The essence of rational design syntheses of functional inorganic materials lies in understanding and control of crystal structures that determine the physical properties. AgGaS2 has the highest ...figure of merit for IR nonlinear optical interactions to date, but suffers low laser‐induced damage threshold (LIDT). The partial Li substitution of Ag atoms is now shown to push up the bottom of the conduction band and flatten the top of the valence band, leading to an ultrawide band gap of 3.40 eV (record high for AgGaS2, indicating a transparency edging nearly 180 nm shorter than that of AgGaS2), which gives Li0.60Ag0.40GaS2 a LIDT 8.6 times stronger when AgGaS2 is compared. Li0.60Ag0.40GaS2 exhibits 1.1 times stronger nonlinear susceptibility, which is because the energy‐favorable Li substitution gradually decreases the sulfur dislocation in the lattice, which allows a better geometric superposition of nonlinear optical tensors.
Lithium substitution maintains the symmetry of AgGaS2 structure and leads to an ultrawide band gap, simultaneously enhanced laser induced damage threshold (LIDT), and large second harmonic generation (SHG) that are otherwise inversely correlated. These enhancements are governed by the energy‐favorable decrease in dislocation in the lattice.
Rumination is strongly and consistently correlated with depression. Although multiple studies have explored the neural correlates of rumination, findings have been inconsistent and the mechanisms ...underlying rumination remain elusive. Functional brain imaging studies have identified areas in the default mode network (DMN) that appear to be critically involved in ruminative processes. However, a meta-analysis to synthesize the findings of brain regions underlying rumination is currently lacking. Here, we conducted a meta-analysis consisting of experimental tasks that investigate rumination by using Signed Differential Mapping of 14 fMRI studies comprising 286 healthy participants. Furthermore, rather than treat the DMN as a unitary network, we examined the contribution of three DMN subsystems to rumination. Results confirm the suspected association between rumination and DMN activation, specifically implicating the DMN core regions and the dorsal medial prefrontal cortex subsystem. Based on these findings, we suggest a hypothesis of how DMN regions support rumination and present the implications of this model for treating major depressive disorder characterized by rumination.
•Rumination is strongly and consistently correlated with depression.•Meta-analyze the findings of brain regions regarding to rumination.•Specifically examined the contribution of three DMN subsystems to rumination.•Rumination is specifically correlated with the DMN core regions and the dorsal medial prefrontal cortex subsystem.
Novel molybdenum(VI/V) POM‐based self‐constructed frameworks MoVI12O24(μ2‐O)12(trz)6(H2O)6 ⋅ 6Hma ⋅ 18H2O (1, Htrz=1H‐1,2,3‐triazole, ma=methylamine), MoVI7O14(μ2‐O)8(trz)5(H2O) ⋅ 7Hma ⋅ 5H2O (2), ...Na3MoV6O6(μ2‐O)9(Htrz)3(trz)3 ⋅ 7.5H2O (3) and MoV8O8(μ2‐O)12(Htrz)8 ⋅ 30H2O (4) have been covalently decorated with tri‐coordinated deprotonated/protonated 1,2,3‐triazoles. Channels with an inner diameter of 7.5 Å were found in 1, whereas a tunnel composed of stacking molecules with an inner diameter of 4.1 Å along the b‐axis exists in 2; it is occupied by free disordered methylamines, showing selective adsorption of O2 and CO2 at 25 °C. Obvious downfield shifts were observed by 13C NMR spectroscopies for methylamines inside the confined channels in 1 and 2. There are diversified pores in 3 and 4, which are formed by the molecules themselves and intermolecular accumulations. Adsorption tests indicate that 3 and 4 are fine adsorption materials for CH4 and CO2 under low pressure that rely on the environments built by the POMs. Correspondingly, 1 and 2 display reversible photoresponsive thermochromism that is subtlety influenced by the channels. The polyoxometalate organic frameworks (POMOFs) with multiple functional adsorptions are easy to assemble. Their photo‐/thermoresponse properties offer a new pathway for the self‐constructions of one‐off hybrid materials that possess the good properties of both POMs and MOFs.
Best of both worlds: Novel intrinsic polyoxometalate (POM)‐based microporous frameworks with 1H‐1,2,3‐triazoles as auxiliary agents possess an impressive interrelated nature derived from both POM and MOFs, for example, excellent adsorption affinities for common gases like CO2, O2 and CH4 as well as admirable photochromic properties.
Summary
Clinical trials have investigated the weight loss effect of glucagon‐like peptide‐1 receptor agonists (GLP‐1 RA) in adults with obesity without diabetes mellitus, but results for weight loss ...efficacy were varied. We aimed to provide an up‐to‐date systematic review and meta‐analysis for overall weight loss effect of GLP‐1 RA in adults with obesity and overweight without diabetes mellitus. We retrieved eligible randomized control trials that assessed the weight loss effect of GLP‐1 RA in adults (≥18 years old) without type 1/type 2 diabetes up to September 30, 2021, using Pubmed and Embase. Of 36 clinical trials assessed for eligibility, 12 trials were included, with a combined total of 11,459 participants. Compared with control groups, a more significant weight loss was seen in GLP‐1 RA groups with an overall mean difference of −7.1 kg (95% CI −9.2 to −5.0) (I2 = 99%). The overall analysis results showed that GLP‐1 RA improved glycemic control without increasing the risk of hypoglycemic events. Better control of blood pressure and plasma levels of LDL, HDL, and triglycerides was seen with GLP‐1 RA treatment. Subgroup analysis showed greater treatment effect of semaglutide than liraglutide. Vomiting, nausea, dyspepsia, diarrhea, constipation, and abdominal pain were GLP‐1 RA‐associated common adverse effects.
Mobile power sources (MPSs), including electric vehicle fleets, truck-mounted mobile energy storage systems, and mobile emergency generators, have great potential to enhance distribution system (DS) ...resilience against extreme weather events. However, their dispatch is not well investigated. This paper implements resilient routing and scheduling of MPSs via a two-stage framework. In the first stage, i.e., before the event, MPSs are pre-positioned in the DS to enable rapid pre-restoration, in order to enhance survivability of the electricity supply to critical loads. DS network is also proactively reconfigured into a less impacted or stressed state. A two-stage robust optimization model is constructed and solved by the column-and-constraint generation algorithm to derive first-stage decisions. In the second stage, i.e., after the event, MPSs are dynamically dispatched in the DS to coordinate with conventional restoration efforts, so as to enhance system recovery. A novel mixed-integer programming model that resolves different timescales of MPS dispatch and DS operation, coupling of road and power networks, etc., is formulated to optimize dynamic dispatch of MPSs. Case studies conducted on IEEE 33-node and 123-node test systems demonstrate the proposed method's effectiveness in routing and scheduling MPSs for DS resilience enhancement.
Chiral chromophores and their ordered assemblies are intriguing for yielding circularly polarized luminescence (CPL) and exploring intrinsic structure–light emission relationships. With the ...extensively studied chiral organic molecules and inorganic nanoparticle assemblies for the amplified CPL, the assemblies of copper halide hybrid clusters have attracted intensive attention due to their potential efficient CPL. Here, we report robust chiral phosphine–copper iodide hybrid clusters and their layered assemblies in crystalline states for amplified CPL. We reveal that the intermolecular interactions endow the clusters with the capability of assembling into chiral crystalline CPL materials, including hexagonal platelet-shaped microcrystals (g lum ≈ 9.5 × 10–3) and highly oriented crystalline films (g lum ≈ 5 × 10–3). Owing to the high crystalline feature of the thin film, we demonstrate an electroluminescent device with bright electroluminescence (1200 cd m–2).
The cyanine fluorophores, a kind of classic organic fluorophores, are famous for their high extinction coefficient, simple synthetic route, and relatively long absorption and emission wavelengths. ...Moreover, the excellent biocompatibility and low toxicity in biological samples make cyanine fluorophores show excellent application value in the biomedical field, especially in Near-Infrared II (NIR-II) sensing and imaging. In this review, we briefly outline the history, characteristics, and current state of development of cyanine fluorophores. In particular, we described the application of cyanine fluorophores in NIR-II sensing and imaging. We hope this review can help researchers grab the latest information in the fast-growing field of cyanine fluorophores for NIR-II sensing and imaging.
Fly ash is the fine solid particulate residue driven out of the boiler with the flue gases in coal-fired power plants. Now it can be used for making geopolymer which acts as a cement-like product. ...The geopolymer technology provides an alternative good solution to the utilization of fly ash with little negative impact on environment. This review summarizes and examines the scientific advances in the preparation, properties and applications of fly ash-based geopolymer. The production of fly ash-based geopolymer is mainly based on alkali activated geopolymerization which can occur under mild conditions and is considered as a cleaner process due to much lower CO2 emission than that from the production of cement. The geopolymerization can trap and fix the trace toxic metal elements from fly ash or external sources. The Si/Al ratios, the type and the amount of the alkali solution, the temperature, the curing conditions, and the additives are critical factors in a geopolymerization process. The mechanical performances of the fly ash-based geopolymer, including compressive strength, flexural and splitting tensile strength, and durability such as the resistance to chloride, sulfate, acid, thermal, freeze-thaw and efflorescence, are the primary concerns. These properties of fly ash-based geopolymer are inherently dependent upon the chemical composition and chemical bonding and the porosity. The mechanical properties and durability can be improved by fine tuning Si/Al ratios, alkali solutions, curing conditions, and adding slag, fiber, rice husk-bark ash and red mud. Fly ash-based geopolymer is expected to be used as a kind of novel green cement. Fly ash-based geopolymer can be used as a class of materials to adsorb and immobilize toxic or radioactive metals. The factors affecting the performances of fly ash-based geopolymer concrete, in particular aggregate, are discussed. For future studies on fly ash-based geopolymer, further enhancing mechanical performance, scaling up production and exploring new applications are suggested.
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•Fly ash is activated by alkali to form geopolymer and such a process is cleaner.•Slag, rice husk-bark ash, fiber and red mud are added to improve the performance of fly ash-based geopolymer.•Mechanical properties and durability of fly ash-based geopolymer are main concerns.•Fly ash-based geopolymer is used as cement and as fixation materials for toxic metals.•Improving performance, scaling-up production and finding new applications are proposed for future.
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