Titan's lower atmosphere has long been known to harbor organic aerosols (tholins) presumed to have been formed from simple molecules, such as methane and nitrogen (CH₄ and N₂). Up to now, it has been ...assumed that tholins were formed at altitudes of several hundred kilometers by processes as yet unobserved. Using measurements from a combination of mass/charge and energy/charge spectrometers on the Cassini spacecraft, we have obtained evidence for tholin formation at high altitudes (~1000 kilometers) in Titan's atmosphere. The observed chemical mix strongly implies a series of chemical reactions and physical processes that lead from simple molecules (CH₄ and N₂) to larger, more complex molecules (80 to 350 daltons) to negatively charged massive molecules (~8000 daltons), which we identify as tholins. That the process involves massive negatively charged molecules and aerosols is completely unexpected.
The Pioneer and Voyager spacecraft made close-up measurements of Saturn's ionosphere and upper atmosphere in the 1970s and 1980s that suggested a chemical interaction between the rings and ...atmosphere. Exploring this interaction provides information on ring composition and the influence on Saturn's atmosphere from infalling material. The Cassini Ion Neutral Mass Spectrometer sampled in situ the region between the D ring and Saturn during the spacecraft's Grand Finale phase. We used these measurements to characterize the atmospheric structure and material influx from the rings. The atmospheric He/H
ratio is 10 to 16%. Volatile compounds from the rings (methane; carbon monoxide and/or molecular nitrogen), as well as larger organic-bearing grains, are flowing inward at a rate of 4800 to 45,000 kilograms per second.
Titan's ionosphere contains a rich positive ion population including organic molecules. Here, using CAPS electron spectrometer data from sixteen Titan encounters, we reveal the existence of negative ...ions. These ions, with densities up to ∼100 cm−3, are in mass groups of 10–30, 30–50, 50–80, 80–110, 110–200 and 200+ amu/charge. During one low encounter, negative ions with mass per charge as high as 10,000 amu/q are seen. Due to their unexpectedly high densities at ∼950 km altitude, these negative ions must play a key role in the ion chemistry and they may be important in the formation of organic‐rich aerosols (tholins) eventually falling to the surface.
Composition of Titan's ionosphere Cravens, T. E.; Robertson, I. P.; Waite, J. H. ...
Geophysical research letters,
April 2006, Letnik:
33, Številka:
7
Journal Article
Recenzirano
Odprti dostop
We present Cassini Ion and Neutral Mass Spectrometer (INMS) measurements of ion densities on the nightside of Titan from April 16, 2005, and show that a substantial ionosphere exists on the nightside ...and that complex ion chemistry is operating there. The total ionospheric densities measured both by the INMS and the Cassini Radio and Plasma Wave (RPWS) experiments on Cassini suggest that precipitation from the magnetosphere into the atmosphere of electrons with energies ranging from 25 eV up to about 2 keV is taking place. The absence of ionospheric composition measurements has been a major obstacle to understanding the ionosphere. Seven “families” of ion species, separated in mass‐to‐charge ratio by 12 Daltons (i.e., the mass of carbon), were observed and establish the importance of hydrocarbon and nitrile chains in the upper atmosphere. Several of the ion species measured by the INMS were predicted by models (e.g., HCNH+ and C2H5+). But the INMS also saw high densities at mass numbers not predicted by models, including mass 18, which we suggest will be ammonium ions (NH4+) produced by reaction of other ion species with neutral ammonia.
Cassini's Grand Finale orbits provided for the first time in-situ measurements of Saturn's topside ionosphere. We present the Pedersen and Hall conductivities of the top near-equatorial dayside ...ionosphere, derived from the in-situ measurements by the Cassini Radio and Wave Plasma Science Langmuir Probe, the Ion and Neutral Mass Spectrometer and the fluxgate magnetometer. The Pedersen and Hall conductivities are constrained to at least 10
-10
S/m at (or close to) the ionospheric peak, a factor 10-100 higher than estimated previously. We show that this is due to the presence of dusty plasma in the near-equatorial ionosphere. We also show the conductive ionospheric region to be extensive, with thickness of 300-800 km. Furthermore, our results suggest a temporal variation (decrease) of the plasma densities, mean ion masses and consequently the conductivities from orbit 288 to 292.
The Cassini Ultraviolet Imaging Spectrograph (UVIS) observed an occultation of the Sun by the water vapor plume at the south polar region of Saturn's moon Enceladus. The Extreme Ultraviolet (EUV) ...spectrum is dominated by the spectral signature of H2O gas, with a nominal line‐of‐sight column density of 0.90 ± 0.23 × 1016 cm−2 (upper limit of 1.0 × 1016 cm−2). The upper limit for N2 is 5 × 1013 cm−2, or <0.5% in the plume; the lack of N2 has significant implications for models of the geochemistry in Enceladus' interior. The inferred rate of water vapor injection into Saturn's magnetosphere is ∼200 kg/s. The calculated values of H2O flux from three occultations observed by UVIS have a standard deviation of 30 kg/s (15%), providing no evidence for substantial short‐term variability. Collimated gas jets are detected in the plume with Mach numbers of 5–8, implying vertical gas velocities that exceed 1000 m/sec. Observations at higher altitudes with the Cassini Ion Neutral Mass Spectrometer indicate correlated structure in the plume. Our results support the subsurface liquid model, with gas escaping and being accelerated through nozzle‐like channels to the surface, and are consistent with recent particle composition results from the Cassini Cosmic Dust Analyzer.
Key Points
N2 upper limit
Mach number of jets ranges from 5 to 8, more collimated than previous estimate
Flux of water vapor stable over last 6 years at 200 kg/sec
Titan's upper atmosphere produces an ionosphere at high altitudes from photoionization and electron impact that exhibits complex chemical processes in which hydrocarbons and nitrogen‐containing ...molecules are produced through ion‐molecule reactions. The structure and composition of Titan's ionosphere has been extensively investigated by the Ion and Neutral Mass Spectrometer (INMS) onboard the Cassini spacecraft. We present a detailed study using linear correlation analysis, 1‐D photochemical modeling, and empirical modeling of Titan's dayside ionosphere constrained by Cassini measurements. The 1‐D photochemical model is found to reproduce the primary photoionization products of N2 and CH4. The major ions, CH5+, C2H5+, and HCNH+ are studied extensively to determine the primary processes controlling their production and loss. To further investigate the chemistry of Titan's ionosphere we present an empirical model of the ion densities that calculates the ion densities using the production and loss rates derived from the INMS data. We find that the chemistry included in our model sufficiently reproduces the hydrocarbon species as observed by the INMS. However, we find that the chemistry from previous models appears insufficient to accurately reproduce the nitrogen‐containing organic compound abundances observed by the INMS. The major ion, HCNH+, is found to be overproduced in both the empirical and 1‐D photochemical models. We analyze the processes producing and consuming HCNH+ in order to determine the cause of this discrepancy. We find that a significant chemical loss process is needed. We suggest that the loss process must be with one of the major components, namely C2H2, C2H4, or H2.
Key Points
The primary products of photoionization are well described by our model
Correlations in the INMS data show the existence of new chemical pathways
Titan's ionospheric chemistry can be represented by a 1‐D photochemical model
Between 26 April and 15 September 2017, Cassini executed 23 highly inclined Grand Finale orbits through a new frontier for space exploration, the narrow region between Saturn and the D Ring, ...providing the first opportunity for obtaining in situ ionospheric measurements. During the Grand Finale orbits, the Radio and Plasma Wave Science instrument observed broadband whistler mode emissions and narrowband upper hybrid frequency emissions. Using known wave propagation characteristics of these two plasma wave modes, the electron density is derived over a broad range of ionospheric latitudes and altitudes. A two‐part exponential scale height model is fitted to the electron density measurements. The model yields a double‐layered ionosphere with plasma scale heights of 545/575 km for the northern/southern hemispheres below 4,500 km and plasma scale heights of 4,780/2,360 km for the northern/southern hemispheres above 4,500 km. The interpretation of these layers involves the interaction between the rings and the ionosphere.
Plain Language Summary
For the final 5 months of the Cassini mission in 2017, the spacecraft executed 23 orbits through a new frontier for space exploration, the narrow region between Saturn and the innermost of Saturn's main rings, the D Ring. For the first time in the history of space exploration, the Cassini instruments were able to take measurements inside Saturn's ionosphere. This paper provides the density distribution of Saturn's ionospheric electrons, derived from plasma waves detected by the Radio and Plasma Wave Science instrument. The electron density distributions with altitude and latitude show that the ionospheric electron densities peak at 10,000 particles per cubic centimeter at low altitudes in the equatorial region and drop below 100 particles per cubic centimeter at higher altitudes and latitudes. Two simple ionospheric scale height density models for the northern and southern hemispheres are presented.
Key Points
We present the first in situ measurements of the electron density in the low to middle latitudes of Saturn's ionosphere
The distribution of electron density measurements with altitude shows evidence of a two‐layered ionospheric electron density distribution up to an altitude of 15,000 km
We present a scale height electron density model for a double‐layered ionosphere for both the northern and southern hemispheres
The importance of the heavy ions and dust grains for the chemistry and aerosol formation in Titan's ionosphere has been well established in the recent years of the Cassini mission. In this study we ...combine independent in situ plasma (Radio Plasma and Wave Science Langmuir Probe (RPWS/LP)) and particle (Cassini Plasma Science Electron Spectrometer, Cassini Plasma Science Ion Beam Spectrometer, and Ion and Neutral Mass Spectrometer) measurements of Titan's ionosphere for selected flybys (T16, T29, T40, and T56) to produce altitude profiles of mean ion masses including heavy ions and develop a Titan‐specific method for detailed analysis of the RPWS/LP measurements (applicable to all flybys) to further constrain ion charge densities and produce the first empirical estimate of the average charge of negative ions and/or dust grains. Our results reveal the presence of an ion‐ion (dusty) plasma below ~1100 km altitude, with charge densities exceeding the primary ionization peak densities by a factor ≥2 in the terminator and nightside ionosphere (ne/ni ≤ 0.1). We suggest that ion‐ion (dusty) plasma may also be present in the dayside ionosphere below 900 km (ne/ni < 0.5 at 1000 km altitude). The average charge of the dust grains (≥1000 amu) is estimated to be between −2.5 and −1.5 elementary charges, increasing toward lower altitudes.
Key Points
Detection of electron‐depleted dusty ion‐ion plasma in lower ionosphere with enhanced densities
First empirical estimate of the negative ion and dust grain charge
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