Phthalates (PAEs) and alkylphenols (APs), known as endocrine-disrupting compounds (EDCs), are ubiquitous in aquatic environments worldwide and may be harmful to aquatic ecosystems. This study is the ...first to comprehensively assess the occurrence and potential ecological risks of 12 EDCs in the surface sediments of seven major harbors in Taiwan. In addition, a correlation model was established between the concentration levels of individual PAEs and APs in the sediments and their production. The total PAEs concentrations in the sediments ranged between 129-1894 ng/g dw (mean: 558 ± 479 ng/g dw). Total APs concentrations ranged between<0.2-913 ng/g dw with a mean of 52 ± 178 ng/g dw. Among the 12 EDCs, bis(2-ethylhexyl) phthalate (55.1%) and diisononyl phthalate (31.6%) were the predominant PAEs, while 4-nonylphenol (93.2%) was the main AP. The occurrence and concentrations of PAEs and APs in the sediments were significantly correlated with their production (r = 0.989, p < .01), reflecting the status and degree of anthropogenic pollution. The concentrations of PAEs and APs in the sediments of Taiwanese harbors showed a potential decreasing trend over time, which should be related to strengthened regulations and changes in the industrial market. The estimated total risk quotient (TRQ) of algae exposed to the concentrations of 12 EDCs in sediments suggests moderate to high potential risks (TRQ = 0.74-2.18), while crustaceans (TRQ = 0.02-0.27) and fish (TRQ = 0.03-0.10) may have low to moderate potential risks. The main compounds responsible for these risks are dibutyl phthalate, dioctyl phthalate, and 4-nonylphenols. The results show that the pollution degree of surface sediments in the harbor could reflect anthropogenic pollution. Therefore, it is necessary to monitor the pollution of surface sediments in harbors, grasp the pollution situation, and evaluate the regulatory effect.
► Sediments columns of Rijeka harbor were analyzed for 63 elements. ► Metal enrichment factor and geoaccumulation index were calculated. ► Spatial maps of recent and historic maps were constructed. ► ...Hg was heaviest pollutant and it is followed by Ag. ► Concentrations of investigated toxic elements are comparable with other port sediments.
We studied metal pollution in the sediments of Rijeka harbor, including anthropogenic influence during recent decades and at the present time. Sediment profiles were collected at ten sampling points. The concentrations of 63 elements in bulk sediment were obtained using ICP–MS, and the concentrations of selected elements were evaluated by statistical factor analyses. We also calculated metal-enrichment factors and geoaccumulation indices and constructed spatial-distribution maps.
Mercury (Hg) was the heaviest pollutant, with concentrations exceeding 4mg/kg. Silver (Ag) was the second most important pollutant, with constantly increasing values. The average concentrations of the most toxic elements were comparable to those found in sediments of other ports throughout the world, and their toxicity ranged from threshold values chromium (Cr), arsenic (As) and midrange-effect values cadmium (Cd), lead (Pb), copper (Cu), zinc (Zn), nickel (Ni) to extreme-effect values (Hg). Metal pollution has decreased during recent decades, except for Ag and barium (Ba).
This work investigates the ecotoxicological evaluation of contaminated dredged sediments from French Mediterranean navy harbour (A), commercial port (B) and two composite specimens (C) and (D) coming ...from the mixture of A and B with other port sediments. The toxicity of elutriates from these sediments is estimated using embryo-toxicity test, Microtox® solid phase test, LuminoTox, phytotoxicity tests and genotoxicity test. Bioassay responses are not clearly correlated with chemical contamination in the whole sediment and vary as a function of tested organisms. The highest contaminated samples (A and C) are almost always more toxic than the less contaminated samples (B and D). Among composite sediments, the mixture effect with other sediments is not efficient to decrease toxicity in sample C, suggesting that other parameters influence toxicity level such as particle size or organic matter content. These parameters should be taken into consideration in order to improve the efficiency of the mixture process and produce composite sediments with low toxicity.
Heavy metal abundance and potential environmental risks are reported for surface sediments (n = 21) from the Port of Koper area, Republic of Slovenia. The enrichment factor (EF) indicates minor ...enrichment in arsenic (As), cadmium (Cd), copper (Cu), molybdenum (Mo), lead (Pb), antimony (Sb), and zinc (Zn), moderately to severely enriched with nickel (Ni). The trace metal chemistries, in the context of sediment quality guidelines (SQG), imply adverse threshold effect concentrations (TEC) and probable effect concentrations (PEC), for Ni only. Sediment sequential leaching experiments demonstrated that the majority of heavy metals were of natural lithogenic origin and low bioavailability. The heavy metals’ potential for “Risk Assessment Code” values exhibited no or low anthropogenic environmental burden, with the exception of Mo.
The Apulia region in Italy has the longest Adriatic coastline; thus, maritime tourism is the driving force for its economic development. Pollution risk for four representative touristic ports of the ...region was assessed by determining the concentrations of 10 metals, 16 polycyclic aromatic hydrocarbons (PAHs) congeners, and the main nutrients. The cumulative mean Effects Range–Median quotient (mERMq) was used to assess the hazard degree, while the distribution patterns and content ratios of different PAH sediment concentrations were investigated to identify the pollution sources. Principal component analyses indicated an anomalous pollution trend for one of the small touristic ports assessed; this trend emerged from contamination by heavy metals and PAHs to a larger extent than expected, considering the main activity in this port, especially in its inner basin. The reason of this anomaly is thought to be the hydrodynamic and/or other stress factors.
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•Touristic ports are driving force for the local development of coastal regions.•Touristic port activity can affect the quality of port area and the nearby coast.•Cumulative indexes and PAH content ratio were used to assess port pollution sources.•The inner basin of the ports resulted unusually more affected than the outer one.•Hydrodynamic or other factors need to be studied for a spot-on risk assessment.
Although the dredging of ports is a necessary management activity, it generates immense quantities of sediments, that are defined by the European Union as residues. On the other hand, the relevant ...peat demand for plant cultivation compromises its availability worldwide. In this context, the present work wanted to find an alternative substrate in order to replace and/or reduce the use of peat in agriculture, through the study of the suitability, concerning the exchange of substrate–plant–water pollutants, of the dredged remediated sediments as a fruit-growing media. Forty-five pomegranate trees (Punica granatum L. cv “Purple Queen”) were cultivated in three types of substrates (100% peat as a control, 100% dredged remediated sediments and 50% both mixed). The metal ion content and pesticide residues were analysed in the different plant parts (root, stem, leaves and fruits) and in drainage water. The results showed a limited transfer of pollutants. All the pollutants were below the legal limits, confirming that the dredged sediments could be used as a growing media, alone or mixed with other substrates. Thus, the results point out the need to open a European debate on the reuse and reconsideration of this residue from a circular economy point of view.
The need to remove deposited material from water basins is common and has been shared by many ports and channels since the earliest settlements along coasts and rivers. Dredging, the most widely used ...method to remove sediment deposits, is a reliable and wide-spread technology. Nevertheless, dredging is only able to restore the desired water depth but without any kind of impact on the causes of sedimentation and so it cannot guarantee navigability over time. Moreover, dredging operations have relevant environmental and economic issues. Therefore, there is a growing market demand for alternatives to sustainable technologies to dredging able to preserve navigability. This paper aims to evaluate the effectiveness of guaranteeing a minimum water depth over time at the port entrance at Marina of Cervia (Italy), wherein the first industrial scale ejector demo plant has been installed and operated from June 2019. The demo plant was designed to continuously remove the sediment that naturally settles in a certain area through the operation of the ejectors, which are submersible jet pumps. This paper focuses on a three-year analysis of bathymetries realized at the port inlet before and after ejector demo plant installation and correlates the bathymetric data with metocean data (waves and sea water level) collected in the same period. In particular, this paper analyses the relation between sea depth and sediment volume variation at the port inlet with ejector demo plant operation regimes. Results show that in the period from January to April 2020, which was also the period of full load operation of the demo plant, the water depth in the area of influence of the ejectors increased by 0.72 mm/day, while in the whole port inlet area a decrease of 0.95 mm/day was observed. Furthermore, in the same period of operation, the ejector demo plant’s impact on volume variation was estimated in a range of 245–750 m3.
The increase in maritime trade and its global economic importance have forced port management actors to carry out the periodic dredging of their sediments to maintain an adequate depth for the ...passage of large ships to maintain their operation and competitiveness. During the dredging process, large volumes of port sediment are generated. Dredged port sediment is currently considered a waste material and its disposal is regulated. Finding ways to safely reuse port sediments is necessary for sustainable development. In this study, a life cycle assessment (LCA) methodology was applied to identify the environmental impact of port sediments when used as a culture medium for lemon trees. A total of 90 lemon trees (Citrus limon L. Burm var ‘Verna’) were used in the trial. The trees were grown under controlled conditions using three substrates, with different portions of peat and port sediment (25%, 50%, and 75%) to identify the real impacts of the culture media on the growth process. The LCA was calculated and analyzed according to the ISO 14040:2006 standard, using the SimaPro v. 9.3 software (PRé Sustainability B.V, Amersfoort, The Netherlands). The functional unit defined for the three-culture media was 1 kg of lemons. The LCA results showed a significant increase in the environmental impact of lemon cultivation proportional to port sediment content (75%), due to the decrease in fruit production caused by the sediment. However, the least impact was identified for the culture medium at 50% peat and 50% port sediment. The greatest impacts were more related to crop management rather than the port sediment content. The results showed that the use of the port sediment, mixed with other substrates as an agricultural medium amendment, is a viable option for lemon growers.
The increasingly evident threat of depletion of world peat bogs is encouraging the search for and study of alternative agricultural substrates that can fully or partially replace peat, guaranteeing ...food supply (quality and quantity). On the other hand, the identification of the potential for the reuse of waste from relevant economic activities has increased in recent years, mainly motivated by the change to a sustainable circular economy, as is the case of port sediments. Taking into account that significant volumes of dredged port sediments are generated annually so that ports can maintain their economic activity, it is necessary to find objective, sustainable and safe reuse alternatives. In this sense, the objective of this study was to study the response of the "Purple Queen" pomegranate when grown with dredged port sediment. For this, the fruit production (kg), number of fruits (fruits tree-1), fruit weight (g), and seed yield (%) aiming to verify the correct tree development were evaluated. In addition, a 1H-NMR foliar metabolomic study for the three most relevant phenological phases was performed (flowering, fruit development, and post-harvest) to identify metabolic changes in trees. In total, 29 metabolites were identified; among them, 11 were amino acids, 6 organic acids, 5 sugars, and 7 secondary metabolites. The good agronomical development of the trees and fruits indicated the potential for using the dredged sediment as an agricultural substrate. On the other hand, the results revealed that the greatest variability in the metabolomic study occurred between the phenological phases and a lower variability is explained by the substrates used.
This work assesses the ecotoxicological effects of polluted sediment after a decontamination treatment process using a new sediment washing technique. Sediment samples were collected from four sites ...in Marghera Port industrial channels (Venice, Italy). Ecotoxicological evaluations were performed with
Vibrio fischeri and
Crassostrea gigas bioassays. Whole sediment and elutriate were deemed as the most suitable environmental matrices for this study. Toxicity scores developed in the Lagoon of Venice for
V. fischeri on whole sediment and for
C. gigas on elutriate were considered for the final ranking of samples. Ecotoxicological results showed that the treated sediment samples presented both acute and sub-chronic toxicities, which were mainly attributed to the presence of some remaining chemicals such as metals and polyaromatic hydrocarbons. The acute toxicity ranged from low to medium, while the sub-chronic one from absent to very high, suggesting that treated sediments could not be reused in direct contact with seawater.
A sediment washing technique was assessed for port contaminated sediment remediation and reuse, indicating its reduced efficiency and the need for further improvements.
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