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  • Phase Diagram and Soft Mode...
    Krylov, A. S.; Vtyurin, A. N.; Gudim, I. A.; Nemtsev, I. V.; Krylova, S. N.

    Optics and spectroscopy, 09/2023, Letnik: 131, Številka: 9
    Journal Article

    The Raman spectra of four crystals of TbFe 3– x Ga x (BO 3 ) 4 solid solutions ( x from 0 to 0.54) were studied in the temperature range from 8 to 350 K. The temperatures of structural phase transitions were determined. The observed spectral behavior is characteristic to condensation and restoration of soft modes. Soft modes are associated with a structural phase transition from the R 32 phase to the P 3 1 21 phase. The Compositions-Temperature phase diagram was constructed.