Accurate characterization of the Chemistry Camera (ChemCam) laser-induced breakdown spectroscopy (LIBS) on-board composition targets is of prime importance for the ChemCam instrument. The Mars ...Science Laboratory (MSL) science and operations teams expect ChemCam to provide the first compositional results at remote distances (1.5–7
m) during the
in situ analyses of the Martian surface starting in 2012. Thus, establishing LIBS reference spectra from appropriate calibration standards must be undertaken diligently. Considering the global mineralogy of the Martian surface, and the possible landing sites, three specific compositions of igneous targets have been determined. Picritic, noritic, and shergottic glasses have been produced, along with a Macusanite natural glass. A sample of each target will fly on the MSL
Curiosity rover deck, 1.56
m from the ChemCam instrument, and duplicates are available on the ground. Duplicates are considered to be identical, as the relative standard deviation (RSD) of the composition dispersion is around 8%. Electronic microprobe and laser ablation inductively coupled plasma mass spectrometry (LA ICP-MS) analyses give evidence that the chemical composition of the four silicate targets is very homogeneous at microscopic scales larger than the instrument spot size, with RSD <
5% for concentration variations >
0.1
wt.% using electronic microprobe, and <
10% for concentration variations >
0.01
wt.% using LA ICP-MS. The LIBS campaign on the igneous targets performed under flight-like Mars conditions establishes reference spectra for the entire mission. The LIBS spectra between 240 and 900
nm are extremely rich, hundreds of lines with high signal-to-noise, and a dynamical range sufficient to identify unambiguously major, minor and trace elements. For instance, a first LIBS calibration curve has been established for strontium from Sr
=
284
ppm to Sr
=
1480
ppm, showing the potential for the future calibrations for other major or minor elements.
We compare element and isotopic fractionations measured in bulk solar wind samples collected by NASA's Genesis mission with those predicted from models incorporating both the ponderomotive force in ...the chromosphere and conservation of the first adiabatic invariant in the low corona. Generally good agreement is found, suggesting that these factors are consistent with the process of solar wind fractionation. Based on bulk wind measurements, we also consider in more detail the isotopic and elemental abundances of O. We find mild support for an O abundance in the range 8.75-8.83, with a value as low as 8.69 disfavored. A stronger conclusion must await solar wind regime-specific measurements from the Genesis samples.
The upper mantle and transition zone beneath Antarctica and the surrounding oceans are among the poorest‐imaged regions of the Earth's interior. Over the last 15 years, several large broadband ...regional seismic arrays have been deployed, as have new permanent seismic stations. Using data from 297 Antarctic and 26 additional seismic stations south of ~40°S, we image the seismic structure of the upper mantle and transition zone using adjoint tomography. Over the course of 20 iterations, we utilize phase observations from three‐component seismograms containing P, S, Rayleigh, and Love waves, including reflections and overtones, generated by 270 earthquakes that occurred from 2001–2003 and 2007–2016. The new continental‐scale seismic model (ANT‐20) possesses regional‐scale resolution south of 60°S. In East Antarctica, thinner continental lithosphere is found beneath areas of Dronning Maud Land and Enderby‐Kemp Land. A continuous slow wave speed anomaly extends from the Balleny Islands through the western Ross Embayment and delineates areas of Cenozoic extension and volcanism that span both oceanic and continental regions. Slow wave speed anomalies are also imaged beneath Marie Byrd Land and along the Amundsen Sea Coast, extending to the Antarctic Peninsula. These anomalies are confined to the upper 200–250 km of the mantle, except in the vicinity of Marie Byrd Land where they extend into the transition zone and possibly deeper. Finally, slow wave speeds along the Amundsen Sea Coast link to deeper anomalies offshore, suggesting a possible connection with deeper mantle processes.
Key Points
The strongest variability in East Antarctic lithosphere is observed across Dronning Maud Land and Enderby‐Kemp Land
A slow anomaly extends from the Balleny Islands through the western Ross Embayment, delineating areas of Cenozoic extension and volcanism
Slow anomalies imaged beneath Marie Byrd Land, the Amundsen Sea Coast, and the Antarctic Peninsula reflect hotspot and subduction processes
•Passive ChemCam observations were used to retrieve relative reflectance spectra of Mars.•First high spectral/spatial resolution 400–840nm in situ observations of Mars.•Spectra consistent with ...iron-bearing oxides, pyroxenes, and calcium sulfates.
The spectrometers on the Mars Science Laboratory (MSL) ChemCam instrument were used in passive mode to record visible/near-infrared (400–840nm) radiance from the martian surface. Using the onboard ChemCam calibration targets’ housing as a reflectance standard, we developed methods to collect, calibrate, and reduce radiance observations to relative reflectance. Such measurements accurately reproduce the known reflectance spectra of other calibration targets on the rover, and represent the highest spatial resolution (0.65mrad) and spectral sampling (<1nm) visible/near-infrared reflectance spectra from a landed platform on Mars. Relative reflectance spectra of surface rocks and soils match those from orbital observations and multispectral data from the MSL Mastcam camera. Preliminary analyses of the band depths, spectral slopes, and reflectance ratios of the more than 2000 spectra taken during the first year of MSL operations demonstrate at least six spectral classes of materials distinguished by variations in ferrous and ferric components. Initial comparisons of ChemCam spectra to laboratory spectra of minerals and Mars analog materials demonstrate similarities with palagonitic soils and indications of orthopyroxene in some dark rocks. Magnesium-rich “raised ridges” tend to exhibit distinct near-infrared slopes. The ferric absorption downturn typically found for martian materials at <600nm is greatly subdued in brushed rocks and drill tailings, consistent with their more ferrous nature. Calcium-sulfate veins exhibit the highest relative reflectances observed, but are still relatively red owing to the effects of residual dust. Such dust is overall less prominent on rocks sampled within the “blast zone” immediately surrounding the landing site. These samples were likely affected by the landing thrusters, which partially removed the ubiquitous dust coatings. Increased dust coatings on the calibration targets during the first year of the mission were documented by the ChemCam passive measurements as well. Ongoing efforts to model and correct for this dust component should improve calibration of the relative reflectance spectra. This will be useful as additional measurements are acquired during the rover’s future examinations of hematite-, sulfate-, and phyllosilicate-bearing materials near the base of Mt. Sharp that are spectrally active in the 400–840nm region.
The Mars Science Laboratory rover Curiosity found host rocks of basaltic composition and alteration assemblages containing clay minerals at Yellowknife Bay, Gale Crater. On the basis of the observed ...host rock and alteration minerals, we present results of equilibrium thermochemical modeling of the Sheepbed mudstones of Yellowknife Bay in order to constrain the formation conditions of its secondary mineral assemblage. Building on conclusions from sedimentary observations by the Mars Science Laboratory team, we assume diagenetic, in situ alteration. The modeling shows that the mineral assemblage formed by the reaction of a CO2‐poor and oxidizing, dilute aqueous solution (Gale Portage Water) in an open system with the Fe‐rich basaltic‐composition sedimentary rocks at 10–50°C and water/rock ratio (mass of rock reacted with the starting fluid) of 100–1000, pH of ~7.5–12. Model alteration assemblages predominantly contain phyllosilicates (Fe‐smectite, chlorite), the bulk composition of a mixture of which is close to that of saponite inferred from Chemistry and Mineralogy data and to that of saponite observed in the nakhlite Martian meteorites and terrestrial analogues. To match the observed clay mineral chemistry, inhomogeneous dissolution dominated by the amorphous phase and olivine is required. We therefore deduce a dissolving composition of approximately 70% amorphous material, with 20% olivine, and 10% whole rock component.
Key Points
Thermochemical modelling constrains the secondary minerals in Gale Crater
Inhomogeneous dissolution of amorphous and olivine phases forms clay, magnetite
Formed by reaction of CO2‐poor, oxidising brine with basaltic sedimentary rocks
In Situ Analysis of Opal in Gale Crater, Mars Rapin, W.; Chauviré, B.; Gabriel, T. S. J. ...
Journal of geophysical research. Planets,
August 2018, Letnik:
123, Številka:
8
Journal Article
Recenzirano
Odprti dostop
Silica enrichments resulting in up to ~90 wt% SiO2 have been observed by the Curiosity rover's instruments in Gale crater, Mars, within the Murray and Stimson formations. Samples acquired by the ...rover drill revealed a significant abundance of an X‐ray amorphous silica phase. Laser‐induced breakdown spectroscopy (LIBS) highlights an overall correlation of the hydrogen signal with silica content for these Si‐enriched targets. The increased hydration of the high‐silica rocks compared to the surrounding bedrock is also confirmed by active neutron spectroscopy. Laboratory LIBS experiments have been performed to calibrate the hydrogen signal and show that the correlation observed on Mars is consistent with a silica phase containing on average 6.3 ± 1.4 wt% water. X‐ray diffraction and LIBS measurements indicate that opal‐A, amorphous hydrated silica, is the most likely phase containing this water in the rocks. Pyrolysis experiments were also performed on drilled samples by the Sample Analysis at Mars (SAM) instrument to measure volatile content, but the data suggests that most of the water was released during handling prior to pyrolysis. The inferred low‐temperature release of water helps constrain the nature of the opal. Given the geological context and the spatial association with other phases such as calcium sulfates, the opal was likely formed from multiple diagenetic fluid events and possibly represents the latest significant water‐rock interaction in these sedimentary rocks.
Key Points
Sedimentary rocks with high amorphous silica content were analyzed at Gale crater on Mars
Calibration of the LIBS hydrogen signal reveals >4 wt% water content associated with silica
The stability of opal‐A over several billion years is an anomaly relative to terrestrial mineralogy
SUMMARY
We determine crustal shear wave velocity structure and crustal thickness at recently deployed seismic stations across West Antarctica, using a joint inversion of receiver functions and ...fundamental mode Rayleigh wave phase velocity dispersion. The stations are from both the UK Antarctic Network (UKANET) and Polar Earth Observing Network/Antarctic Network (POLENET/ANET). The former include, for the first time, four stations along the spine of the Antarctic Peninsula, three in the Ellsworth Land and five stations in the vicinity of the Pine Island Rift. Within the West Antarctic Rift System (WARS) we model a crustal thickness range of 18–28 km, and show that the thinnest crust (∼18 km) is in the vicinity of the Byrd Subglacial Basin and Bentley Subglacial Trench. In these regions we also find the highest ratio of fast (Vs = 4.0–4.3 km s–1, likely mafic) lower crust to felsic/intermediate upper crust. The thickest mafic lower crust we model is in Ellsworth Land, a critical area for constraining the eastern limits of the WARS. Although we find thinner crust in this region (∼30 km) than in the neighbouring Antarctic Peninsula and Haag-Ellsworth Whitmore block (HEW), the Ellsworth Land crust has not undergone as much extension as the central WARS. This suggests that the WARS does not link with the Weddell Sea Rift System through Ellsworth Land, and instead has progressed during its formation towards the Bellingshausen and Amundsen Sea Embayments. We also find that the thin WARS crust extends towards the Pine Island Rift, suggesting that the boundary between the WARS and the Thurston Island block lies in this region, ∼200 km north of its previously accepted position. The thickest crust (38–40 km) we model in this study is in the Ellsworth Mountain section of the HEW block. We find thinner crust (30–33 km) in the Whitmore Mountains and Haag Nunatak sectors of the HEW, consistent with the composite nature of the block. In the Antarctic Peninsula we find a crustal thickness range of 30–38 km and a likely dominantly felsic/intermediate crustal composition. By forward modelling high frequency receiver functions we also assess if any thick, low velocity subglacial sediment accumulations are present, and find a 0.1–0.8-km-thick layer at 10 stations within the WARS, Thurston Island and Ellsworth Land. We suggest that these units of subglacial sediment could provide a source region for the soft basal till layers found beneath numerous outlet glaciers, and may act to accelerate ice flow.
Recently, there has been an increasing interest in the laser-induced breakdown spectroscopy (LIBS) technique for stand-off detection of geological samples for use on landers and rovers to Mars, and ...for other space applications. For space missions, LIBS analysis capabilities must be investigated and instrumental development is required to take into account constraints such as size, weight, power and the effect of environmental atmosphere (pressure and ambient gas) on flight instrument performance. In this paper, we study the in-situ LIBS method at reduced pressure (7 Torr CO
2 to simulate the Martian atmosphere) and near vacuum (50 mTorr in air to begin to simulate the Moon or asteroids' pressure) as well as at atmospheric pressure in air (for Earth conditions and comparison). Here in-situ corresponds to distances on the order of 150 mm in contrast to stand-off analysis at distance of many meters. We show the influence of the ambient pressure on the calibration curves prepared from certified soil and clay pellets. In order to detect simultaneously all the elements commonly observed in terrestrial soils, we used an Echelle spectrograph. The results are discussed in terms of calibration curves, measurement precision, plasma light collection system efficiency and matrix effects.
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