The efficient removal of organic impurities in waste salts is significant for their recycling and environmental protection. The pyrolysis process of organic impurities in waste salt was investigated by thermogravimetric experiment to analyze the reaction kinetics characteristics. The results indicate that the pyrolysis reaction temperature range for the present waste salt is between 641.15 K and 726.22 K. The activation energy is 177.59 kJ mol−1, and the pre-exponential factor is 2.98 × 1011 s−1. Based on this, a numerical model was established to investigate the pyrolysis performance of organic impurities in practical tubular reactor. The effects of configuration and operating parameters on reaction performance and energy consumption were revealed. It was discovered that increasing the heating rate and wall temperature can accelerate pyrolysis rate but results in higher energy consumption. To balance reaction time and energy consumption, the heating rate of 15 K/min and heating temperature of 773.15 K are recommended. The content of organic impurities and bed porosity have minimal impact on the reaction rate and energy consumption, indicating that the tubular reactor has wide applicability in various working conditions. Additionally, reducing bed porosity can improve the processing rate and daily processing capacity. This paper provides a method to analyze the pyrolysis performance of organic impurities in waste salt, which is significant for designing and selecting working conditions of practical reactor for waste salt treatment. Display omitted •Pyrolysis kinetics characteristics of organic impurities were investigated.•Reaction temperature is between 641.15 K and 726.22 K.•Activation energy and pre-exponential factor are 177.59 kJ/mol and 2.98 × 1011 s−1.•Numerical model for pyrolysis process of organic impurities was established.•Effects of parameters on reaction rate and energy consumption were investigated.