•The chemical weathering intensity in Maritime Antarctica is modeled.•A geophysical survey and lithological characteristics as input data.•Proximal geophysical sensors and terrain attributes are ...combined for modeling.•Use of leave-one-out-cross-validation method in modeling.•Periglacial processes control the distribution of geophysical variables.
The chemical weathering intensity in Antarctica is underestimated. As the chemical weathering intensity increases, hydrological, geochemical and geophysical changes occur in the different environmental spheres and at their interfaces through reactions and energy flows. Thus, once chemical weathering rates are understood and estimated, they can be used to predict and assess changes and trends in different environmental spheres. Few studies on the chemical weathering intensity have been performed in Antarctica. We used radiometric and magnetic properties associated with terrain attributes and the chemical degree of alteration of the igneous rock to model the chemical weathering intensity in Maritime Antarctica by using machine learning. Then, we related the chemical weathering intensity and geophysical variables with periglacial processes. To do this, gamma-spectrometric and magnetic readings were carried out using proximal-field sensors at 91 points located on different lithologies in a representative area of Maritime Antarctica. A qualitative analysis of chemical alteration for the different lithologies was carried out based on field observations and rock properties, and the levels of the chemical weathering degree were established. The geophysical data associated with terrain attributes were used as input data in the modeling of the weathering intensity. Then, the levels of the rock weathering degree were used as the “y” variable in the models. The results indicated that the C5.0 algorithm had the best performance in predicting the weathering intensity, and the most important variables were eTh, 40K, 40K/eTh, 40K/eU, the magnetic susceptibility and terrain attributes. The contents of radionuclides and ferrimagnetic minerals in different lithologies, concomitantly with the intensity at which chemical weathering occurs, determine the contents of these elements. However, the stability and distribution of these elements in a cold periglacial environment are controlled by periglacial processes. The chemical weathering intensity prediction model using gamma-spectrometric and magnetic data matched the in situ estimate of the chemical degree of alteration of the rock. The pyritized andesites showed the highest intensities of weathering, followed by tuffites, diorites, andesitic basalts and basaltic andesites, and the lowest weathering intensity was shown by undifferentiated marine sediments. This work highlighted the suitability of using machine learning techniques and proximal-field sensor data to study the chemical weathering process on different rocks in these important and inhospitable areas of the cryosphere system.
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•Two distinct groups of mafic dykes emplaced in same NW-SE structures in SE Brazil.•Ca. 140 Ma tholeiitic dykes related to West Gondwana breakup.•Ca. 500 Ma alkaline dykes related to ...gravitational collapse of the Araçuaí Orogen.•They are distinguished by petrographic, geochemical and isotopic signatures.•Reactivation of structures as magma conduits in distinct tectonic settings and ages.
Mafic dyke swarms emplaced in regional NW-SE trending structures crosscutting the Precambrian basement in the Southeastern Brazilian coast are commonly interpreted as associated to West Gondwana breakup. Recently, however, U-Pb dating suggested that at least some of those dykes were emplaced earlier, at ca. 500–490 Ma, during the gravitational collapse of the Araçuaí Orogen. In order to clarify this issue, we studied dykes from the southern Espírito Santo State. Our results indicate that dykes emplaced in the same regional lineaments can be separated into two distinct groups, according to petrographic, geochemical, isotopic and geochronological characteristics. Group 1 is tholeiitic, with 87Sr/86Sr(i) of 0.7041–0.7065, εNd(t) of −3.4 to −5.5 and TDM ages between 0.8 and 1.5 Ga. Zircon crystals from a dyke of this group yielded the first robust lower Cretaceous U-Pb age for mafic dykes of SE Brazil with a Concordia age of 141.9 ± 1.9 Ma and εHf(t) in a range of −5.5 to −7.9. Group 2 is alkaline, shows higher 87Sr/86Sr(i) of 0.7064–0.7088, evolved εNd(t) < −12 and older TDM ages of 1.7–1.9 Ga. The youngest zircon crystals from a dyke of this group yielded a Concordia age of 504.7 ± 6.9 Ma and εHf(t) of −18.9. Our results suggest that the regional NW-SE trending lineaments of the Brazilian coast were active in at least three episodes, serving as conduits for mafic magmatism of distinct sources and tectonic settings: First, in the Cambrian, during the Araçuaí-Ribeira Orogen collapse, when they served as conduits for both the post-tectonic G5 Supersuite (530–490 Ma; composed of granitic and mafic plutons) and the alkaline dykes of Group 2; second, during the lower Cretaceous breakup of West Gondwana, when they served as conduits for the tholeiitic dykes of Group 1, synchronous to syn-rift evolution of the Phanerozoic Brazilian coast basins; and third, during the Cenozoic, when they were reactivated as normal brittle faults.
The Araçuaí and Ribeira orogens have been studied for decades, and recently, these two orogens were described as the Araçuaí–Ribeira Orogen System. Despite much work investigating this orogenic ...system, some issues, such as the connection between the two orogens, are still not fully understood. This work aimed to present unpublished Lu-Hf data for the Santa Angélica Intrusive Complex (SAIC) and for the host rocks that are part of the Rio Negro magmatic arc, as well as to present U-Pb ages for these rocks, thus contributing to the understanding of the geological processes that acted in the transition zone between the Araçuaí and Ribeira orogens. Two samples were collected corresponding to the magmatic arc and six samples from the Santa Angélica Intrusive Complex. The zircon grains were separated from the samples and subjected to geochronological (U-Pb) and isotopic (Lu-Hf) analysis by laser ablation-induced coupled plasma mass spectrometry (LA-ICP-MS). The geochronological data for the host rocks indicate a crystallization age of ca. 595 Ma. In contrast, the Hf isotopic data point to at least two magmatic sources, one crust, and one mantle. The geochronological data obtained for the SAIC rocks show three age peaks. The first peak (537 ± 5 Ma) coincides with the process of crustal anatexis and possibly marks the beginning of the generation of magmas associated with post-collisional magmatism. The second peak (510 ± 5 Ma) registers the apex of crystallization of the SAIC, and the third peak of ages (488 ± 7 Ma) marks the upper limit of the magmatism in the SAIC. The SAIC isotopic data point to at least two crustal components and a mantle component (juvenile).
This paper concerns the study of petrography, mineral chemistry and geochronology of skarns generated at the contact of marbles of the Paraíba do Sul Complex with felsic and metamafic dykes in the ...southern Espírito Santo State. The marbles were metamorphosed under P-T granulite facies conditions during the syn-collisional stage of the Neoproterozoic Araçuaí orogen. Metamafic bodies are composed of amphibolite and hornblende granofels, while felsic dykes consist of alkali-feldspar granite, monzogranite or syenogranite. From marble towards the dyke, skarns related to the metamafic bodies are composed of carbonate + olivine and diopside + hornblende zones. Skarn associated to the granitic dykes are composed of three different zones: carbonate + tremolite, diopside, scapolite + diopside. Variations in mineral chemical compositions along the metasomatic zones suggest introduction of Mg and Ca from the marbles, Fe from the metamafic dykes and Na from the granitoids. The presence of spinel in the metamafic dykes and their skarns indicates that both were metamorphosed under granulite facies conditions during the 580-560 Ma syn-collisional stage. U-Pb zircon geochronology (LA-ICP-MS) of an alkali-feldspar granite dyke resulted in a crystallization age of ca.540 Ma, which suggests that its skarns are therefore younger than skarns associated with the syn-collisional metamafic dykes.
RESUMO: Este trabalho apresenta o estudo de petrografia, química mineral e geocronologia de escarnitos gerados no contato de mármores do Complexo Paraíba do Sul com diques metamáficos e félsicos, no sul do Espírito Santo. Os mármores foram metamorfizados sob condições de pressão e temperatura da fácies granulito durante a fase sin-colisional do orógeno neoproterozoico Araçuaí. Os corpos metamáficos são compostos de anfibolito e hornblenda granofels, enquanto os diques félsicos consistem de álcali-feldspato granito, monzogranito ou sienogranito. Do mármore para o dique, escarnitos associados com os diques metamáficos são compostos das zonas carbonato + olivina e diopsídio + hornblenda. Escarnitos associados com os diques graníticos são compostos de três zonas mineralógicas distintas: carbonato + tremolita, diopsídio e escapolita + diopsídio. Variações na composição química mineral ao longo das zonas metassomáticas sugerem introdução de Mg e Ca dos mármores, Fe dos diques metamáficos e Na dos granitos. A presença de espinélio nos diques metamáficos e em seus escarnitos indica que ambos foram metamorfizados sob condições de fácies granulito durante o estágio sin-colisional (580-560 Ma). A geocronologia U-Pb via LA-ICP-MS em zircões de um dique de álcali-feldspatogranito resultou em uma idade de cristalização de ca.540 Ma, o que sugere que seus escarnitos são, portanto, mais novos que os escarnitos associados com os diques metamáficos sin-colisionais.
The Afonso Cláudio Intrusive Complex (ACIC) is an inversely zoned pluton that intruded the Araçuaí-West Congo Orogen (AWCO) during the orogenic collapse, which lasted from 530 to 480 Ma. It is hosted ...in orthogneisses of the Pre-collisional Supersuite and paragneisses from Nova Venécia Complex and is mostly constituted by two off-centered mafic cores, composed by monzogabbro and monzodiorite, surrounded by quartz monzonite hills. Mingling and mixing zones were mapped between these rocks, where jotunite and quartz mangerite were locally found. In this study, we present a petrographic, mineral chemistry and geothermobarometric study concerning the most abundant ACIC rocks. These rocks showed emplacement conditions corresponding to middle and lower crust, which are similar to crustal levels estimated for its main host rocks. In addition, the ACIC rocks enclose many host rocks xenoliths, with some of them showing melting evidences. These evidences suggest that the ACIC host rocks were one of the main sources of the ACIC felsic magmas, which contaminated mantle mafic magmas during ACIC evolution. Due to the similarities between the AWCO post-collisional rocks, present work concludes that post-collisional plutons intruded between the middle and lower crust levels and were contaminated by its host rocks during its evolution and cooling, contributing also to the felsic magma sources.
•The ACIC rocks were crystallized between middle and lower crustal levels.•The ACIC minerals revealed sources involving mantle and crustal magmas.•The ACIC host rocks can be the main source of crustal magmas.•The host rocks had an important role in the AWCO post-collisional plutons evolution.
The Afonso Cláudio Intrusive Complex (ACIC) is a typical post-collisional intrusion from Araçuaí-West Congo orogen (AWCO). The ACIC intruded allanite-bearing orthogneisses from AWCO pre-collisional ...tectonic stage (Rio Doce arc related rocks) and paragneisses from Nova Venécia Complex and it is composed of two lowered off-centered monzogabbroic and monzodioritic cores surrounded by quartz monzonite high hills, showing intense magma mingling and mixing between these domains. Xenoliths attributed to the enclosing gneisses have been commonly found widespread in the quartz monzonitic rocks, while are occasional in the monzogabbroic and monzodioritic domain. This paper presents the first detailed investigation of the xenoliths hosted by an AWCO post-collisional intrusion, focusing on petrography, major and trace element geochemistry and U–Th–Pb monazite dating of the main xenolith types. For comparison, major and trace element data investigation of the ACIC enclosing rocks has also been conducted. The correlated xenoliths and ACIC enclosing rocks show partially similar geochemical features, however both show different REE and multi-element normalized patterns compared to the ACIC main rocks. These results suggest that correlated xenoliths and enclosing rocks are cogenetic, however both could not represent the main sources of magmas that generated the ACIC. Geochemical modeling of igneous processes of previous ACIC dataset considering the investigated xenoliths and enclosing rocks as the main assimilant material suggests that mixing was responsible for both ACIC main rocks similar geochemical patterns and linear trends in the bimodal diagrams. This modeling also indicates that the evolution of the ACIC main rocks was ruled by different processes. Fractional crystallization with minor influence of assimilation of enclosing rocks controlled the magmatic evolution of monzogabbro and monzodiorite related to an enriched mantle source, while coupled assimilation and fractional crystallization ruled the evolution of quartz monzonite possibly associated to lower crust magmas mainly contaminated by enclosing rocks. U–Th–Pb monazite dating of two xenoliths showed that these rocks preserved similar main ages related to different stages of ACIC and AWCO post-collisional evolution. Both xenoliths showed main older ages of 478 and 477 Ma which are related to ACIC intrusion during AWCO post-collisional stage, while younger ages of 431 and 427 Ma are probably related to the intrusion of syenogranite dykes that crosscut the ACIC, representing an extension of AWCO post-collisional magmatism or a later unrelated thermal event. Due to the similarities between the typical AWCO post-collisional intrusions, the insights brought about the evolution of ACIC magmas could be considered to the typical AWCO post-collisional mantle and crustal magmas. This first investigation of xenoliths hosted by an AWCO post-collisional intrusion has showed that these strange rock pieces could bring new and important insights about the AWCO evolution, which shows an amazing and long-lasting magmatism with common occurrence of poorly investigated xenoliths.
•The ACIC is formed by the interaction between mantle and crustal contrasting magmas.•The contrasting magmas evolved ruled by different processes.•Assimilation of enclosing country rocks is an important process in ACIC evolution.•The xenoliths preserved two main ages related to ACIC and AWCO evolution.
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