Gas management during electrocatalytic water splitting is vital for improving the efficiency of clean hydrogen production. The accumulation of gas bubbles on electrode surfaces prevents electrolyte ...access and passivates the electrochemically active surface area. Electrode morphologies are sought to assist in the removal of gas from surfaces to achieve higher reaction rates at operational voltages. Herein, regular arrays of linear ridges with specific microscale separations were systematically studied and correlated to the performance of the oxygen evolution reaction (OER). The dimensions of the linear ridges were proportional to the size of the oxygen bubbles, and the mass transfer processes associated with gas evolution at these ridges were monitored using a high-speed camera. Characterization of the adhered bubbles prior to detachment enabled the use of empirical methods to determine the volumetric flux of product gas and the bubble residence times. The linear ridges promoted a self-cleaning effect as one bubble would induce neighboring bubbles to simultaneously release from the electrode surfaces. The linear ridges also provided preferential bubble growth sites, which expedited the detachment of bubbles with similar diameters and shorter residence times. The linear ridges enhanced the OER in comparison to planar electrodes prepared by electrodeposition from the same high-purity nickel (Ni). Linear ridges with a separation distance of 200 μm achieved nearly a 2-fold increase in current density relative to the planar electrode at an operating voltage of 1.8 V (vs Hg/HgO). The electrodes with linear ridges having a separation distance of 200 μm also had the highest sustained current densities over a range of operating conditions for the OER. Self-cleaning surface morphologies could benefit a variety of electrocatalytic gas evolving reactions by improving the efficiency of these processes.
This work utilizes EIS to elucidate the impact of catalyst–ionomer interactions and cathode hydroxide ion transport resistance (R CL,OH– ) on cell voltage and product selectivity for the ...electrochemical conversion of CO to ethylene. When using the same Cu catalyst and a Nafion ionomer, varying ink dispersion and electrode deposition methods results in a change of 2 orders of magnitude for R CL,OH– and ca. a 25% change in electrode porosity. Decreasing R CL,OH– results in improved ethylene Faradaic efficiency (FE), up to ∼57%, decrease in hydrogen FE, by ∼36%, and reduction in cell voltage by up to 1 V at 700 mA/cm2. Through the optimization of electrode fabrication conditions, we achieve a maximum of 48% ethylene with >90% FE for non-hydrogen products in a 25 cm2 membrane electrode assembly at 700 mA/cm2 and <3 V. Additionally, the implications of optimizing R CL,OH– is translated to other material requirements, such as anode porosity. We find that the best performing electrodes use ink dispersion and deposition techniques that project well into roll-to-roll processes, demonstrating the scalability of the optimized process.
Abstract
Paleolimnological evidence indicates the ancient Maya transformed terrestrial ecosystems by felling forest vegetation to construct large civic-ceremonial centers and to expand agriculture. ...Human settlements influenced lacustrine environments but the effects of Maya activities on aquatic ecosystems remain poorly studied. Here we analyzed a sediment core from Lake Petén Itzá, Guatemala, to infer paleoenvironmental changes resulting from Maya occupation of the archaeological site of Nixtun-Ch’ich’. Increases in charcoal and fecal stanol concentrations indicate Maya occupation of the Candelaria Peninsula by the late Early Preclassic period. Geochemical proxies reveal a period of lake ecosystem alteration during construction and expansion of the city’s urban grid in the Middle and Late Preclassic periods. Depopulation of the city in the Terminal Preclassic resulted in a decline in lake trophic state. Whereas previous studies of Petén waterbodies have indicated depressed lacustrine primary production, the core collected near Nixtun-Ch’ich’ shows evidence of ancient Maya lake ecosystem deterioration.
The cathode materials in lithium-ion batteries (LIBs) require improvements to address issues such as surface degradation, short-circuiting, and the formation of dendrites. One such method for ...addressing these issues is using surface coatings. Coatings can be sought to improve the durability of cathode materials, but the characterization of the uniformity and stability of the coating is important to assess the performance and lifetime of these materials. For microscale particles, there are, however, challenges associated with characterizing their surface modifications by transmission electron microscopy (TEM) techniques due to the size of these particles. Often, techniques such as focused ion beam (FIB)-assisted lift-out can be used to prepare thin cross sections to enable TEM analysis, but these techniques are very time-consuming and have a relatively low throughput. The work outlined herein demonstrates a FIB technique with direct support of microscale cathode materials on a TEM grid that increases sample throughput and reduces the processing time by 60–80% (i.e., from >5 to ∼1.5 h). The demonstrated workflow incorporates an air–liquid particle assembly followed by direct particle transfer to a TEM grid, FIB milling, and subsequent TEM analysis, which was illustrated with lithium nickel cobalt aluminum oxide particles and lithium manganese nickel oxide particles. These TEM analyses included mapping the elemental composition of cross sections of the microscale particles using energy-dispersive X-ray spectroscopy. The methods developed in this study can be extended to high-throughput characterization of additional LIB cathode materials (e.g., new compositions, coating, end-of-life studies), as well as to other microparticles and their coatings as prepared for a variety of applications.
The Journal of Arthroplasty Reviewers Bowen, Taylor; Liu, Steve S.; Bellamy, Jaime L. ...
The Journal of arthroplasty,
April 2024, 2024-Apr, 2024-04-00, 20240401, Letnik:
39, Številka:
4
Journal Article
The genetic and molecular basis of flagellar motility has been investigated for several decades, with innovative research strategies propelling advances at a steady pace. Furthermore, as the ...phenomenon is examined in diverse bacteria, new taxon-specific regulatory and structural features are being elucidated. Motility is also a straightforward bacterial phenotype that can allow undergraduate researchers to explore the palette of molecular genetic tools available to microbiologists. This study, driven primarily by undergraduate researchers, evaluated hundreds of flagellar motility mutants in the Gram-negative plant-associated bacterium Agrobacterium fabrum. The nearly saturating screen implicates a total of 37 genes in flagellar biosynthesis, including genes of previously unknown function.
The Pacific Islands Fisheries Science Center deploys the Modular Optical Underwater Survey System (MOUSS) to estimate the species-specific, size-structured abundance of commercially-important fish ...species in Hawaii and the Pacific Islands. The MOUSS is an autonomous stereo-video camera system designed for the in situ visual sampling of fish assemblages. This system is rated to 500 m and its low-light, stereo-video cameras enable identification, counting, and sizing of individuals at a range of 0.5-10 m. The modular nature of MOUSS allows for the efficient and cost-effective use of various imaging sensors, power systems, and deployment platforms. The MOUSS is in use for surveys in Hawaii, the Gulf of Mexico, and Southern California. In Hawaiian waters, the system can effectively identify individuals to a depth of 250 m using only ambient light. In this paper, we describe the MOUSS's application in fisheries research, including the design, calibration, analysis techniques, and deployment mechanism.
Persistent bubble accumulation during the oxygen evolution reaction (OER) can effectively block catalytically active surface sites and reduce overall system performance. The OER is an essential ...half-reaction with relevance to metal–air batteries, fuel cells, and water electrolysis for power to gas applications. The renewable energy sector could benefit from the identification of surface morphologies that can effectively reduce the accumulation of bubbles on electrocatalytic surfaces. In this work, regular dimpled nickel (Ni) features were prepared to investigate how electrode morphology and therefore its roughness and wetting properties may affect the efficiency of the OER. The dimpled Ni features were prepared using spherical poly(styrene) (PS) templates with a diameter of 1 μm. The electrodeposition against regular, self-assembled arrays of PS templates was tuned to produce four types of dimpled features each with a different depth. Enhancements to the OER efficiency were observed for some types of dimpled Ni features when compared to a planar electrodeposited Ni electrode, while the dimpled features that were the most recessed demonstrated reduced efficiencies for the OER. The findings from this study emphasize the influences of electrode surface morphology on processes involving electrocatalytic gas evolution.
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