Superlubricity of graphite and graphene has aroused increasing interest in recent years. Yet how to obtain a long-lasting superlubricity between graphene layers, under high applied normal load in ...ambient atmosphere still remains a challenge but is highly desirable. Here, we report a direct measurement of sliding friction between graphene and graphene, and graphene and hexagonal boron nitride (h-BN) under high contact pressures by employing graphene-coated microsphere (GMS) probe prepared by metal-catalyst-free chemical vapour deposition. The exceptionally low and robust friction coefficient of 0.003 is accomplished under local asperity contact pressure up to 1 GPa, at arbitrary relative surface rotation angles, which is insensitive to relative humidity up to 51% RH. This ultralow friction is attributed to the sustainable overall incommensurability due to the multi-asperity contact covered with randomly oriented graphene nanograins. This realization of microscale superlubricity can be extended to the sliding between a variety of two-dimensional (2D) layers.
In this paper, the wear and corrosion resistance of FeNiCoCrMox (x: atomic ratio, x = 0, 0.15, 0.20, 0.25) high entropy alloy coatings (HEACs) which prepared by laser cladding (LC) technology on 316 ...stainless steel (SS) was investigated. According to XRD, SEM, MicroXAM-3D, microhardness tester and electrochemical workstation tests results, the HEACs presented typical DR-ID structure with single FCC solid solution phase. The average microhardness of Mo0, Mo0.15, Mo0.20 and Mo0.25 HEACs increased by 70.1%, 77.0%, 84.9% and 90.5% relative to the substrate. Dry sliding friction and wear tests results showed that the average friction coefficient of the HEACs were significantly lower than that of 316 SS substrate. Meanwhile, it can be found that Mo0.25 HEACs had the lowest average friction coefficient which displayed the best wear resistance. Compared with Mo0 HEAC, the specific wear rates of Mo0.15, Mo0.20 and Mo0.25 HEACs decreased by 11.1%, 27.8% and 38.9% respectively. The electrochemical tests results showed that the corrosion type of HEACs was intergranular corrosion and all HEACs had a higher corrosion resistance than that of 304 SS or 316 SS. Moreover, Mo0.20 HEACs showed the best corrosion resistance due to the enhancing effect of MoO3 on Cr2O3 passivation film.
•The enhancement effect of Mo on wear resistance and corrosion resistance was explored.•The conclusions provide a reference for expanding the application range of 316stainless steel FeNiCoCrMox HEACs.
Friction is a fundamental phenomenon that affects many different areas of human life and technology. In this Colloquium the microscopic origins of friction are reviewed in light of recent ...developments that are beginning to unveil the processes at the interface of two sliding materials. Large-scale simulations and theoretical modeling help reveal the complex nature of this basic phenomenon which is still the subject of much controversy. The physics of sliding friction is gaining impulse from nanoscale and mesoscale experiments, simulations, and theoretical modeling. This Colloquium reviews some recent developments in modeling and in atomistic simulation of friction, covering open-ended directions, unconventional nanofrictional systems, and unsolved problems.
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•Developed molecular model of sliding contact between two non-Gaussian rough surfaces.•Surface topography changes after sliding motion for each plate spacing (δ).•More increase in ...autocorrelation length signifies more flattening of the surface.•Higher atomic wear and dislocation length are observed for lower plate spacing (δ).
Friction plays a significant role in the wear and tear of sliding metallic surfaces, particularly in gears and bearings employed in nano and micro electro-mechanical systems (NEMS/MEMS). To comprehend the nature of dry sliding friction in mechanical devices, it is crucial to investigate surface interactions at the nano-scale. Molecular dynamics (MD) simulation has been utilized in this study to explore how asperities come into contact at this minute scale. Specifically, the interaction between two non-Gaussian rough surfaces is examined at varying dimensionless spacing (δ/Seq), ranging from 3.6 to 2.7. The von Mises strain, atomic wear, and changes in the atomic arrangement after sliding action are obtained for Cu-Cu (soft-to-soft) tribo-pair at a given sliding speed of 10 m/s. The average friction force on the lower surface increased when the space between surfaces was decreased. More percentage changes in surface topography are found for the lesser dimensionless spacing (δ/Seq) of 2.7. The changes in surface topography parameters during sliding action may have an immense effect on the performance of tribo-pair in NEMS/MEMS. A greater increase in autocorrelation length signifies a more pronounced flattening of the lower surface at the lower dimensionless spacing (δ/Seq).
The origin of ultra-low friction exhibited by heterogeneous junctions of graphene and hexagonal boron nitride (h-BN) is revealed. For aligned interfaces, we identify a characteristic contact size, ...below which the junction behaves like its homogeneous counterparts with friction forces that grow linearly with the contact area. Superlubricity sets in due to the progressive appearance of Moiré patterns resulting in a collective stick-slip motion of the elevated super-structure ridges that turns into smooth soliton-like gliding with increasing contact size. Incommensurability effects are enhanced in misaligned contacts, where the friction coefficients further drop by orders of magnitude. Our fully atomistic simulations show that the superlubric regime in graphene/h-BN heterostructures persists up to significantly higher loads compared to the well-studied twisted homogeneous graphene interface. This indicates the potential of achieving robust superlubricity in practical applications using two-dimensional layered materials heterojunctions.
This paper presents a novel micro end-milling cutting forces prediction methodology including the edge radius, material strengthening, varying sliding friction coefficient and run-out together. A new ...iterative algorithm is proposed to evaluate the effective rake angle, shear angle and friction angle, which takes into account the effects of edge radius as well as varying sliding friction coefficient. A modified Johnson–Cook constitutive model is introduced to estimate the shear flow stress. This model considers not only the strain-hardening, strain-rate and temperature but also the material strengthening. Furthermore, a generalized algorithm is presented to calculate uncut chip thickness considering run-out. The cutting forces model is calibrated and validated by NAK80 steel, and the relevant micro slot end-milling experiments are carried out on a 3-axis ultra-precision micro-milling machine. The comparison of the predicted and measured cutting forces shows that the proposed model can provide very accurate predicted results. Finally, the effects of material strengthening, edge radius and cutting speed on the cutting forces are investigated by the proposed model and some conclusions are given as follows: (1) the material strengthening behavior has significant effect on micro end-milling process at the micron level. (2) Cutting forces predicted increase with the increase of edge radius. (3) Considering varying sliding friction coefficient can enhance the sensitivity of the predicted cutting forces to cutting speed.
•A novel micro end-milling cutting forces prediction methodology was presented.•Edge radius, material strengthening and sliding friction coefficient were considered.•Material strengthening has a significant effect on cutting forces at micron level.•Cutting forces predicted increase with the increase of edge radius.•Varying sliding friction coefficient affects the predicted cutting forces.
Particle-based simulations of discontinuous shear thickening (DST) and shear jamming (SJ) suspensions are used to study the role of stress-activated constraints, with an emphasis on resistance to ...gearlike rolling. Rolling friction decreases the volume fraction required for DST and SJ, in quantitative agreement with real-life suspensions with adhesive surface chemistries and "rough" particle shapes. It sets a distinct structure of the frictional force network compared to only sliding friction, and from a dynamical perspective leads to an increase in the velocity correlation length, in part responsible for the increased viscosity. The physics of rolling friction is thus a key element in achieving a comprehensive understanding of strongly shear-thickening materials.
Structural superlubricity is a fascinating tribological phenomenon, in which the lateral interactions between two incommensurate contacting surfaces are effectively cancelled resulting in ultralow ...sliding friction. Here we report the experimental realization of robust superlubricity in microscale monocrystalline heterojunctions, which constitutes an important step towards the macroscopic scale-up of superlubricity. The results for interfaces between graphite and hexagonal boron nitride clearly demonstrate that structural superlubricity persists even when the aligned contact sustains external loads under ambient conditions. The observed frictional anisotropy in the heterojunctions is found to be orders of magnitude smaller than that measured for their homogeneous counterparts. Atomistic simulations reveal that the underlying frictional mechanisms in the two cases originate from completely different dynamical regimes. Our results are expected to be of a general nature and should be applicable to other van der Waals heterostructures.
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