Vehicular energy network (VEN), as an important part of the Internet of Things for the smart city, can facilitate the renewable energy (RE) transportation over a large geographical area by means of electric vehicles (EVs) through wireless power transfer technology. However, due to the potential security vulnerability in VEN, EV users can be attacked by external or internal adversaries. In addition, owing to the selfishness of EVs, it is a great challenge to optimally schedule the charging/discharging behaviors of EVs to realize regional energy balance in VEN. To tackle the above issues, this paper proposes a blockchain-based secure incentive scheme for energy delivery in VEN. First, a novel permissioned energy blockchain system is introduced in VEN to implement secure energy delivery services for EVs and energy nodes through the use of distributed ledgers and cryptocurrency. Second, a proof of reputation consensus protocol is proposed to efficiently reach consensus in energy blockchain, where the reputation derivation is constructed based on the local trust computing and credibility computing. Third, motivated by the pricing mechanism, an incentive model is developed to stimulate EVs to cooperatively deliver RE to various areas with different electricity loads while maximizing EVs' utilities. Finally, extensive numerical results are provided, which demonstrate the efficiency of the proposed scheme through the comparison with conventional schemes.