The aim of this paper is the presentation of the current state-of-the-art about the determination of polycyclic aromatic hydrocarbons (PAHs) and their oxidized forms originating from Suspended ...Particulate Matter (SPM) samples. The influence of SPM on health is twofold. SPM, as composed of small particles, is dangerous for the respiratory system. Additionally, SPM is a carrier of many hazardous compounds, particularly PAHs. Recently, several researches focus on the derivatives of PAHs, particularly nitro-, oxy- and hydroxy-PAHs, which are more dangerous than the parent PAHs. Both gas and high-performance liquid chromatography with various detection techniques are used to analyze both PAHs and their oxidized forms. Due to the appearance of these compounds in the environment, at a very low level, an analyte concentration step has to be applied prior to analysis. If GC and HPLC techniques are chiefly used as analytical tools for these analyses, the spectrum of analyte concentration procedures is very broad. Many analyte concentration techniques are proposed: from classic liquid-solid extractions, including Soxhlet technique, pressurized liquid extraction (ASE) or microwave oven (MWE) and sonic supported extraction to SPE techniques applications. However, one should remember that PAH determination methods are tools for solving the main problem, i.e., the evaluation the health hazard connected to the presence of SPM in air. Thus, the main drawback of several papers found in this review, i.e., the lack of information concerning limit of detection (LOD) of these methods makes their applicability very limited.
Oxidation of water or wastewaters with classical oxidants such as chloramine, chlorine dioxide, ozone or permanganate may lead to formation of carcinogenic N-nitrosodimethylamine (NDMA), when ...dimethylamine (DMA) is present as water pollution. This study shows that peroxydisulfate (PDS) could be considered as relatively ‘safe’ oxidant as PDS partly destroys dimethylamine without formation of NDMA. Prior to use, peroxydisulfate was activated. Metal ions Fe
+2
, UV radiation and metal oxides CuO were compared as activator compounds to understand their efficiency in PDS systems (radical and non-radical) for oxidation of DMA. The amount of nitrate formed as the result of nitrogen oxidation, as well as formaldehyde (FA), formed as the result of methyl groups oxidation, was monitored as an indicator of DMA degradation. Application studies conducted on natural water showed that activated peroxydisulfate can effectively protect against the undesirable NDMA formation.
The presence of a neutron halo in 15C has been demonstrated in several reaction experiments at intermediate energies. In the present study, the dynamical effects of this structure are observed for ...the first time at Coulomb barrier energies in the 15C + 208Pb quasi-elastic scattering at Elab=65 MeV, measured at the HIE-ISOLDE facility, CERN using the high-granularity detector array GLORIA. A combined continuum discretised coupled channels and coupled reaction channels calculation describes the data well and significant coupling effects due both to breakup and single-neutron stripping are identified.
Adaptive computing on the Grid using AppLeS Berman, F.; Wolski, R.; Casanova, H. ...
IEEE transactions on parallel and distributed systems,
04/2003, Letnik:
14, Številka:
4
Journal Article
Recenzirano
Ensembles of distributed, heterogeneous resources, also known as computational grids, have emerged as critical platforms for high-performance and resource-intensive applications. Such platforms ...provide the potential for applications to aggregate enormous bandwidth, computational power, memory, secondary storage, and other resources during a single execution. However, achieving this performance potential in dynamic, heterogeneous environments is challenging. Recent experience with distributed applications indicates that adaptivity is fundamental to achieving application performance in dynamic grid environments. The AppLeS (Application Level Scheduling) project provides a methodology, application software, and software environments for adaptively scheduling and deploying applications in heterogeneous, multiuser grid environments. We discuss the AppLeS project and outline our findings.
.
Many fusion experimental data have been analyzed in terms of a simple universal function which could be used for predictions of fusion cross section below the barrier for arbitrary systems. ...Sub-barrier fusions based on the concept of
Q
-fusion value dependence were studied. It is attempted to parameterize the energy-reduced fusion excitation functions around the Coulomb barriers by an analytical phenomenological function. It was found that the speed of driving nuclei towards fusion is faster with the increase of mass asymmetry of colliding systems and those systems with a large difference of the ratio of neutrons to protons. However, a general trend with respect to total mass has not been observed. An exposition of more qualitative conclusions is hindered by apparent inconsistencies of measured fusion cross sections.
The proton and deuteron pickup reactions
and
were studied with the
radioactive beam produced by the new fragment separator ACCULINNA-2 at FLNR, JINR. These measurements were initially motivated as ...the test reactions intended for the elucidation of results obtained in the study of the extremely neutron-rich
H and
H systems created in the
and
reactions with the use of the same setup. In the
reaction the
Li ground-state (
) and its first excited state (2.69 MeV,
) were identified in the low-energy region of its excitation spectrum. The differential cross sections for the
population were extracted at the forward center-of-mass angles (
) and compared with the FRESCO calculations. Spectroscopic factor of
, derived by a model suggesting the
clustering was found in accord with the experimental data. The energy spectrum of
Li populated in the
reaction shows the strong peak which corresponds to the excitation of the second excited state of
Li (2.25 MeV,
). The fact that the ground and the first excited states of
Li were not observed in this reaction is consistent with the shell-model structure of the nuclei involved.
Setup fitting the requirements for the detailed study of the five-body decay of the
7
H nucleus obtained as a result of the proton transfer from the
8
He projectiles to the deuterium target nuclei is ...being built at the radioactive beam line of ACCULINNA-2 separator in the G.N. Flerov Laboratory of Nuclear Reactions. Described here is the assembly of 100 BC-404 plastic scintillators, intended for neutron detection, the annular Si detector telescope for the
3
He recoils, and the detector array providing the Δ
E
–
E
-TOF registration of
3
H nuclei emitted at the
7
H decay. Results obtained by the Monte Carlo simulations made for the energy values and flight passes of all these particles are given together with the luminosity expected for the discussed experiments.
The low-lying spectroscopy of 6He was investigated via the 2-neutron transfer reaction p (He 8 , t) with the 8He beam delivered by the SPIRAL facility at 15.4 A MeV . The light charged particles ...produced by the direct reactions were measured using the MUST2 Si-strip telescope array. Above the known 2 + state, two new resonances were observed: at E a = 2.6 +/- 0.3 MeV (width Phi = 1.6 +/- 0.4 MeV) and at 5.3 +/- 0.3 MeV with Phi = 2 +/- 1 MeV . Through the analysis of the angular distributions, they correspond to a 2 + state and to an L = 1 state, respectively. These new states, challenging the nuclear theories, could be used as benchmarks for checking the microscopic inputs of the newly improved structure models, and should trigger development of models including the treatments of both core excitation and continuum coupling effects.
The neutron rich carbon isotope 15C is the only known case of an almost "pure" 2s1/2 single-neutron halo ground state configuration. At collision energies around the Coulomb barrier the reaction ...dynamics is expected to be dominated by single neutron transfer and breakup. To investigate these effects, we have measured the scattering of 15C with a 208Pb target at 65 MeV at the HIE-ISOLDE facility in CERN (Geneva, Switzerland). The preliminary data demonstrates the presence of a strong long-range absorption pattern in the angular distribution of the elastic cross section. The results are discussed in the framework of Optical Model calculations.
In the recent work Nikolskii et al., Phys. Rev. C 105, 064605 (2022) the 2H(8He,4He)6H reaction was used for the study of the extreme neutron-rich 6H isotope. A broad bump was observed in the ...measured 6H spectrum interpreted as the broad overlapping ground and some low-lying states of this nuclide. There could be certain doubts in the interpretation of this work: in conditions of the limited phase space it is not impossible that the structure in the missing mass spectrum of 6H is actually induced by the resonant states populated by some other channels opened in the 8He+2H interaction. This work provides a body of the evidence for the correct channel identification and for the absence of the 6H resonances at energy ET = 0 − 3.5 MeV above the 3H+3n decay threshold. In addition the first strong experimental evidence is given that the 6H → 5H*+n → 3H+3n sequential decay is the dominating 6H decay channel.
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