated guideline is to optimize stroke care across Canada, by reducing practice variations and reducing the gap between current knowledge and clinical practice.
The goal of this research is to determine what chemicals are present in two different extracts (hexane and acetone) of Vicia faba (family Fabaceae, VF) peels and evaluate their effectiveness as a ...corrosion inhibitor on mild steel in a saline media containing 3.5% sodium chloride. Gas chromatography-mass spectrometry (GC/MS) was used to determine the composition of various extracts. It was determined that fourteen different chemicals were present in the hexane extract, the most prominent of which were octacosane, tetrasodium tetracontane, palmitic acid, and ethyl palmitate. Heptacosane, lauric acid, myristic acid, ethyl palmitate, and methyl stearate were some of the 13 chemicals found in the acetone extract. Using open circuit potential, potentiodynamic polarisation, and electrochemical impedance spectroscopic techniques, we can approximate the inhibitory effects of (VF) extracts on mild steel. The most effective inhibitory concentrations were found to be 200 ppm for both the hexane and acetone extracts (97.84% for the hexane extract and 88.67% for the acetone extract). Evaluation experiments were conducted at 298 K, with a 3.5% (wt/v) NaCl content and a flow velocity of about 250 rpm. Langmuir adsorption isotherm shows that the two extracts function as a mixed-type inhibitor in nature. Docking models were used to investigate the putative mechanism of corrosion inhibition, and GC/MS was used to identify the major and secondary components of the two extracts. Surface roughness values were calculated after analyzing the morphology of the metal's surface with and without (VF) using a scanning electron microscope (SEM). The results showed that throughout the surface of the mild steel, a thick adsorbate layer was formed. Quantum chemical calculations conducted on the two extracts as part of the theoretical research of quantum chemical calculation demonstrated a connection between the experimental analysis results and the theoretical study of the major chemical components.
The major objective of this study was to examine the viability of using 5, 10, or 15 mass% of Activated Alum Sludge waste (AAS) instead of Ordinary Portland Cement (OPC) as a pozzolanic ingredient in ...concrete. This fundamental inquiry framed the investigation and OPC-AAS-hardened composites were studied to see whether they may benefit from inexpensive nanocomposites in terms of improved physical properties, mechanical strength, and resistance to heat and flame. The investigation set out to see how inexpensive nanocomposite might be put to use and the nanoparticles of CuFe
O
spinel with an average size of less than 50 nm were successfully manufactured. Many different OPC-AAS-hardened composites benefit from the addition of CuFe
O
spinel, which increases the composites' resistance to fire and enhances their physicomechanical properties at roughly average curing ages. Synthesized CuFe
O
spinel was shown to have desirable characteristics by TGA/DTG and XRD. By using these methods, we were able to identify a broad variety of hydration yields, including C-S-Hs, C-A-S-Hs, C-F-S-Hs, and Cu-S-Hs, that enhance the physicomechanical properties and thermal resistivity of OPC-AAS-hardened composites as a whole. The composite material comprising 90% OPC, 10% AAS waste, and 2% CuFe
O
has several positive economic and environmental outcomes.
Abstract
Powder metallurgy (PM) is a technique that involves the manufacturing of metal powders and their consolidation into finished products or components. This process involves the mixing of metal ...powders with other materials such as ceramics or polymers, followed by the application of heat and pressure to produce a solid, dense material. The use of PM has several advantages over traditional manufacturing techniques, including the ability to create complex shapes and the production of materials with improved properties. Cu–TiO
2
composite materials are of great interest due to their unique properties, such as high electrical conductivity, improved mechanical strength, and enhanced catalytic activity. The synthesis of Cu–TiO
2
composites using the PM technique has been gaining popularity in recent years due to its simplicity, cost-effectiveness, and ability to produce materials with excellent homogeneity. The novelty of using the PM technique for the preparation of Cu–TiO
2
composite lies in the fact that it enables the production of materials with controlled microstructures and optical properties. The microstructure of the composite can be fine-tuned by controlling the particle size and distribution of the starting powders, as well as the processing parameters such as temperature, pressure, and sintering time. The optical properties of the composite can also be tailored by adjusting the size and distribution of the TiO
2
particles, which can be used to control the absorption and scattering of light. This makes Cu–TiO
2
composites particularly useful for applications such as photocatalysis and solar energy conversion. In summary, the use of Powder Metallurgy for the preparation of Cu–TiO
2
composite is a novel and effective technique for producing materials with controlled microstructures and optical properties. The unique properties of Cu–TiO
2
composites make them attractive for a wide range of applications in various fields, including energy, catalysis, and electronics.
Eichhornia crassipes
root powder (ECRP) has been used to remove ammonia from aqueous solutions. The biosorption factors such as biosorbent dosage, pH, initial ammonia concentration, and contact time ...have been considered in batch conditions. The optimal conditions, at pH (6), sorbent dose 5 g/l, time (30 min) ammonia concentration (10 mg/l). Langmuir is better suited than Freundlich isotherm. The kinetic models Thomas, Yoon-Nelson, and Bohart-Adams were applied. These models showed that the adsorption capacity decreased with flow rate increases as follows: 32.57, 31.82, 31.25, and 30.17 mg/g, respectively, at a flow rate 10, 15, 20, and 25 ml/min. The root powder of
Eichhornia crassipes
was used to treat specific drainage wastewater obtained from the Sabal drain at Menoufia, Egypt. The average efficiency of ammonia removal was 87% per batch adsorption method at pH value = 7.5, sorbent dose 5 g/l, uptake period (30 min), and primary load 7.1 mg/l; however, ammonia removal by column continuous adsorption method exceeded 94%. In addition, ECRP is efficient in removing arsenic, sulfate, nitrates, nitrite, silica, iron, manganese, copper, zinc, aluminum, and lead from actual sewage wastewater, in addition to removing more than 75% COD.
The purpose of this research was to examine the viability of applying a flawless polyaniline coating on steel spearheads to preserve them and protect them from corrosion. The spearpoints, thought to ...be archaeologically significant, were acquired from the Military Museum in Al-Qala, Egypt. X-ray diffraction (XRD), scanning electron microscopy (SEM), and energy-dispersive X-ray spectroscopy were used to characterize the spearheads chemical composition and microstructure (EDX). The spearheads were determined to be constructed of steel and to have a coating of ferric oxide and other corrosion products on their exteriors. After that, a flawless polyaniline coating was electrochemically deposited onto the spearpoints in a way that was both quick and cheap. Many types of corrosion tests, such as electrochemical impedance spectroscopy and potentiodynamic polarization (PDP) readings, were used to determine the coating's effectiveness. The steel spearheads' findings revealed a significant improvement in their resistance to corrosion after being coated with flawless polyaniline. The coating served as a barrier, blocking out water and other corrosive substances and slowing the buildup of corrosion byproducts on the spearpoints. In conclusion, our research shows that a flawless polyaniline coating may be an effective anti-corrosion treatment for ancient steel artifacts. The approach is straightforward, cheap, and readily scalable for massive conservation efforts.
Due to a lack of water treatment technology, developing and emerging nations have become significant polluters and water shortage is exacerbated by pollution. Ammonium toxicity is a huge global ...environmental concern with no clear solution. Population growth and industrialization destroy the ecosystem. Common and industrial products contain ammonium ions. Water pollution damages fish and other aquatic life. An inexpensive and green wastewater treatment method is adsorption. Adsorbent polymers that remove ammonium ions from wastewater have been explored. Ammonium ions are very hazardous when deposited into surface waters. Surfaces of bentonite and montmorillonite clay may attach sodium ammonium ions. They are cheap and abundant, therefore used to treat drain water. Bentonite outperformed montmorillonite in eliminating ammonium ions from water. Bentonite and montmorillonite clays were used to remove residual ammonium ions. These are utilized for bentonitic and montmorillonitic clays. Both clays were absorbed in a neutral pH, and it was free of sulfuric acid, ammonium ions, and phosphorus ions. Montmorillonitic clay boosted TDS by nearly 10% whereas bentonitic clay only raised TDS by 1%. Adsorption may inexpensively filter water and the surface charge of adsorbents affect their adsorption capacity. Ammonium ions may be recycled, and several bioreactors can remove ammonium ions from liquid and solid phases. Iterate over several models and the Freundlich isotherm model outperforms the Langmuir model by 5%. And bentonite clay adsorbs better due to iron oxide content.
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