The interstellar medium has a rich chemistry which involves a wide variety of molecules. Of particular interest are molecules that have a link to prebiotic chemistry which hold the key to ...understanding of our origins. On the basis of suggestions that selenium may have been involved in the origin and evolution of life, we have studied the selenium analogue of cyanoethenethiol, namely the novel cyanoetheneselenol. Cyanoetheneselenol exhibits conformational and geometrical isomerism. This theoretical work deals with the study of four forms of cyanoetheneselenol in terms of their structural, spectroscopic and thermodynamic parameters. All computations were performed using density functional theory method with the B3LYP functional and the Pople basis set, 6–311 + G(d,p), for all atoms. The relative stability of the four isomers of cyanoetheneselenol was obtained and interpreted. The infrared spectra were generated and assignment of the normal modes of vibration was performed. Probable regions of detection, proposed on the basis of parameters obtained from this study for the four isomers, include comets, the molecular cloud: Sagittarius B2(N), and planetary atmospheres. The molecular and spectroscopic parameters should be useful for future identification of the astrobiological molecule cyanoetheneselenol and the development of the Square Kilometre Array.
Graphical Abstract
E
and
Z
isomers of cyanoetheneselenol
Because of the high energies and long distances to the sources, astrophysical observations provide a unique opportunity to test possible signatures of Lorentz invariance violation (LIV). Superluminal ...LIV enables the decay of photons at high energy. The high altitude water Cherenkov (HAWC) observatory is among the most sensitive gamma-ray instruments currently operating above 10 TeV. HAWC finds evidence of 100 TeV photon emission from at least four astrophysical sources. These observations exclude, for the strongest of the limits set, the LIV energy scale to 2.2 × 1031 eV , over 1800 times the Planck energy and an improvement of 1 to 2 orders of magnitude over previous limits.
Steady gamma-ray emission up to at least 200 GeV has been detected from the solar disk in the Fermi-LAT data, with the brightest, hardest emission occurring during solar minimum. The likely cause is ...hadronic cosmic rays undergoing collisions in the Sun’s atmosphere after being redirected from ingoing to outgoing in magnetic fields, though the exact mechanism is not understood. An important new test of the gamma-ray production mechanism will follow from observations at higher energies. Only the High Altitude Water Cherenkov (HAWC) Observatory has the required sensitivity to effectively probe the Sun in the TeV range. Here, using 3 years of HAWC data from November 2014 to December 2017, just prior to the solar minimum, we search for 1–100 TeV gamma rays from the solar disk. No evidence of a signal is observed, and we set strong upper limits on the flux at a few 10-12 TeV-1 cm-2 s-1 at 1 TeV. Our limit, which is the most constraining result on TeV gamma rays from the Sun, is ~ 10 % of the theoretical maximum flux (based on a model where all incoming cosmic rays produce outgoing photons), which in turn is comparable to the Fermi-LAT data near 100 GeV. The prospects for a first TeV detection of the Sun by HAWC are especially high during the solar minimum, which began in early 2018.
•Structural and spectroscopic data of cyanoacetylenes were computed using theoretical methods.•Comparisons of these parameters with experiments indicate the good performance of DFT method.•The large ...electric dipole moment of the cyanoacetylenes should help towards their detections.•The theoretical findings of these cyanoacetylenes should be helpful to experimentalists.•Plausible formation mechanisms of the cyanoacetylenes are also proposed.
Theoretical studies were performed on seven potential interstellar and circumstellar substituted cyanoacetylenes, Y(CC)CN Y = C2H5, C3H7, C4H9, F, Cl, Br and CN. Geometry optimizations were carried out using the DFT/B3LYP, the CCSD and CCSD(T) levels of theory. The cc-pVTZ basis set was used for all atoms. Frequency computations were also carried out at the same level of theory as for the optimization to check the nature of the stationary points. The molecular and spectroscopic parameters of the cyanoacetylenes were computed. An analysis of these parameters is in line with the satisfactory performance of the B3LYP/cc-pVTZ level compared to the golden standard, the CCSD(T) level. The theoretical data reported in this work should facilitate future identifications of these cyanoacetylenes in extraterrestrial locations. Plausible mechanisms for the formation of these molecules have been proposed.
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Many gamma-ray bursts (GRBs) have been observed from radio wavelengths, and a few at very-high energies (VHEs, > 100GeV). The HAWC gamma-ray observatory is well suited to study transient phenomena at ...VHEs due to its large field of view and duty cycle. These features allow for searches of VHE emission and can probe different model assumptions of duration and spectra. In this paper, we use data collected by HAWC between December 2014 and May 2020 to search for emission in the energy range from 80 to 800 GeV coming from a sample 47 short GRBs that triggered the Fermi, Swift and Konus satellites during this period. This analysis is optimized to search for delayed and extended VHE emission within the first 20 s of each burst. We find no evidence of VHE emission, either simultaneous or delayed, with respect to the prompt emission. Upper limits (90% confidence level) derived on the GRB fluence are used to constrain the synchrotron self-Compton forward-shock model. Constraints for the interstellar density as low as \(10^{-2}\) cm\(^{-3}\) are obtained when assuming z=0.3 for bursts with the highest keV-fluences such as GRB 170206A and GRB 181222841. Such a low density makes observing VHE emission mainly from the fast cooling regime challenging.
The MGRO J2019+37 region is one of the brightest sources in the sky at TeV energies. It was detected in the 2 year HAWC catalog as 2HWC J2019+367 and here we present a detailed study of this region ...using data from HAWC. This analysis resolves the region into two sources: HAWC J2019+368 and HAWC J2016+371. We associate HAWC J2016+371 with the evolved supernova remnant CTB 87, although its low significance in this analysis prevents a detailed study at this time. An investigation of the morphology (including possible energy dependent morphology) and spectrum for HAWC J2019+368 is the focus of this work. We associate HAWC J2019+368 with PSR J2021+3651 and its X-ray pulsar wind nebula, the Dragonfly nebula. Modeling the spectrum measured by HAWC and Suzaku reveals a \(\sim\)7 kyr pulsar and nebula system producing the observed emission at X-ray and \({\gamma}\)-ray energies.
Due to the high energies and long distances to the sources, astrophysical observations provide a unique opportunity to test possible signatures of Lorentz invariance violation (LIV). Superluminal LIV ...enables the decay of photons at high energy. The High Altitude Water Cherenkov (HAWC) Observatory is among the most sensitive gamma-ray instruments currently operating above 10 TeV. HAWC finds evidence of 100 TeV photon emission from at least four astrophysical sources. These observations exclude, for the strongest of the limits set, the LIV energy scale to \(2.2\times10^{31}\) eV, over 1800 times the Planck energy and an improvement of 1 to 2 orders of magnitude over previous limits.
Cosmic rays, along with stellar radiation and magnetic fields, are known to make up a significant fraction of the energy density of galaxies such as the Milky Way. When cosmic rays interact in the ...interstellar medium, they produce gamma-ray emission which provides an important indication of how the cosmic rays propagate. Gamma rays from the Andromeda Galaxy (M31), located 785 kpc away, provide a unique opportunity to study cosmic-ray acceleration and diffusion in a galaxy with a structure and evolution very similar to the Milky Way. Using 33 months of data from the High Altitude Water Cherenkov Observatory, we search for TeV gamma rays from the galactic plane of M31. We also investigate past and present evidence of galactic activity in M31 by searching for Fermi Bubble-like structures above and below the galactic nucleus. No significant gamma-ray emission is observed, so we use the null result to compute upper limits on the energy density of cosmic rays \(>10\) TeV in M31. The computed upper limits are approximately ten times higher than expected from the extrapolation of the Fermi LAT results.
We describe plans for the development of the Southern Wide-field Gamma-ray Observatory (SWGO), a next-generation instrument with sensitivity to the very-high-energy (VHE) band to be constructed in ...the Southern Hemisphere. SWGO will provide wide-field coverage of a large portion of the southern sky, effectively complementing current and future instruments in the global multi-messenger effort to understand extreme astrophysical phenomena throughout the universe. A detailed description of science topics addressed by SWGO is available in the science case white paper 1. The development of SWGO will draw on extensive experience within the community in designing, constructing, and successfully operating wide-field instruments using observations of extensive air showers. The detector will consist of a compact inner array of particle detection units surrounded by a sparser outer array. A key advantage of the design of SWGO is that it can be constructed using current, already proven technology. We estimate a construction cost of 54M USD and a cost of 7.5M USD for 5 years of operation, with an anticipated US contribution of 20M USD ensuring that the US will be a driving force for the SWGO effort. The recently formed SWGO collaboration will conduct site selection and detector optimization studies prior to construction, with full operations foreseen to begin in 2026. Throughout this document, references to science white papers submitted to the Astro2020 Decadal Survey with particular relevance to the key science goals of SWGO, which include unveiling Galactic particle accelerators 2-10, exploring the dynamic universe 11-21, and probing physics beyond the Standard Model 22-25, are highlighted in red boldface.
The Andromeda Galaxy (M31) is a nearby (\(\sim\)780 kpc) galaxy similar to our own Milky Way. Observational evidence suggests that it resides in a large halo of dark matter (DM), making it a good ...target for DM searches. We present a search for gamma rays from M31 using 1017 days of data from the High Altitude Water Cherenkov (HAWC) Observatory. With its wide field of view and constant monitoring, HAWC is well-suited to search for DM in extended targets like M31. No DM annihilation or decay signal was detected for DM masses from 1 to 100 TeV in the \(b\bar{b}\), \(t\bar{t}\), \(\tau^{+}\tau^{-}\), \(\mu^{+}\mu^{-}\), and \(W^{+}W^{-}\) channels. Therefore we present limits on those processes. Our limits nicely complement the existing body of DM limits from other targets and instruments. Specifically the DM decay limits from our benchmark model are the most constraining for DM masses from 25 TeV to 100 TeV in the \(b\bar{b}, t\bar{t}\) and \(\mu^{+}\mu{-}\) channels. In addition to DM-specific limits, we also calculate general gamma-ray flux limits for M31 in 5 energy bins from 1 TeV to 100 TeV.
