Global climate change will modify precipitation and temperatures’ temporal and spatial distribution, trigger more extreme weather events, and impact hydrological processes. The Yangtze River basin is ...one of the world’s largest basins, and understanding future climate changes is vital for water resource management and supply. Research on predicting future climate change in the upper Yangtze River basin (UYRB) and introducing machine learning algorithms to analyze the impact of climate factors, including extreme weather indicators, on surface runoff is urgently needed. In this study, a statistical downscaling model (SDSM) was used to forecast the future climate in the UYRB, and the Mann–Kendall (MK) or modified Mann–Kendall (MMK) trend test at a 5% level of significance was applied to analyze temporal trends. The Spearman rank correlation (SRC) test at a 5% level of significance and random forest regression (RFR) model were employed to identify the key climatic factors affecting surface runoff from annual precipitation, annual temperature, maximum 5-day precipitation (R×5Day), number of tropical nights (TR), and consecutive dry days (CDD), and the RFR model was also used to predict future runoff. Based on the results, we found that, compared to the selected historical period (1985–2014), the mean annual precipitation (temperature) during the mid-term (2036–2065) increased by 18.93% (12.77%), 17.78% (14.68%), 20.03% (17.03%), and 19.67% (19.29%) under SSP1-2.6, SSP2-4.5, SSP3-7.0, and SSP5-8.5, respectively, and during the long term (2071–2100), increased by 19.44% (12.95%), 22.01% (21.37%), 30.31% (30.32%), and 34.48% (37.97%), respectively. The warming and humidification characteristics of the northwestern UYRB were more pronounced. The key climatic factors influencing surface runoff were annual precipitation, maximum 5-day precipitation (R×5day), and annual temperature. Because of warming and humidification, surface runoff in the UYRB is expected to increase relative to the historical period. The surface runoff during the mid-term (long term) increased by 12.09% (12.58%), 8.15% (6.84%), 8.86% (8.87%), and 5.77% (6.21%) under SSP1-2.6, SSP2-4.5, SSP3-7.0, and SSP5-8.5, respectively. The implementation of sustainable development pathways under the low radiative forcing scenario can be effective in mitigating climate change, but at the same time, it may increase the risk of floods in the UYRB.
Serious groundwater pollution not only affects the development of enterprises but also threatens the life and health of residents. To explore the utilization potential of shallow groundwater and the ...status of water quality pollution in Daqing city, factor analysis and Kriging spatial interpolation methods were applied to analyze the spatial distribution characteristics of pollution sources. The results showed that the HCO
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-Ca + Mg type water with a maximum salinity of 1.5 g/L was the main chemical type of shallow groundwater in this area. Based on the Fe pollution index, the shallow underground water quality in the northeast of Daqing city can be used for drinking. Due to higher salinity, the locations of the availability of groundwater for irrigation only were in the west. Multivariate statistical analysis was carried out using a factor analysis method, and eight main impact factors were extracted in the study. The pollution sources of human activity impact factors were mainly found to be the direct discharge of organic matter from industrial wastewater in petrochemical enterprises and domestic sewage and the inappropriate or excessive application of agricultural fertilizers. The primary geological environment factors were mainly affected by the hydrogeological and runoff conditions in the study area. Pollution factors were mainly distributed in the northeast of the study area where the pollution was a serious problem, while those in the south-central area were fewer and the pollution was light. This study provides a scientific decision basis for the application of groundwater and the management of groundwater resources in this area.
Graphical abstract
Access to safe drinking water is one of the fundamental human rights and an important part of healthy living. This study considered various land use methods, used geostatistical analysis, and ...triangular random model to explore nitrogen pollution and estimate its potential risk to human health for local populations in Songnen Plain of Northeast China and recognize parameter uncertainties. Nitrate concentrations in groundwater ranged from 0.01 to 523.45 mg/L, more than 72.35% of the samples exceeded Grade III threshold (20 mg/L of N) as per China's standard, and nitrate nitrogen content is greater than 20 mg/L accounted for around 60% of the research area, mainly distributed in the eastern and central high plain area. The nitrate-nitrogen content of groundwater in the town land was significantly higher than that of agricultural land, and the ammonia nitrogen content was conversely. The townland's risk value was two times that of agricultural land, considering different land use methods would avoid overestimating or underestimating regional risk value. Non-carcinogenic risks (HI) of two land use were above the safety level (i.e., HI > 1), suggesting that groundwater nitrate would have significant health effects on the age groups, and further threaten children. There was a wide range of fluctuations in the uncertainty of nitrogen concentration and model evaluation parameters; triangular random model was more sensitive to data changes, which could reduce the uncertainty. The contribution rate of nitrate-nitrogen concentration to risk was above 90%, which explained the need for random sampling to improve the evaluation results reliability. The findings in this paper will provide new insight for solving uncertainties in water safety management.
•Nitrate-nitrogen content in townland was higher than that of agricultural land.•The townland's risk value was two times that of agricultural land.•Triangular stochastic models would reduce the risk uncertainty.•Nitrate-nitrogen concentration was the most sensitive to risk values.
The groundwater vulnerability assessment has been identified as an important tool of groundwater pollution prevention. In this study, the DRASTIC method was modified to estimate the groundwater ...vulnerability of porous aquifers to nitrate. The parameter system was optimized by replacing the original parameters of aquifer media, soil media, impact of the vadose zone and hydraulic conductivity with quantitative parameters of aquifer thickness, nitrate attenuation intensity, hydraulic resistance and groundwater velocity and adding pollutant input intensity to develop the DRANTHVP method. In addition, the rating scale of the DRASTIC method was revised, and the weight and influence degree of each parameter were determined using the projection pursuit dynamic clustering (PPDC) model. The DRANTHVP method was applied to the plain area of western Jilin Province, and the vulnerability index map of groundwater to nitrate pollution was established. The DRANTHVP method improved the correlation coefficient between vulnerability index and nitrate concentration to 0.720, which was more than three times that of the original DRASTIC method. And the high variance of the (ANOVA) F statistic indicated that there was less overlap between the nitrate values in different vulnerability classes. Furthermore, the DRANTHVP method produced a more uniform distribution of vulnerability classes. In short, the DRANTHVP method using the PPDC model was suitable to assess the groundwater vulnerability of porous aquifers to nitrate in the study area. Hence, the mapping of groundwater vulnerability to nitrate can provide a scientific and reasonable basis for the formulation of groundwater resource protection plan.
•The DRANTHVP method was developed based on DRASTIC method modified to assess groundwater vulnerability to nitrate.•The parameter system was optimized by quantitative parameters.•The weight and influence degree of each parameter were determined using the PPDC model.•The correlation with nitrate concentration was more than three times higher than DRASTIC method.
Dongliao River Basin (DLRB) is facing serious deterioration of water quality impacted by anthropogenic activities. As China attaches increasing importance to environmental protection, many regions ...are trying to reduce water pollution through land use changes. The long-term variations of the nonpoint source (NPS) pollution affected by land use changes in the DLRB have not been previously assessed. In this study, the contributions of land use/land cover (LULC) changes in 1980–2015 to NPS pollution were evaluated by comparing simulations under paired land use scenarios using the Soil and Water Assessment Tool (SWAT). The historical trend and ecological protection scenarios in 2025 were established based on CA–Markov model, and pollution loads in both scenarios were forecasted. Results show that the expansion of dryland and urban areas and the decline in forest and grassland coverage were the major contributors to the increase in NPS pollution in the DLRB. The expansion of paddy field resulted in an increase in actual total phosphorus (TP) but a decrease in total nitrogen (TN). In the historical trend scenario, dryland would decrease by 4.57%. TN and TP loads were 1.40% and 1.45% lower than those in 2015, respectively. In the ecological protection scenario, TN and TP loads were 3.37% and 6.11% lower than those in 2015, respectively, due to the decreased area of dryland by 7.22%. Pollutions in the riverside and southeast areas of the basin would be reduced in 2025. This finding shows that NPS pollution is controlled under the current policy.
* A model coupling water-heat-salt of unsaturated frozen soil was established. * Future temperature, precipitation, and evaporation increase in freeze-thaw period. * Soil water, heat, and salt ...transport are closely coupled during freeze-thaw period. * Freeze-thaw cycles and future climate change can exacerbate salinization.
The transport mechanisms of water, heat, and salt in unsaturated frozen soil, as well as its response to future climate change are in urgent need of study. In this study, western Jilin Province in north-eastern China was studied to produce a model of coupled water-heat-salt in unsaturated frozen soil using CoupModel. The water, heat, and salt dynamics of unsaturated frozen soil under three representative concentration pathway (RCP) scenarios were simulated to analyze the effects of future climate change on unsaturated frozen soil. The results show that water, heat, and salt migration are tightly coupled, and the soil salt concentration in the surface layer (10 cm) exhibits explosive growth after freezing and thawing. The future (2020-2099) meteorological factors in the study area were predicted using the Statistical Downscaling Model (SDSM). For RCP2.6, RCP4.5, and RCP8.5 scenarios, future temperatures during the freeze-thaw period increased by 2.68°C, 3.18°C, and 4.28°C, respectively; precipitation increased by 30.28 mm, 28.41 mm, and 32.17 mm, respectively; and evaporation increased by 93.57 mm, 106.95 mm, and 130.57 mm, respectively. Climate change will shorten the freeze-thaw period, advance the soil melting time from April to March, and enhance water and salt transport. Compared to the baseline period (1961-2005), future soil salt concentrations at 10 cm increased by 1547.54 mg/L, 1762.86 mg/L, and 1713.66 mg/L under RCP2.6, RCP4.5, and RCP8.5, respectively. The explosive salt accumulation is more obvious. Effective measures should be taken to prevent the salinization of unsaturated frozen soils and address climate change.
Abstract
Fluctuations in groundwater depth play an important role and are often overlooked when considering the transport of nitrogen in the unsaturated zone. To evaluate directly the variation of ...nitrogen transport due to fluctuations in groundwater depth, the prediction model of groundwater depth and nitrogen transport were combined and applied by least squares support vector machine and Hydrus-1D in the western irrigation area of Jilin in China. The calibration and testing results showed the prediction models were reliable. Considering different groundwater depth, the concentration of nitrogen was affected significantly with a groundwater depth of 3.42–1.71 m, while it was not affected with groundwater depth of 5.48–6.47 m. The total leaching loss of nitrogen gradually increased with the continuous decrease of groundwater depth. Furthermore, the limited groundwater depth of 1.7 m was found to reduce the risk of nitrogen pollution. This paper systematically analyzes the relationship between groundwater depth and nitrogen transport to form appropriate agriculture strategies.
Abstract
Quantifying the ways in which biological activity may alter the hydraulic properties of soils (the soil-water characteristic curves; SWCCs) is vital for understanding and engineering water ...pollution and supply systems. The study used centrifugation and a sand funnel method to determine the SWCCs of pure sandy soils with different particle sizes and sandy soils mixed with different extracellular polymeric substance (EPS) analogs. The sensitivity of correlated parameters for SWCCs obtained using a van Genuchten (VG) model was analyzed by single-factor perturbation analysis. The results show the following. (1) Fine sand has the strongest water retention ability. (2) The more polysaccharide there is in the media, the stronger its water-holding capacity. Polysaccharide not only has its strong water-holding capacity, but also changes the structure of medium to increase water-holding capacity. The humic acid and protein components had little effect on the hydrodynamic properties of fine sandy soil. (3) Sensitivity analyses revealed that the saturated water content, θs, greatly affected the ability of solute transport to reach equilibrium concentrations. Therefore, it is essential to define the range of media particles and component content, and ensure the accuracy of VG model parameters in the practical application of soil media affected by biological activity.
Few studies of frost heave mechanisms have considered multifactor interactions, particularly in unsaturated saline soils typical of northeastern China. We collected soil samples in western Jijin ...Province and assessed their potential frost heave behavior with reference to four controllable factors: soluble salt content (CSS), compactness (C), temperature (T), and water content (WC) using a two-level split-plot experiment. The resulting frost heave ratio was between −0.6% and 2.1%. Analysis of variance showed that water content, compactness, and temperature had significant effects on frost heave behavior, with water content having the strongest correlation (factor coefficient of 0.82), while content of soluble salt (CSS) had no significant effect. The interaction factors (products of single factors) CSS × WC and C × WC had significant effects on frost heave behavior. A correlation analysis using these interaction factors with experimental data drawn from previous research showed results consistent with the improved frost heave experiment as the significant effects of single factors on frost heave behavior ranked from WC > C > T and the interaction factors CSS × WC and C × WC gain had significant effects. We then established two generalized regression neural network (GRNN) models based on the single and interaction factors in order to predict frost heave behavior, showing that adding the latter to the input dataset improved the model accuracy. Thus, future research on predicting frost heave behavior in unsaturated saline soils should consider multiple interacting factor for greater accuracy.