Biochar may be a tool for mine spoil remediation; however, its mechanisms for achieving this goal remain unclear. In this study, Miscanthus (Miscanthus giganteus) biochar was evaluated for its ...ability to reclaim acidic mine spoils (pH < 3) through reducing metal availability, improving soil microbial enzymatic activity, and initial growth of grass seedlings. Biochar was applied at 0, 1, 2.5 and 5% (w/w) along with lime/no lime and fertilizer additions. Blue Wildrye (Elymus glaucus cv. ‘Elkton’) was planted and later the shoots and roots were collected and metal concentrations determined. Afterwards, each pot was leached with deionized water, and the leachate analyzed for pH, electrical conductivity (EC), dissolved organic carbon (DOC) and soluble metal concentrations. After drying, the spoil was extracted with 0.01 M CaCl2 and Mehlich 3 (M3) to determine extractable Al, Cu, and Zn concentrations. Additionally, microbial activity was measured using a fluorescent β-glucosidase and N-acetyl-β-d-glucosaminidase assay. Spoil treated with lime and biochar had significantly greater pH and EC values. Significantly greater β-glucosidase activity occurred only in the 5% biochar plus lime treatment, while N-acetyl-β-d-glucosaminidase activities were not altered. Metal concentrations in rye shoot and roots were mixed. Lime additions significantly reduced extractable metal concentrations. Increasing biochar rates alone significantly reduced leachate DOC concentrations, and subsequently reduced leachable metal concentrations. Surprisingly, miscanthus biochar, by itself, was limited at mitigation, but when combined with lime, the combination was capable of further reducing extractable metal concentrations and improving β-glucosidase enzyme activity.
•Blue Wildrye shoot and root growth was improved after lime treatment of spoil.•Miscanthus biochar had minimal impact on reducing extractable metal concentrations.•Lime increased mine spoil pH and reduced extractable metal concentrations.•Water leachates were lower in dissolved metals after lime and biochar additions.•Microbial enzymatic activity was influenced only at highest biochar and lime application.
Ethiopia faces high risk of soil carbon depletion for nearly half of its total land mass largely due to forest clearing and continuous cultivation. Conversion of natural ecosystems to cultivated ...agriculture resulted in losses of between 20 and 50% of the soil C stocks in the first meter of the soil depth. Dry Afromontane forests of northern Ethiopia have faced vast exploitation, and almost all these forests have been converted to agricultural lands affecting the functionality and stability of agroecosystem. Here, we studied the effect of land use-land cover changes on soil organic C, total N, and soil C sequestration. Specifically, (a) we characterized major soils of the Desa’a Dry Afromontane forest, northern Ethiopia, and (b) we analyzed the organic C and total N contents of soils with varying land use-land cover types of the Desa’a Dry Afromontane forest. Results show that soil organic C (1.9%) and total N (0.3%) were higher for the middle landscape position than that observed for the upper and lower landscape positions. Soil organic C that ranged from 1.2 in farmland to 2.3% in dense forest also varied with land use-land cover types. Concentration of soil organic C was different among dense forest (2.3%), open forest (1.7%), grazing land (1.6%), and farmland (1.2%). Due to the effect of land use-land cover types, soil total N varied from 0.2% in the farmland to 0.3% in the dense forest. The soil organic C and total nitrogen of the top and lower layer soils were 2.0 and 1.5 and 0.2 and 0.3%, respectively. The soil organic C sequestration for dense forest was significantly higher (48.5 t ha
−1
) than that of grassland, open forest, and farm land. The top soil sequestered higher soil organic C (44.9 t ha
−1
) than the lower soil layer. Thus, the top soil layers of dense forest at the middle landscape positions stored significant amount of soil organic carbon.
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•Catalytic oxidation (H2O2) is used to activate fulvic acid-like in paper mill effluent.•Activated fulvic acid-like features lower molecular weight and richer functional groups than ...un-activated fulvic acid-like.•Activated fulvic acid-like enhances rice seed germination and seedling growth under salt stress.•Activated fulvic acid-like improve salt tolerance by alleviating salt-induced oxidative damage at the cellular level.
Increasing environmental concerns about organic waste in paper mill effluents demand alternative wastewater management technology. We reported novel activation of fulvic acid-like in paper mill effluents using hydrogen peroxide (H2O2) as oxidizer and titanium oxide (TiO2) as catalyst. Spectroscopic characteristics of fulvic acid-like in paper mill effluents before and after activation (PFA and PFA-Os, respectively) were compared with a benchmark fulvic acid extracted from leonardite (LFA). Results indicated that PFA-Os exhibited less lignin structures, more functional groups and lower molecular weight than PFA, sharing much similarity with LFA. Among PFA-Os with varying degrees of oxidation, PFA-O-3 activated with 1:2 vol ratio of paper mill effluent and 30% H2O2 for 20 min digestion at 90 °C stands out to be the optimal for further examination of its biological activity. Bioassays with rice seed/seedling indicated that applications of LFA at 2–5 mg-C/L and PFA-O-3 at 60–100 mg-C/L significantly increased rice seed germination rate and seedling growth under salt stress imposed with 100 mM NaCl. The mechanism was mainly through reduced oxidative damage via activation of antioxidative enzymes and lipid peroxidation. This study provides the needed technical basis of safer and cleaner technologies for innovative management of paper mill effluents.
Potential new sources of phosphorus (P) fertilizer are the recovered P from livestock wastewater through chemical precipitation and the ash from combusting animal manures. Although most of the ...research on P losses from conservation tillage include high water-soluble P compounds from commercial fertilizer sources, information on the use of non-conventional, low water-soluble, recycled P sources is scarce. Particularly for sandy soils of the United States (US) Southeastern Coastal Plain region, research driven information on P loss into the environment is needed to determine recommendations for a direct use of new recycled P sources as crop P fertilizers. The objective of this study is to investigate the potential P runoff from sandy soils under conservation tillage, fertilized with recovered P from liquid swine manure and turkey litter ash in comparison with commercial P fertilizer triple superphosphate (TSP). The field study included two typical sandy soils of the US Southeastern Coastal Plain region, the Noboco and Norfolk. Simulated rain corresponding to the annual 30-min rainfall in the study site (Florence County, South Carolina) was applied to plots treated with recovered P from liquid swine manure, turkey litter ash, and TSP, including a control with no P added. The runoff was monitored and sampled every 5 min during the test and composite soil samples were collected from the top (0–15 cm) and subsurface (15–30 cm) soil layers in each plot. Laboratory analyses were conducted to quantify both total P (TP) and soluble reactive P (SRP) in runoff samples, and the soil test P in the soil layers. Two-way analyses of variances show significant treatment effects on both TP and SRP runoff. The quantities of SRP runoff from plots treated with the recovered P from swine manure and turkey litter ash represent respectively 1% and 7–8% of SRP runoff from plots treated with TSP. Hence, the use of the recovered P materials as crop P fertilizers through surface broadcast application present less environmental risks compared to commercial TSP.
•Phosphorus (P) runoff evaluated for two recycled P materials from animal manure, commercial P, and a control on sandy soils.•Plot-scale analyses show significant treatment effects, less P losses for recycled P materials.•Broadcast application of recycled P materials presents less environmental risks.•Recycled P materials could be an alternative to enhance soil nutrient management on sandy soils.
Biochar is being considered a climate change mitigation tool by increasing soil organic carbon contents (SOC), however, questions remain concerning its longevity in soil. We applied 30,000 kg ha−1 of ...biochars to plots containing a Goldsboro sandy loam (Fine-loamy, siliceous, sub-active, thermic Aquic Paleudults) and then physically disked all plots. Thereafter, the plots were agronomically managed under 4 years (Y) of continuous corn (Zea Mays, L.) planting. Annually, incremental soil along with corresponding bulk density samples were collected and SOC concentrations were measured in topsoil (down to 23-cm). The biochars were produced from Lodgepole pine (Pinus contorta) chip (PC) and Poultry litter (PL) feedstocks. An untreated Goldsboro soil (0 biochar) served as a control. After four years, SOC contents in the biochar treated plots were highest in the top 0–5 and 5–10 cm depth suggesting minimal deeper movement. Declines in SOC contents varied with depth and biochar type. After correction for SOC declines in controls, PL biochar treated soil had a similar decline in SOC (7.9 to 10.3%) contents. In contrast, the largest % SOC content decline (20.2%) occurred in 0–5 cm deep topsoil treated with PC biochar. Our results suggest that PC biochar had less stability in the Goldsboro soil than PL biochar after 4 years of corn grain production.
Biochars have the potential to reclaim mine-impacted soils; however, their variable physico-chemical properties incite speculation about their successful remediation performance. This investigation ...examined the capability of biochars produced from three different feedstocks along with a compost blend to improve switchgrass growth conditions in a mine-impacted soil by examining influences on soil pH, grass metal contents, and soil-extractable metal concentrations. Cadmium (Cd)- and zinc (Zn)-contaminated mine soil was collected from a site near Webb City, Missouri, USA—a location within the Tri-State Mining District. In a full factorial design, soil was treated with a 0%, 2.5%, and 5% (
w/w
) compost mixture (wood chips + beef cattle manure), and 0%, 2.5% and 5% of each biochar pyrolyzed from beef cattle manure, poultry litter, and lodgepole pine feedstocks. Switchgrass (
Panicum virgatum
, ‘Cave-In-Rock’ variety) was grown in a greenhouse for 50 days and the mass of shoots (above-ground biomass) and roots was assessed, while soil pH, deionized H
2
O- and 0.01 M CaCl
2
-extractable Cd and Zn concentrations were measured. Poultry litter biochar and compost had the greatest ability to raise soil pH (from 4.40 to 6.61), beef cattle manure biochar and compost moderately raised pH (from 4.4 to 5.92), and lodgepole pine biochar and compost weakly raised pH (from 4.40 to 5.05). Soils treated with beef cattle manure biochar, poultry litter biochar significantly reduced deionized H
2
O- and 0.01 M CaCl
2
-extractable Cd and Zn concentrations, while lodgepole pine biochar-treated soils showed mixed results. Switchgrass shoot and root masses were greatest in soil treated with compost in combination with either beef cattle manure biochar or poultry litter biochar. Soils treated with 5% beef cattle manure biochar + 5% compost had greater reductions in total Cd and Zn concentrations measured in switchgrass shoots and roots compared to the other two treatments. The three biochars and compost mixtures applied to heavy metal, mine-impacted soil had considerable performance dissimilarities for improving switchgrass productivity. Switchgrass growth was noticeably improved after treatment with the compost in combination with biochar from beef cattle manure or poultry litter. This may be explained by the increased soil pH that promoted Zn and Cd precipitation and organic functional groups that reduced soil-available heavy metal concentrations. Our results imply that creating designer biochars is an important management component in developing successful mine-site phytostabilization programs.
The soil nitrogen (N) availability and urease activity (UA) in a humid ecosystem with variable rainfall distribution and poor soil fertility are not well understood. A complete appreciation of N ...cycling in the soil–water–plant continuum is needed to better manage N and water in regions that will be strongly affected by climate change. A sorghum (Sorghum bicolor L.) study located in Florence, South Carolina, USA, was conducted using a variable-rate pivot system. We hypothesized that supplemental irrigation (SI) and N would enhance UA and N uptake while minimizing the concentration of N in porewater (TINW). The aim of the study was to assess the impact of SI (0, 50, and 100%) and N fertilization (0, 85, and 170 kg N ha−1) on: UA; total N (TNS); total inorganic N (TINS); TINW; and N uptake of sorghum. Results support our research hypothesis. The greatest UA was from 0% SI and 170 kg ha−1 (18.7 µg N g−1 ha−1). Porewater N (mg L−1), when averaged across SI and N showed a significantly lower concentration at lower soil depth (9.9 ± 0.7) than the upper depth (26.1 ± 2.4). The 100% SI had the greatest biomass N uptake (NUPB) of 67.9 ± 31.1 kg ha−1 and grain N uptake (NUG) of 52.7 ± 20.5 kg ha−1. The greatest NUPB (70.9 ± 30.3 kg ha−1) and NUG (55.3 ± 16.5 kg ha−1) was from the application of 170 kg N ha−1. Overall, results showed that proper use of water and N enhanced soil N dynamics, and improved biomass productivity and N uptake of sorghum.
Biochars are used for soil fertility improvement because they may contain certain elements that plants use as nutrients. However, few studies have demonstrated enhanced crop nutrient uptake. Our ...study examined nutrient uptake responses of corn (Zea Mays L.) grain and stover over 4 years (Y) after a Goldsboro sandy loam (fine-loamy, siliceous, sub-active, thermic Aquic Paleudults) received different designer biochars and a compost. The designer biochars were produced from lodgepole pine (Pinus contorta) chip (PC), poultry litter (PL), blends with switchgrass (SG; Panicum virgatum), and a SG compost alone. Topsoil treated with 100% PL biochar and blended PC:PL biochar had significantly greater Mehlich 1 (M1) extractable P, K and Na contents compared to the control or other treatments. No significant differences were detected in annual grain nutrient concentrations. In the first corn stover harvest (Y1), significantly greater concentrations of P and K were taken up after treatment with 100% PL biochar, with PC:PL blend and with SG when compared to control. By the fourth corn stover harvest (Y4), nutrient uptake between treatments was not significantly different. Biochar impact on corn stover P, K and Na concentrations was time dependent, suggesting that repeated biochar applications may be needed.
There are mixed reports for biochars’ ability to increase corn grain and biomass yields. The objectives of this experiment were to conduct a three-year corn (Zea mays L.) grain and biomass production ...evaluation to determine soil fertility characteristics after designer biochars were applied to a highly weathered Ultisol. The amendments, which consisted of biochars and compost, were produced from 100% pine chips (PC); 100% poultry litter (PL); PC:PL 2:1 blend; PC mixed 2:1 with raw switchgrass (Panicum virgatum; rSG) compost; and 100% rSG compost. All treatments were applied at 30,000 kg/ha to a Goldsboro loam sandy (Fine-loamy, siliceous, sub-active, thermic Aquic Paleudult). Annual topsoil samples were collected in 5-cm depth increments (0 to 15-cm deep) and pH was measured along with Mehlich 1 phosphorus (M1 P) and potassium (M1 K) contents. After three years of corn production, there was no significant improvement in the annual mean corn grain or biomass yields. Biochar, which was applied from PL and PC:PL 2:1 blend, significantly increased M1 P and M1 K concentrations down to 10-cm deep, while the other biochar and compost treatments showed mixed results when the soil pH was modified. Our results demonstrated that designer biochar additions did not accompany higher corn grain and biomass productivity.
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