In this paper, we report the synthesis of functionalized carbon nanotubes (F-CNTs) by acid treatment and their hydrogen storage properties. These F-CNTs have been characterized by XRD, FTIR, Raman ...spectroscopy and electron microscopy techniques. The results show that the structure and morphology of P-CNTs have been modified after the acid treatment. The hydrogen storage capacity was determined by volumetric measurements at room temperature and experimental results showed that the storage capacities of P-CNTs and F-CNTs were 0.65 wt% and 0.89 wt%, respectively. A notable enhancement in hydrogen storage capacity of F-CNTs was observed which could be attributed to the enhanced oxygen functionalities, opening of end caps and presence of surface defects that offered enhanced surface area for hydrogen adsorption. The key results of present research show that structural, morphological and chemical changes are responsible factors to enhance the hydrogen storage density.
•Functionalization of carbon nanotubes was done using chemical oxidative method.•Structure and morphology of P-CNTs has been modified after being open acid treatment.•Sievert’s type storage setup is designed, fabricated and installed indigenously.•CNTs were characterized by SEM, TEM, XRD, Raman and FTIR spectroscopy.•Storage capacity enhanced due to presence of structural defects in F-CNTs.
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ABSTRACT
We prospectively studied the efficacy of peribulbar anesthesia in 76 consecutive patients who underwent vitreoretinal surgery. The mean duration of anesthesia was 124.74 ± 50.17 minutes, and ...the mean duration of akinesia, 151.5 ± 54.45 minutes. Adequate anesthesia and akinesia, independent of the duration of surgery, was obtained in 26 of 33 (78.8%) patients who underwent vitrectomy; 9 of 32 (28.1%) who underwent scleral buckling; and 2 of 11 (18.2%) who underwent vitrectomy combined with scleral buckling. In all, topical and systemic supplementation of drugs for inadequate anesthesia or akinesia allowed 32 of the 33 (97%) vitrectomies, 30 of the 32 (94%) scleral buckling procedures, and all 11 of the combined surgeries to be completed as planned. Three (4%) patients vomited, moved, or were restless, resulting in an operative complication or postponement of surgery. Fifty-eight (76%) said they would desire similar anesthesia if subsequent surgery was needed in the same or fellow eye. We conclude that peribulbar anesthesia should be considered primarily for patients requiring vitreous surgery alone, and as an alternative for patients requiring scleral buckling or combined surgery for whom general anesthesia is contraindicated.
We prospectively studied the efficacy of peribulbar anesthesia in 76 consecutive patients who underwent vitreoretinal surgery. The mean duration of anesthesia was 124.74 +/- 50.17 minutes, and the ...mean duration of akinesia, 151.5 +/- 54.45 minutes. Adequate anesthesia and akinesia, independent of the duration of surgery, was obtained in 26 of 33 (78.8%) patients who underwent vitrectomy; 9 of 32 (28.1%) who underwent scleral buckling; and 2 of 11 (18.2%) who underwent vitrectomy combined with scleral buckling. In all, topical and systemic supplementation of drugs for inadequate anesthesia or akinesia allowed 32 of the 33 (97%) vitrectomies, 30 of the 32 (94%) scleral buckling procedures, and all 11 of the combined surgeries to be completed as planned. Three (4%) patients vomited, moved, or were restless, resulting in an operative complication or postponement of surgery. Fifty-eight (76%) said they would desire similar anesthesia if subsequent surgery was needed in the same or fellow eye. We conclude that peribulbar anesthesia should be considered primarily for patients requiring vitreous surgery alone, and as an alternative for patients requiring scleral buckling or combined surgery for whom general anesthesia is contraindicated.
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