We evaluate the contribution of cosmic microwave background (CMB) polarization spectra to cosmological parameter constraints. We produce cosmological parameters using high-quality CMB polarization data from the ground-based QUaD experiment and demonstrate for the majority of parameters that there is significant improvement on the constraints obtained from satellite CMB polarization data. We split a multi-experiment CMB dataset into temperature and polarization subsets and show that the best-fit confidence regions for the LCDM 6-parameter cosmological model are consistent with each other, and that polarization data reduces the confidence regions on all parameters. We provide the best limits on parameters from QUaD EE/BB polarization data and we find best-fit parameters from the multi-experiment CMB dataset using the optimal pivot scale of k_p=0.013 Mpc-1 to be {omch2, ombh2, H_0, A_s, n_s, tau}= {0.113, 0.0224, 70.6, 2.29 times 10^-9, 0.960, 0.086}.