There is currently concern that glyphosate, a strongly sorbing non-selective herbicide which is widely used in Europe, may be leached from the root zone into drainage water and groundwater. The ...purpose of this review is to present and discuss the state of knowledge with respect to the mobility and leaching of glyphosate from agricultural soils. Specific attention is given to the adsorption behaviour of glyphosate and the analysis of available studies on glyphosate transport. In addition, there are a number of experimental and numerical studies indicating that other strongly sorbing substances may be transported rapidly to the sub-surface. The experimental studies analysed in the paper encompass column-, lysimeter- and field-scale experiments on glyphosate transport. The experimental findings, combined with transport studies on other strongly sorbing pesticides in the literature, support the hypothesis that transport of glyphosate may be caused by an interaction of high rainfall events shortly after application on wet soils showing the presence of preferential flow paths. Concentrations of glyphosate in European groundwater have been reported occasionally but monitoring is still limited.
Animal manure application as organic fertilizer does not only sustain agricultural productivity and increase soil organic carbon (SOC) stocks, but also affects soil nitrogen cycling and nitrous oxide ...(N2O) emissions. However, given that the sign and magnitude of manure effects on soil N2O emissions is uncertain, the net climatic impact of manure application in arable land is unknown. Here, we performed a global meta‐analysis using field experimental data published in peer‐reviewed journals prior to December 2015. In this meta‐analysis, we quantified the responses of N2O emissions to manure application relative to synthetic N fertilizer application from individual studies and analyzed manure characteristics, experimental duration, climate, and soil properties as explanatory factors. Manure application significantly increased N2O emissions by an average 32.7% (95% confidence interval: 5.1–58.2%) compared to application of synthetic N fertilizer alone. The significant stimulation of N2O emissions occurred following cattle and poultry manure applications, subsurface manure application, and raw manure application. Furthermore, the significant stimulatory effects on N2O emissions were also observed for warm temperate climate, acid soils (pH < 6.5), and soil texture classes of sandy loam and clay loam. Average direct N2O emission factors (EFs) of 1.87% and 0.24% were estimated for upland soils and rice paddy soils receiving manure application, respectively. Although manure application increased SOC stocks, our study suggested that the benefit of increasing SOC stocks as GHG sinks could be largely offset by stimulation of soil N2O emissions and aggravated by CH4 emissions if, particularly for rice paddy soils, the stimulation of CH4 emissions by manure application was taken into account.
The uncertain manure effects on N2O emissions constrain evaluation of the net climatic impact of manure application in arable lands. A global meta‐analysis was performed to quantify the overall responses of N2O emissions to manure application relative to synthetic N fertilizer in agricultural soils. Manure application on average significantly increased N2O emissions by 32.7% as compared to synthetic N fertilizer alone, and the sign and magnitude of N2O emissions were dependent on manure characteristics, climate, and soil properties. The benefit of C sequestration could be largely offset by stimulation of soil N2O emissions and aggravated by CH4 emissions if, particularly for rice paddy soils, the stimulation of CH4 emissions by manure application was taken into account.
Soil moisture (SM) is a key hydrologic state variable that is of significant importance for numerous Earth and environmental science applications that directly impact the global environment and human ...society. Potential applications include, but are not limited to, forecasting of weather and climate variability; prediction and monitoring of drought conditions; management and allocation of water resources; agricultural plant production and alleviation of famine; prevention of natural disasters such as wild fires, landslides, floods, and dust storms; or monitoring of ecosystem response to climate change. Because of the importance and wide‐ranging applicability of highly variable spatial and temporal SM information that links the water, energy, and carbon cycles, significant efforts and resources have been devoted in recent years to advance SM measurement and monitoring capabilities from the point to the global scales. This review encompasses recent advances and the state‐of‐the‐art of ground, proximal, and novel SM remote sensing techniques at various spatial and temporal scales and identifies critical future research needs and directions to further advance and optimize technology, analysis and retrieval methods, and the application of SM information to improve the understanding of critical zone moisture dynamics. Despite the impressive progress over the last decade, there are still many opportunities and needs to, for example, improve SM retrieval from remotely sensed optical, thermal, and microwave data and opportunities for novel applications of SM information for water resources management, sustainable environmental development, and food security.
Key Points
Recent soil moisture measurement and monitoring techniques and estimation models from the point to the global scales and their limitations are presented
The importance and application of soil moisture information for various Earth and environmental sciences disciplines such as forecasting weather and climate variability, modeling hydrological processes, and predicting and monitoring extreme events and their impacts on the environment and human society are presented
Most soil hydraulic information used in Earth System Models (ESMs) is derived from pedo-transfer functions that use easy-to-measure soil attributes to estimate hydraulic parameters. This ...parameterization relies heavily on soil texture, but overlooks the critical role of soil structure originated by soil biophysical activity. Soil structure omission is pervasive also in sampling and measurement methods used to train pedotransfer functions. Here we show how systematic inclusion of salient soil structural features of biophysical origin affect local and global hydrologic and climatic responses. Locally, including soil structure in models significantly alters infiltration-runoff partitioning and recharge in wet and vegetated regions. Globally, the coarse spatial resolution of ESMs and their inability to simulate intense and short rainfall events mask effects of soil structure on surface fluxes and climate. Results suggest that although soil structure affects local hydrologic response, its implications on global-scale climate remains elusive in current ESMs.
Atrazine was banned in Germany in 1991 due to findings of atrazine concentrations in ground- and drinking waters exceeding threshold values. Monitoring of atrazine concentrations in the groundwater ...since then provides information about the resilience of the groundwater quality to changing agricultural practices. In this study, we present results of a monitoring campaign of atrazine concentrations in the Zwischenscholle aquifer. This phreatic aquifer is exposed to intensive agricultural land use and susceptible to contaminants due to a shallow water table. In total 60 observation wells (OWs) have been monitored since 1991, of which 15 are sampled monthly today. Descriptive statistics of monitoring data were derived using the “regression on order statistics” (ROS) data censoring approach, estimating values for nondetects. The monitoring data shows that even 20 years after the ban of atrazine, the groundwater concentrations of sampled OWs remain on a level close to the threshold value of 0.1 μg l−1 without any considerable decrease. The spatial distribution of atrazine concentrations is highly heterogeneous with OWs exhibiting permanently concentrations above the regulatory threshold on the one hand and OWs were concentrations are mostly below the limit of quantification (LOQ) on the other hand. A deethylatrazine-to-atrazine ratio (DAR) was used to distinguish between diffuse – and point-source contamination, with a global mean value of 0.84 indicating mainly diffuse contamination. Principle Component Analysis (PCA) of the monitoring dataset demonstrated relationships between the metabolite desisopropylatrazine, which was found to be exclusively associated with the parent compound simazine but not with atrazine, and between deethylatrazine, atrazine, nitrate, and the specific electrical conductivity. These parameters indicate agricultural impacts on groundwater quality.
The findings presented in this study point at the difficulty to estimate mean concentrations of contamination for entire aquifers and to evaluate groundwater quality based on average parameters. However, analytical data of monthly sampled single observation wells provide adequate information to characterize local contamination and evolutionary trends of pollutant concentration.
•Atrazine was monitored in an aquifer in Germany after its ban in 1991 until today.•Atrazine groundwater concentrations hardly changed within 20 years after its ban.•Concentrations vary strongly in space but the spatial pattern is stable in time.•Spatial variability hampers the estimation of mean groundwater quality parameters.
Soil, through its various functions, plays a vital role in the Earth's ecosystems and provides multiple ecosystem services to humanity. Pedotransfer functions (PTFs) are simple to complex knowledge ...rules that relate available soil information to soil properties and variables that are needed to parameterize soil processes. In this paper, we review the existing PTFs and document the new generation of PTFs developed in the different disciplines of Earth system science. To meet the methodological challenges for a successful application in Earth system modeling, we emphasize that PTF development has to go hand in hand with suitable extrapolation and upscaling techniques such that the PTFs correctly represent the spatial heterogeneity of soils. PTFs should encompass the variability of the estimated soil property or process, in such a way that the estimation of parameters allows for validation and can also confidently provide for extrapolation and upscaling purposes capturing the spatial variation in soils. Most actively pursued recent developments are related to parameterizations of solute transport, heat exchange, soil respiration, and organic carbon content, root density, and vegetation water uptake. Further challenges are to be addressed in parameterization of soil erosivity and land use change impacts at multiple scales. We argue that a comprehensive set of PTFs can be applied throughout a wide range of disciplines of Earth system science, with emphasis on land surface models. Novel sensing techniques provide a true breakthrough for this, yet further improvements are necessary for methods to deal with uncertainty and to validate applications at global scale.
Plain Language Summary
For the application of pedotransfer functions in current Earth system models, and specifically for the different fluxes of water, solutes, and gas between soil and atmosphere, subject of the land surface models, recent developments of knowledge are entered in a new generation of pedotransfer functions. Methods for development and evaluation of pedotransfer functions are described in this comprehensive review, and perspectives for future developments in different Earth system science disciplines are presented. Challenges are still present for the application in some extreme environments of the Earth. We argue that a comprehensive set of pedotransfer functions can be applied throughout a wide range of disciplines of Earth system science, with emphasis on land surface models. Even though methodological challenges are still present for extrapolation and scaling, as outlined, integration and validation in global‐scale models is an achievable goal.
Key Points
Methods for development and evaluation of pedotransfer functions are described, and perspectives in different Earth system science disciplines presented
Novel applications are present for the different fluxes of water, solutes, and gas between soil and atmosphere, subject of the land surface models
Methodological challenges are still present for extrapolation and scaling, but integration and validation in global‐scale models is an achievable goal
In soils, the isotopic composition of water (δ2H and δ18O) provides qualitative (e.g., location of the evaporation front) and quantitative (e.g., evaporation flux and root water uptake depths) ...information. However, the main disadvantage of the isotope methodology is that contrary to other soil state variables that can be monitored over long time periods, δ2H and δ18O are typically analyzed following destructive sampling. Here we present a nondestructive method for monitoring soil liquid water δ2H and δ18O over a wide range of water availability conditions and temperatures by sampling water vapor equilibrated with soil water using gas‐permeable polypropylene tubing and a cavity ring‐down laser absorption spectrometer. By analyzing water vapor δ2H and δ18O sampled with the tubing from a fine sand for temperatures ranging between 8°C and 24°C, we demonstrate that our new method is capable of monitoring δ2H and δ18O in soils online with high precision and after calibration, also with high accuracy. Our sampling protocol enabled detecting changes of δ2H and δ18O following nonfractionating addition and removal of liquid water and water vapor of different isotopic compositions. Finally, the time needed for the tubing to monitor these changes is compatible with the observed variations of δ2H and δ18O in soils under natural conditions.
Key Points
Soil water isotopic compositions are usually measured by destructive sampling
We present a new method for monitoring soil water isotopic compositions
The new method is field deployable, user friendly, and affordable
Core Ideas
Parameters of different RWU models were optimized using data from a rhizotron facility.
The same soil hydraulic properties were obtained for models considering RWU compensation.
...Feddes–Jarvis and Couvreur models predicted similar root‐system‐scale stress functions.
The obtained RWU parameters were consistent with data reported in the literature.
The models with compensation predicted similar total uptake but different local RWU.
The spatiotemporal distribution of root water uptake (RWU) depends on the dynamics of the root distribution and compensatory uptake from wetter regions in the root zone. This work aimed to parameterize three RWU models with different representations of compensation: the Feddes–Jarvis model that uses an empirical function, the Feddes model without compensation, and the Couvreur model that is based on a physical description of water flow in the soil–root system. These models were implemented in HYDRUS‐1D, and soil hydraulic parameters were optimized by inverse modeling using soil water content and potential measurements and observations of root distributions of winter wheat (Triticum aestivum L.) in horizontally installed rhizotubes. Soil moisture was equally well predicted by the three models, and the soil hydraulic parameters optimized by the models with compensation were comparable. The obtained RWU parameters of the Feddes–Jarvis model were consistent with data reported in the literature, although the pressure heads h3l and h3h for lower and higher transpirations rates, respectively, could not be uniquely identified. Response surfaces of the objective function showed that the root‐related parameters of the Couvreur model could be identified using inverse modeling. Furthermore, these parameters were consistent with combined root architectural and hydraulic observations from the literature. The Feddes–Jarvis and Couvreur models simulated similar root‐system‐scale stress functions that link total RWU to the effective root zone water potential, suggesting that parameters may be transferable between the two models. Simulated RWU profiles differed due to different water redistribution by the root system, but the measurements were not sufficiently precise to observe this redistribution.
Abstract
In most of the world, conditions conducive to wildfires are becoming more prevalent. Net carbon emissions from wildfires contribute to a positive climate feedback that needs to be monitored, ...quantified, and predicted. Here we use a causal inference approach to evaluate the influence of top-down weather and bottom-up fuel precursors on wildfires. The top-down dominance on wildfires is more widespread than bottom-up dominance, accounting for 73.3% and 26.7% of regions, respectively. The top-down precursors dominate in the tropical rainforests, mid-latitudes, and eastern Siberian boreal forests. The bottom-up precursors dominate in North American and European boreal forests, and African and Australian savannahs. Our study identifies areas where wildfires are governed by fuel conditions and hence where fuel management practices may be more effective. Moreover, our study also highlights that top-down and bottom-up precursors show complementary wildfire predictability across timescales. Seasonal or interannual predictions are feasible in regions where bottom-up precursors dominate.
Saturated soil column experiments were conducted to investigate the transport, retention, and release behavior of a low concentration (1 mg L−1) of functionalized 14C-labeled multi-walled carbon ...nanotubes (MWCNTs) in a natural soil under various solution chemistries. Breakthrough curves (BTCs) for MWCNTS exhibited greater amounts of retardation and retention with increasing solution ionic strength (IS) or in the presence of Ca2+ in comparison to K+, and retention profiles (RPs) for MWCNTs were hyper-exponential in shape. These BTCs and RPs were well described using the advection-dispersion equation with a term for time- and depth-dependent retention. Fitted values of the retention rate coefficient and the maximum retained concentration of MWCNTs were higher with increasing IS and in the presence of Ca2+ in comparison to K+. Significant amounts of MWCNT and soil colloid release was observed with a reduction of IS due to expansion of the electrical double layer, especially following cation exchange (when K+ displaced Ca2+) that reduced the zeta potential of MWCNTs and the soil. Analysis of MWCNT concentrations in different soil size fractions revealed that >23.6% of the retained MWCNT mass was associated with water-dispersible colloids (WDCs), even though this fraction was only a minor portion of the total soil mass (2.38%). More MWCNTs were retained on the WDC fraction in the presence of Ca2+ than K+. These findings indicated that some of the released MWCNTs by IS reduction and cation exchange were associated with the released clay fraction, and suggests the potential for facilitated transport of MWCNT by WDCs.
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•The retention of MWCNTs in soil was sensitive to solution IS and cation type.•Both breakthrough curves and retention profiles were determined and simulated by HYDRUS 1D.•The release of soil colloids and MWCNTs with IS reduction and cation exchange was investigated.•The association of soil colloids and MWCNTs was determined by soil fractionation.•A large amount of MWCNTs was associated with water-dispersible colloids.
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