We evaluate the controlling factors of hydrothermal wolframite and scheelite precipitation in the quartz vein-type Jiaoxi tungsten deposit situated in the western part of the Lhasa terrane (Tibet, ...China) using texture, major and trace element mineral geochemistry, and sulfur stable isotope geochemistry. Pyrite and chalcopyrite that are intergrown with Fe-enriched wolframite and siderite, have distinct in situ S isotope compositions (δ34SV-CDT) of -31.38 to +1.77 per mille, and +2.07 to +2. per mille0;, respectively. Major and trace element contents and in situ S isotope compositions of pyrite and chalcopyrite indicate that the hydrothermal evolution involved fluid-fluid mixing and greisenization. We report evidence for an early magmatic fluid, which is characterized by the enrichment of W, Mn, Zr, Ti, Sc, and Sn and depletion of Fe. This magmatic fluid was diluted by meteoric water and interacted with biotite monzogranite porphyry to leach Fe, Mg, and Zn into the system to form wolframites with variable Fe/(Fe+Mn) ratios ranging between -013;0.84. The late Fe-enriched magmatic fluid released from the muscovite granite mixed with meteoric water that leached minor Fe and S from shale to form late shale-hosted wolframite with a Fe/(Fe+Mn) mass ratio of >0.75 and coeval siderite and sulfides. This study highlights that multiple Fe sources were present in the system, including muscovite granite-released Fe through fluid exsolution, biotite monzogranite porphyry-released Fe during greisenization, and minor Fe released from the shale as a result of meteoric water leaching.
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•The Late Triassic-Jurassic magmatic belt is extensively distributed in the SL.•The Triassic-Jurassic magmatic belt in the SL was controlled by double subduction.•The early-stage ...tectonic evolution of the Neo-Tethys Ocean is constrained.
The southern Lhasa subterrane (SL), located between the Yarlung-Tsangpo Suture Zone and the Luobadui-Milashan Fault, preserves a complete Late Triassic-Jurassic magmatic record related to Neo-Tethys Ocean evolution. Therefore, the SL is key to understanding the geodynamic processes occurring during the controversial early-stage evolution of this ocean. Here, we present new zircon U–Pb data and a detailed synthesis of geochronological, geochemical, and Sr-Nd-Pb-Hf isotope data from Late Triassic-Jurassic igneous rocks in the SL to constrain the early-stage evolution of the Neo-Tethys Ocean. The data suggest that these igneous rocks can be divided into two groups. Group 1 magmatism lasted from ca. 243 Ma to 145 Ma, with three stages at ca. 243–200 Ma, 199–165 Ma, and 164–145 Ma, and is characterized by high positive εHf(t) and εNd(t) values and low (206Pb/204Pb)t, (207Pb/204Pb)t, and (208Pb/204Pb)t values. Group 2 magmatism lasted from ca. 225 Ma to 160 Ma, with two stages at ca. 225–190 Ma and 189–160 Ma, and is characterized by lower εHf(t) and εNd(t) values and higher (206Pb/204Pb)t, (207Pb/204Pb)t, and (208Pb/204Pb)t values than Group 1. We suggest that the Triassic-Jurassic magmatic belt in the SL was controlled by double subduction; the Group 1 igneous rocks formed in an intraoceanic arc setting, while the Group 2 igneous rocks formed in a continental margin arc setting. An integrated interpretation of magmatism, ophiolites, sedimentary rocks, and metallogenesis within the SL constrains the geodynamic processes that occurred during the early-stage tectonic evolution of the Neo-Tethys Ocean as follows. (1) During the Middle-Late Triassic, the initiation of intraoceanic subduction between Gondwana and the SL produced the ~243–200 Ma magmatism of Group 1. Subsequently, a new continental margin subduction system formed on the southern margin of the SL, which induced the ~225–190 Ma magmatism of Group 2. (2) With ongoing subduction, slab roll-back of the intraoceanic subduction system resulted in the ~199–165 Ma magmatic flare-up of Group 1. Additionally, slab roll-back of the continental margin subduction system resulted in extension of the overriding plate and formed the ~189–160 Ma magmatic flare-up of Group 2. (3) Finally, the slab roll-back associated with intraoceanic subduction transitioned to flat subduction and produced the 164–145 Ma magmatism of Group 1, and porphyry Cu-Au mineralization developed during the stress transition period. In summary, the double subduction system in the early-stage evolution of the Neo-Tethys Ocean controlled the tectonic, magmatic, and metallogenic events in the SL.
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•The Xiongcun district is a unique area where OPCD and RPCD coexist.•A combination of apatite and zircon geochemistry can be used to track petrogenesis.•The mineralizing magmas of No. ...I and No. II deposit have similar fO2.•Apatite can be used as an indicator mineral for mineral exploration.
The Xiongcun district, a unique area where oxidized porphyry copper-gold deposits (OPCD) and reduced porphyry copper-gold deposits (RPCD) coexist, is located in the central part of the Gangdese porphyry copper belt (GPCB) in Tibet, China, and hosts the only known mineralization related to the Neo-Tethyan oceanic subduction. Apatite and zircon major and trace elements, in situ oxygen isotopes in zircon from fertile quartz diorite porphyry (QDP) of the No. I deposit, fertile hornblende quartz diorite porphyry (HQDP) of the No. II deposit, and barren hornblende quartz diorite porphyry with coarse quartz eyes (QQDP) in the Xiongcun district were determined by EPMA, LA-ICP-MS, and SHRIMP II ion microprobe to investigate the petrogenesis, magma oxidation state, and mineralization differences between the No. I and No. II deposits, as well as the potential of apatite as a metallogenic indicator. The results from this study show that a combination of REE, Ti, oxygen isotopes, and the Th/U ratios in zircon and REE as well as Sr in apatite can be used to track the magma compositions and crystallization histories in porphyry systems. Multiple indicators, including the apatite SO3 content, apatite Mn oxybarometer, and zircon Ce4+/Ce3+ ratio, indicate that (1) the parental magmas of fertile QDP and HQDP containing Cu and Au mineralization were more reduced than that of barren QQDP; (2) despite barren QQDP having higher oxygen fugacity than QDP and HQDP, the lower Cu and water contents in the magma result in a lower potential for ore formation; and (3) the similar oxidation states of QDP and HQDP show that the mineralization differences between RPCD (No. I deposit) and OPCD (No. II deposit) were not caused by the oxidation states of the magmas but were likely caused by the different processes of hydrothermal fluid evolution. Apatite grains from fertile porphyries (QDP and HQDP) have much higher Cl/F ratios than those from barren porphyry (QQDP), indicating that the Cl/F ratio of apatite can be used as a proxy for porphyry Cu-Au mineralization related to the Jurassic porphyry intrusions in the Gangdese porphyry copper belt.
The Bangong–Nujiang suture zone (BNSZ), which separates the Gondwana-derived Qiangtang and Lhasa terranes, preserves limited geological records of the Bangong–Nujiang Ocean (BNO). The timing of ...opening of this ocean has been hotly debated due to the rare and complicated rock records in the suture zones, which span over 100 Ma from Carboniferous–Permian to Early Jurassic time, based on geological, palaeontological and palaeomagnetic data. A combination of geochemical, geochronological and isotopic data are reported for the Riasairi trachytes, central BNSZ, northern Tibet, to constrain its petrogenesis and tectonic settings. Zircon U–Pb dating by laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) yields mean ages of 236 Ma. Geochemically, these rocks are high-K calc-alkaline with moderate SiO2 (59.1–67.5 wt%) and high K2O + Na2O (8.1–11.6 wt%) contents. They are enriched in light rare earth elements with negative Eu anomalies, and show enrichments in high-field-strength elements with positive ‘Nb, Ta’ anomalies, similar to the intra-continental rift setting-related felsic lavas from the African Rift System. The high positive zircon ϵHf(t) and bulk ϵNd(t) values, as well as high initial Pb isotopes, imply a heterogeneous source involving both asthenospheric and subcontinental lithospheric mantle. The field and geochemical data jointly suggest that the Riasairi trachytes within the Mugagangri Group were formed in a continental rift setting. We interpret that the continental-rift-related Riaisairi trachytic lavas as derived from the southern margin of the Qiangtang terrane, implying that the BNO would have opened by Middle Triassic time, well after the commonly interpreted break-up of the Qiangtang terrane from Gondwana.
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•Early Permian arc magmatism was identified in the NLT.•Geochemical signatures of Permian-Triassic magmatic rocks in the Lhasa Terrane.•Collision between NLT and SLT was followed by ...subduction of the Neo-Tethys.•Subduction initiation of the Neo-Tethys is a response to Cimmeria-Eurasia collision.
Collision-induced subduction transference may have triggered subduction of the Neo-Tethys oceanic lithosphere. To verify this proposition, we present an integrated geochemical and geochronological studies of new and published data of the Permian-Triassic magmatism in the Lhasa Terrane. The newly identified Chongni mafic intrusions (gabbros and diorites) in the North Lhasa Terrane (NLT) were emplaced during the Early Permian (ca. 275 Ma). The mafic rocks have (87Sr/86Sr)t ratios between 0.7037 and 0.7042, and εNd(t) values between + 5.2 and + 5.8. The zircons of the Chongni mafic rock samples have εHf(t) values from + 9.1 to + 12.9. The isotopic data in conjunction with trace element features suggest that the Chongni mafic intrusions have been derived mainly by partial melting of a metasomatized mantle wedge source. The newly identified Quxu granodiorites and hornblende gabbros in the South Lhasa Terrane (SLT) were emplaced in the Late Triassic (ca. 228–203 Ma). The granodiorites are characterized by (87Sr/86Sr)t ratios of 0.7036–0.7037 and εNd(t) values of +6.6 to +6.7, while the hornblende gabbro samples have (87Sr/86Sr)t ratios of 0.7033–0.7035 and εNd(t) values of +7.3 to +7.4. The zircons of the granodiorite and hornblende gabbro samples revealed εHf(t) values of +10.3 to +14.0 and +10.8 to +16.4, respectively. The isotopic data in combination with trace element signatures suggest that the granodiorites were derived from a juvenile basaltic lower crust with a minor input of mantle components, while the hornblende gabbros are interpreted to have formed during partial melting of a formerly metasomatized depleted mantle wedge source. The Early Permian and Late Triassic magmatic rocks consistently show arc-related signatures, which probably record the northward subduction of the Sumdo Paleo-Tethys and the Neo-Tethys oceanic slabs, respectively. This evidence, in combination with that of other studies on the Permian-Triassic magmatism across the Lhasa Terrane, indicates that arc magmatism within the NLT switched to collisional magmatism at ca. 260 Ma due to the collision of oceanic islands/plateaus and, further on, the collision of the SLT with the NLT. Furthermore, the change from ca. 265–255 Ma alkaline magmatism to ca. 240–200 Ma calc‐alkaline magmatism within the SLT may reflect the geodynamic transition from lithospheric extension to Andean-style orogenesis. Therefore, we propose that subduction initiation of the Neo-Tethys oceanic lithosphere in the Tibetan Plateau resulted from the southward transference of the Sumdo Paleo-Tethys subduction zone, involving the collision of oceanic islands/plateaus and, subsequently, the collision of the SLT with the NLT. Additionally, the geological records of the Tethyan orogenic system suggest that the subduction initiation of the Neo-Tethys oceanic lithosphere is a uniform response to the collision between Cimmeria and Eurasia.
•The Xiongcun district present two middle Jurassic mineralizing episodes separated by 10m.y.•The porphyry mineralization in the Xiongcun district formed in island arc setting.•Four major metallogenic ...events existed in the Gangdese porphyry copper belt.
Two large copper–gold porphyry deposits (No.I and No.II) were discovered in the last decade within the Xiongcun district, which is located along the south margin of the Gangdese porphyry copper belt. These two deposits are hosted by two porphyries that were emplaced into the Early Jurassic volcano-sedimentary rock sequences of the Xiongcun Formation. The porphyries are both quartz diorite bodies, with one of these distinguished by its large quartz eyes. Our new molybdenite Re–Os and zircon U–Pb dates for No.I and No.II deposits and host intrusions reveal the presence of two Middle Jurassic ore-forming episodes in the Xiongcun district. The No.II deposit is related to the 181–175Ma quartz diorite porphyry and formed ca. 172.6±2.1Ma. The No.I deposit is related to the 167–161Ma quartz diorite porphyry with large quartz eyes and formed ca. 161.5±2.7Ma. Geochronological and geochemical features of the Jurassic ore-bearing porphyries in the Xiongcun district indicate that the porphyry copper–gold mineralization formed in an island arc setting, which is related to the northward subduction of the Neo-Tethys oceanic plate. These observations, in combination with geochronological data reported at Gangdese porphyry copper belt, indicated four major metallogenic events existed in the Gangdese porphyry copper belt at 172–161Ma, 65–48Ma, 40–23Ma, and 20–12Ma. We have identified two mineralization episodes comprise Middle Jurassic metallogenic event (172–161Ma) in the Xiongcun district, which provides new constrains for the Middle Jurassic metallogenic event in the Gangdese porphyry copper belt.
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•Gradients in white mica wavelength are associated with specific rock units.•White mica wavelength is corresponding with geochemical results.•The clusters of white mica wavelength ...show the stages of mineralization.•The middle and longer wavelength of white mica are implication for exploration.
Field measurement of the short-wave infrared (SWIR) reflectance from drill hole samples proved to be an effective method to map variations in white mica composition (Tschermak substitution) associated with hydrothermal alteration zonation of the Jiama porphyry-skarn Cu deposit, Tibetan Plateau, China. This SWIR mineral spectral information provides geological insights into: (a) the possible nature of the related magmatic intrusions. (b) the physicochemistry of the associated hydrothermal fluids; (c) the interactions between these fluids and country rocks; and (d) potential vectors to economic mineralization. The results suggest that the Al-OH band wavelength of white mica can used as an indicator in the subsequent steps of prospecting.
The processes and related rock types in post-collision setting are important to fully understand the geodynamic evolution of a collision zone. Bangong-Nujiang collision zone is the oldest collision ...zone in the Tibet Plateau. Slab break-off is one of the primary processes during post-collision, and is considered to have occured in the Bangong-Nujiang collision zone. Here, we report a newly identified rhyolite-biotite monzogranite (A2-type granite)-norite belt from this collision zone, which trend E-W for nearly 1000 km, and formed 115–104 Ma. The felsic rocks include rhyolite and biotite monzogranite, who share whole-rock geochemical similarities with A2-type granites. These felsic rocks were likely generated from a juvenile mafic crust melting at low pressure and high-temperature. The juvenile crust was derived from melting of metasomatized mantle wedge. The norites were generated from low degree (1–5%) melting of remnant enriched lithospheric mantle mixed with upwelling asthenospheric mantle at low pressure (~1.0 GPa) and high melting temperature (up to 1244 °C). A slab break-off beneath the Lhasa Terrane accounts for this post-collisional high-temperature extensional environment. The results provide important implications for the evolution of the Bangong-Nujiang collisional zone, including the subducting polarity, and timing of the Bangong-Nujiang ocean closure.
•~1000 km long rhyolite-A2-granite-norite belt in Bangong-Nujiang collision zone, Tibet•Felsic rocks formed from melting of a juvenile mafic crust.•Norites formed by asthenospheric and metasomatized lithospheric mantle interaction•The belt formed in a low-P/high-T post-collisional setting associated with slab break-off.
Jurassic sandstones in the Xiongcun porphyry copper–gold district, southern Lhasa subterrane, Tibet, China were analysed for petrography, major oxides and trace elements, as well as detrital zircon ...U–Pb and Hf isotopes, to infer their depositional age, provenance, intensity of source-rock palaeo-weathering and depositional tectonic setting. This new information provides important evidence to constrain the tectonic evolution of the southern Lhasa subterrane during the Late Triassic – Jurassic period. The sandstones are exposed in the lower and upper sections of the Xiongcun Formation. Their average modal abundance (Q21F11L68) classifies them as lithic arenite, which is also supported by geochemical studies. The high chemical index of alteration values (77.19–85.36, mean 79.96) and chemical index of weathering values (86.19–95.59, mean 89.98) of the sandstones imply moderate to intensive weathering of the source rock. Discrimination diagrams based on modal abundance, geochemistry and certain elemental ratios indicate that felsic and intermediate igneous rocks constitute the source rocks, probably with a magmatic arc provenance. The detrital zircon ages (161–243 Ma) and εHf(t) values (+10.5 to +16.2) further constrain the sandstone provenance as subduction-related Triassic–Jurassic felsic and intermediate igneous rocks from the southern Lhasa subterrane. A tectonic discrimination method based on geochemical data of the sandstones, as well as detrital zircon ages from sandstones, reveals that the sandstones were most likely deposited in an oceanic island-arc setting. These results support the hypothesis that the tectonic background of the southern Lhasa subterrane was an oceanic island-arc setting, rather than a continental island-arc setting, during the Late Triassic – Jurassic period.
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