Quantum technologies comprise an emerging class of devices capable of controlling superposition and entanglement of quantum states of light or matter, to realize fundamental performance advantages ...over ordinary classical machines. The technology of integrated quantum photonics has enabled the generation, processing and detection of quantum states of light at a steadily increasing scale and level of complexity, progressing from few-component circuitry occupying centimetre-scale footprints and operating on two photons, to programmable devices approaching 1,000 components occupying millimetre-scale footprints with integrated generation of multiphoton states. This Review summarizes the advances in integrated photonic quantum technologies and its demonstrated applications, including quantum communications, simulations of quantum chemical and physical systems, sampling algorithms, and linear-optic quantum information processing.This Review covers recent progress in integrated quantum photonics (IQP) technologies and their applications. The challenges and opportunities of realizing large-scale, monolithic IQP circuits for future quantum applications are discussed.
Luminescent complexes of heavy metals such as iridium, platinum, and ruthenium play an important role in photocatalysis and energy conversion applications as well as organic light-emitting diodes ...(OLEDs). Achieving comparable performance from more-earth-abundant copper requires overcoming the weak spin-orbit coupling of the light metal as well as limiting the high reorganization energies typical in copper(I) Cu(I) complexes. Here we report that two-coordinate Cu(I) complexes with redox active ligands in coplanar conformation manifest suppressed nonradiative decay, reduced structural reorganization, and sufficient orbital overlap for efficient charge transfer. We achieve photoluminescence efficiencies >99% and microsecond lifetimes, which lead to an efficient blue-emitting OLED. Photophysical analysis and simulations reveal a temperature-dependent interplay between emissive singlet and triplet charge-transfer states and amide-localized triplet states.
Since their introduction over 15 years ago, the operational lifetime of blue phosphorescent organic light-emitting diodes (PHOLEDs) has remained insufficient for their practical use in displays and ...lighting. Their short lifetime results from annihilation between high-energy excited states, producing energetically hot states (>6.0 eV) that lead to molecular dissociation. Here we introduce a strategy to avoid dissociative reactions by including a molecular hot excited state manager within the device emission layer. Hot excited states transfer to the manager and rapidly thermalize before damage is induced on the dopant or host. As a consequence, the managed blue PHOLED attains T80=334±5 h (time to 80% of the 1,000 cd m
initial luminance) with a chromaticity coordinate of (0.16, 0.31), corresponding to 3.6±0.1 times improvement in a lifetime compared to conventional, unmanaged devices. To our knowledge, this significant improvement results in the longest lifetime for such a blue PHOLED.
Photophysical properties of two highly emissive three-coordinate Cu(I) complexes, (IPr)Cu(py2-BMe2) (1) and (Bzl-3,5Me)Cu(py2-BMe2) (2), with two different N-heterocyclic (NHC) ligands were ...investigated in detail (IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene; Bzl-3,5Me = 1,3-bis(3,5-dimethylphenyl)-1H-benzodimidazol-2-ylidene; py2-BMe2 = di(2-pyridyl)dimethylborate). The compounds exhibit remarkably high emission quantum yields of more than 70% in the powder phase. Despite similar chemical structures of both complexes, only compound 1 exhibits thermally activated delayed blue fluorescence (TADF), whereas compound 2 shows a pure, yellow phosphorescence. This behavior is related to the torsion angles between the two ligands. Changing this angle has a huge impact on the energy splitting between the first excited singlet state S1 and triplet state T1 and therefore on the TADF properties. In addition, it was found that, in both compounds, spin–orbit coupling (SOC) is particularly effective compared to other Cu(I) complexes. This is reflected in short emission decay times of the triplet states of only 34 μs (1) and 21 μs (2), respectively, as well as in the zero-field splittings of the triplet states amounting to 4 cm–1 (0.5 meV) for 1 and 5 cm–1 (0.6 meV) for 2. Accordingly, at ambient temperature, compound 1 exhibits two radiative decay paths which are thermally equilibrated: one via the S1 state as TADF path (62%) and one via the T1 state as phosphorescence path (38%). Thus, if this material is applied in an organic light-emitting diode, the generated excitons are harvested mainly in the singlet state, but to a significant portion also in the triplet state. This novel mechanism based on two separate radiative decay paths reduces the overall emission decay time distinctly.
Implementing large instances of quantum algorithms1–5 requires the processing of many quantum information carriers in a hardware platform that supports the integration of different components6. ...Although established semiconductor fabrication processes can integrate many photonic components7, the generation and algorithmic processing of many photons has been a bottleneck in integrated photonics. Here, we report the on-chip generation and algorithmic processing of quantum states of light with up to eight photons. Switching between different optical pumping regimes, we implement the scattershot8,9, Gaussian10 and standard boson sampling3,11–14 protocols in the same silicon chip, which integrates linear and nonlinear photonic circuitry. We use these results to benchmark a quantum algorithm for calculating molecular vibronic spectra4. Our techniques can be readily scaled for the on-chip implementation of specialized quantum algorithms with tens of photons, pointing the way to efficiency advantages over conventional computers15.
Future quantum computers require a scalable architecture on a scalable technology-one that supports millions of high-performance components. Measurement-based protocols, using graph states, represent ...the state of the art in architectures for optical quantum computing. Silicon photonics technology offers enormous scale and proven quantum optical functionality. Here we produce and encode photonic graph states on a mass-manufactured chip, using four on-chip-generated photons. We programmably generate all types of four-photon graph state, implementing a basic measurement-based protocol, and measure high-visibility heralded interference of the chip's four photons. We develop a model of the device and bound the dominant sources of error using Bayesian inference. The combination of measurement-based quantum computation, silicon photonics technology, and on-chip multi-pair sources will be a useful one for future scalable quantum information processing with photons.
Flow transitions are an important fluid-dynamic phenomena for many reasons, including the direct effect on the aerodynamic forces acting on the body. In the present study, two-dimensional (2-D) and ...three-dimensional (3-D) wake transitions of a NACA0012 airfoil are studied for angles of attack in the range $0^\circ \leq \alpha \leq 20^\circ$ and Reynolds numbers $500 \leq {\textit {Re}} \leq 5000$. The study uses water-channel experiments and 2-D and 3-D numerical simulations based on the nodal spectral-element method, level-set function-based immersed-interface method and Floquet stability analysis. The different wake states are categorised based on the time-instantaneous wake structure, non-dimensional frequency and aerodynamic force coefficients. The wake states and transition boundaries are summarised in a wake regime map. The critical angle of attack and Reynolds number for the supercritical Hopf bifurcation (i.e. steady to periodic wake transition) varies as $\alpha _1 {\sim} {\textit {Re}}^{-0.65}$, while the critical angle of attack for the onset of three dimensionality varies as $\alpha _{3D} {\sim} {\textit {Re}}^{-0.5}$. Over the entire Reynolds number range, the transition to 3-D flow occurs through a mode C (subharmonic) transition. Beyond this initial transition, further instabilities of the 2-D periodic base flow arise and are investigated. For instance, at $ {\textit {Re}}=2000$ and $\alpha _{3D,2}=11.0^\circ$, mode C coexists together with modes related to modes A and QP seen in a stationary circular cylinder wake. In contrast, at $ {\textit {Re}}=5000$ and $\alpha _{3D,2}=8.0^\circ$, the dominant mode C coexists with mode QP. Three-dimensional simulations well beyond critical angles indicate that 2-D vortex-street transitions are approximately maintained in the fully saturated 3-D wakes in a spanwise-averaged sense.
How do different kinds of democratic backsliding affect opposition pushback? To contribute to the answer, this article compares two divergent cases in the Asia-Pacific - "executive aggrandizement" in ...the Philippines and a "promissory" military coup in Thailand. An institutional explanation focused on remaining electoral, state institutional, and civil societal forms of democratic accountability despite autocratization does not elucidate significant variations in pushback. In the Philippines, elections have been fairer, state institutions less obviously manipulated and restrictions on civil society less overt. But opposition pushback has been significantly weaker than in Thailand despite more generalized repression and institutional manipulation there. An alternative explanation examines how opposition pushback is influenced by regimes' efforts to legitimize autocratization. Thailand's military-monarchical rulers had little success in framing recent elections as democratic while legitimacy linked to the monarchy has also eroded. This has catalysed the formation of a broad civilian opposition alliance, with strong parties, regular protests and critical social media. By contrast, while the Philippines' Rodrigo Duterte acts illiberally, he claims continued democratic legitimacy based on competitive elections and high opinion ratings while ruling largely constitutionally. This has undermined electoral opposition and weakened civil society, with no sustained protests and activists out-"trolled" on social media.
We report the enhancement of photocatalytic performance by introduction of hydrogen-bonding interactions to a Re bipyridine catalyst and Ru photosensitizer system (ReDAC/RuDAC) by the addition of ...amide substituents, with carbon monoxide (CO) and carbonate/bicarbonate as products. This system demonstrates a more-than-3-fold increase in turnover number (TONCO = 100 ± 4) and quantum yield (ΦCO = 23.3 ± 0.8%) for CO formation compared to the control system using unsubstituted Ru photosensitizer (RuBPY) and ReDAC (TONCO = 28 ± 4 and ΦCO = 7 ± 1%) in acetonitrile (MeCN) with 1,3-dimethyl-2-phenyl-2,3-dihydro-1H-benzodimidazole (BIH) as sacrificial reductant. In dimethylformamide (DMF), a solvent that disrupts hydrogen bonds, the ReDAC/RuDAC system showed a decrease in catalytic performance while the control system exhibited an increase, indicating the role of hydrogen bonding in enhancing the photocatalysis for CO2 reduction through supramolecular assembly. The similar properties of RuDAC and RuBPY demonstrated in lifetime measurements, spectroscopic analysis, and electrochemical and spectroelectrochemical studies revealed that the enhancement in photocatalysis is due not to differences in intrinsic properties of the catalyst or photosensitizer, but to hydrogen-bonding interactions between them.
PDF
